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sodium bromodifluoroacetate (6) 6
chemistry, organic (5) 5
chemistry, multidisciplinary (4) 4
fluorine (4) 4
gem-difluorocyclopropanes (4) 4
silyl dienol ethers (4) 4
carbene complexes (3) 3
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reactivity (3) 3
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crafts-type cyclization (2) 2
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difluorocarbene (2) 2
difluoromethylated arenes (2) 2
fluor (2) 2
fluorides (2) 2
generation (2) 2
h insertion (2) 2
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sodium (2) 2
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3,3-disubstituted allylic difluorides (1) 1
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acetylcholinesterase (1) 1
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ethyl bromodifluoroacetate (1) 1
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The Journal of Organic Chemistry, ISSN 0022-3263, 10/2018, Volume 83, Issue 20, pp. 12815 - 12821
Ethyl bromodifluoroacetate (BrCF2COOEt) was first used as the N-formylating reagent in the copper-catalyzed N-formylation of amines. A range of primary,... 
ARYL BROMIDES | ROOM-TEMPERATURE | MILD CONDITIONS | SOLVENT-FREE CONDITIONS | SODIUM BROMODIFLUOROACETATE | CHEMISTRY, ORGANIC | REFORMATSKY REACTION | CARBON-DIOXIDE | SECONDARY-AMINES | OXIDATIVE FORMYLATION | MOLECULAR-OXYGEN
Journal Article
Chemical Communications, ISSN 1359-7345, 04/2017, Volume 53, Issue 31, pp. 4382 - 4385
We report the synthesis of the trifluoromethyl cobalt(III)tetraphenylporphyrinato complex [Co(TPP)CF3], which loses fluoride upon one-electron reduction and... 
METAL-CARBENES | SODIUM BROMODIFLUOROACETATE | CYCLOPROPANATION | REACTIVITY | TETRAFLUOROETHYLENE | H INSERTION | SILYL DIENOL ETHERS | GEM-DIFLUOROCYCLOPROPANES | RADICALS | CARBENE COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Chemical Communications: Chem Comm, ISSN 1359-7345, 04/2017, Volume 53, Issue 31, pp. 4382 - 4385
We report the synthesis of the trifluoromethyl cobalt(iii)tetraphenylporphyrinato complex [Co(TPP)CF3], which loses fluoride upon one-electron reduction and... 
Acrylates | Synthesis | Catalysts | Olefins | Fluorides | Catalysis | Cobalt | Porphyrins
Journal Article
Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry, ISSN 0037-9980, 2017, Volume 75, Issue 11, pp. 1125 - 1132
Fluorine is a key element by virtue of the unique properties associated with the atom itself and its bond to carbon, its high electronegativity and relatively... 
CROSS-COUPLING REACTIONS | F BOND-CLEAVAGE | FACILE SYNTHESIS | ONE-POT SYNTHESIS | PHOSPHOLIPID ANALOGS | SODIUM BROMODIFLUOROACETATE | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | SILYL ETHERS | ELECTROREDUCTIVE DEFLUORINATION | TRIFLUOROMETHYL KETONES
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 07/2016, Volume 358, Issue 14, pp. 2293 - 2299
Carbamoyl fluorides are formed in reactions of hydroxylamines with difluorocarbene generated from sodium bromodifluoroacetate as readily available and... 
carbenes | reaction mechanism | synthetic methods | fluorine | CARBONYL FLUORIDE | REAGENTS | DECOMPOSITION | CHEMISTRY, ORGANIC | DECARBOXYLATION | MEDICINAL CHEMISTRY | DIFLUOROMETHYLATION | ACETYLCHOLINESTERASE | BIOLOGICAL-ACTIVITY | C-F BOND | CHEMISTRY, APPLIED | TRIFLUOROMETHYLATION | Fluorides | Synthesis | Sodium | Precursors | Mathematical analysis | Tolerances | Carbenes | Functional groups
Journal Article
Journal of Engineering, ISSN 1945-8711, 06/2014, p. 5567
  [...]the present inventors found that when using sodium bromodifluoroacetate as a difluorocyclopropanation agent, it is possible to provide a method for... 
Patents | Inventors | Sodium | Decomposition | Methods
Newspaper Article
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