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Chemical Society Reviews, ISSN 0306-0012, 4/2012, Volume 41, Issue 9, pp. 3464 - 3484
Copper salts have been developed as versatile catalysts for oxidative coupling reactions in organic synthesis. During these processes, Cu-catalysts are often... 
SP C-H | TERTIARY-AMINES | COUPLING REACTION | NITROGEN ATOM | INTRAMOLECULAR CARBOAMINATION | TERMINAL ALKYNES | ALPHA | BONDS ADJACENT | ARYL | INTERNAL ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | Electron Transport | Quantum Theory | Copper - chemistry | Nitrogen - chemistry | Oxygen - chemistry | Halogens - chemistry | Catalysis | Carbon - chemistry
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 04/2012, Volume 134, Issue 13, pp. 5750 - 5753
The dehydrogenative β′-functionalization of α-substituted β-keto esters with indoles proceeds with high regioselectivities (C3-selective for the indole partner... 
SP C-H | CARBON | MECHANISM | CROSS | ARYLATION | BOND FUNCTIONALIZATION | ALDEHYDES | PYRROLES | CHEMISTRY, MULTIDISCIPLINARY | ALKENYLATION
Journal Article
Organic Letters, ISSN 1523-7060, 11/2010, Volume 12, Issue 22, pp. 5214 - 5217
A novel cross dehydrogenative coupling (CDC) reaction of N,N-dimethylanilines with methyl ketones by cooperative copper and aminocatalysis has been developed,... 
SP C-H | ACTIVATION | CHEMISTRY, ORGANIC | HYDROGEN-PEROXIDE | BOND | OXIDATIVE CYANATION | ALKALOIDS
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2015, Volume 137, Issue 2, pp. 964 - 973
The addition of a variety of radicals to the double bond of N-(arylsulfonyl)­acrylamides can trigger cyclization/​aryl migration/​desulfonylation cascades via... 
MIGRATION | SP C-H | ACTIVATED ALKENES | BETA-KETOESTERS | C(SP3)H BOND | 1,3-DICARBONYL COMPOUNDS | COUPLING REACTION | CATALYZED TRIFLUOROMETHYLATION | BOND FORMATION | CHEMISTRY, MULTIDISCIPLINARY | METAL-FREE | Amides | Chemical synthesis | Carbon compounds | Analysis | Electric properties
Journal Article
ORGANIC LETTERS, ISSN 1523-7060, 12/2013, Volume 15, Issue 23, pp. 5928 - 5931
A CuI-catalyzed A(3) (amines, aldehydes and alkynes) reaction of tetrahydroisoquinolines (THIQs), aldehydes, and alkynes to give C1-alkynylated THIQ products... 
FUNCTIONALIZATION | OXIDATION | SP C-H | ACTIVATION | COUPLING REACTIONS | TERTIARY-AMINES | PROPARGYLAMINES | CHEMISTRY, ORGANIC | TERMINAL ALKYNES | BONDS ADJACENT | SECONDARY-AMINES
Journal Article
Chemical Communications, ISSN 1359-7345, 11/2013, Volume 49, Issue 88, pp. 10370 - 10372
An efficient silver-catalyzed oxidative cyclization of acrylamides with 1,3-dicarbonyl compounds is described. It proceeds through a tandem radical... 
METAL-FREE SYNTHESIS | FUNCTIONALIZATION | SP C-H | ACTIVATED ALKENES | DIRECT ARYLATION | C(SP3)H BOND | DEHYDROGENATIVE-COUPLING REACTION | OXINDOLES | FREE-RADICAL REACTIONS | CARBON-CARBON BONDS | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
by Liu, D and Li, YX and Qi, XT and Liu, C and Lan, Y and Lei, AW
ORGANIC LETTERS, ISSN 1523-7060, 02/2015, Volume 17, Issue 4, pp. 998 - 1001
An effective strategy for inert Csp(3)H functionalization through nickel-catalyzed selective radical cross-couplings was demonstrated. Density functional... 
CYCLOALKANES | SP C-H | ACIDS | SIMPLE ALKANES | ESTERIFICATION | CHEMISTRY, ORGANIC | BOND FORMATION | COPPER | BETA-KETO-ESTERS | DECARBOXYLATIVE ALKENYLATION | DERIVATIVES
Journal Article
Organic Letters, ISSN 1523-7060, 01/2012, Volume 14, Issue 1, pp. 94 - 97
Our previous studies into visible-light-mediated aza-Henry reactions demonstrated that molecular oxygen played a vital role in catalyst turnover as well as the... 
SP C-H | BOND-DISSOCIATION ENERGIES | LOW-VALENT RUTHENIUM | LEWIS-ACID | TERTIARY-AMINES | NITROGEN ATOM | RADICAL CATIONS | CHEMISTRY, ORGANIC | BASE CATALYSTS | PHOTOREDOX CATALYSIS | MOLECULAR-OXYGEN | Protons | Oxidation-Reduction | Light | Imines - chemistry | Molecular Structure | Catalysis | Alkylation | Photochemical Processes
Journal Article
Organic Letters, ISSN 1523-7060, 01/2015, Volume 17, Issue 1, pp. 134 - 137
The first C3-dicarbonylation of indoles was realized through direct oxidative cross-coupling of indoles with methyl ketones in the presence of molecular iodine... 
FUNCTIONALIZATION | AMINO CARBONYL-COMPOUNDS | CATALYSIS | SP C-H | MOLECULAR-IODINE | TERTIARY-AMINES | STRATEGY | CONSTRUCTION | CHEMISTRY, ORGANIC | BOND FORMATIONS | DERIVATIVES
Journal Article
Organic Letters, ISSN 1523-7060, 05/2014, Volume 16, Issue 10, pp. 2602 - 2605
An intramolecular dehydrogenative (sp3)­C–O bond formation in salicylamides can be initiated by an active Cu/O2 species to generate pharamaceutically relevant... 
FUNCTIONALIZATION | SP C-H | ACTIVATION | OXIDATIVE MANNICH REACTION | TETRAHYDROISOQUINOLINES | TERTIARY-AMINES | NITROGEN ATOM | CHEMISTRY, ORGANIC | TERMINAL ALKYNES | ADJACENT | MOLECULAR-OXYGEN
Journal Article
Organic Letters, ISSN 1523-7060, 02/2015, Volume 17, Issue 4, pp. 884 - 887
By using catalytic amount of CoCl2 with dmgH (dimethylglyoxime) as ligand to form a photosensitizer in situ, a highly selective, efficient, and environmentally... 
FUNCTIONALIZATION | SP C-H | OXIDATIVE MANNICH REACTION | TERTIARY-AMINES | NITROGEN ATOM | CHEMISTRY, ORGANIC | BOND FORMATION | HIGHLY EFFICIENT | METAL-COMPLEXES | PHOTOREDOX CATALYSIS | MOLECULAR-OXYGEN
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 09/2014, Volume 50, Issue 68, p. 9718
A metal-free method for direct C(sp(3))-H bond functionalization of simple ethers with α,α-diaryl allylic alcohols is described. The established protocol... 
Journal Article
Organic Letters, ISSN 1523-7060, 06/2018, Volume 20, Issue 12, pp. 3460 - 3464
A multicomponent synthesis of tetrahydroisoquinolines from carboxylic acids, alkynyl ethers, and dihydroisoquinolines is described. This process features... 
FUNCTIONALIZATION | CATALYSIS | SP C-H | ASYMMETRIC-SYNTHESIS | ENANTIOSELECTIVE SYNTHESIS | NATURAL-PRODUCTS | CHEMISTRY | CHEMISTRY, ORGANIC | RECENT PROGRESS | HIGHLY EFFICIENT | ACCESS
Journal Article
CHEMISTRY-A EUROPEAN JOURNAL, ISSN 0947-6539, 06/2016, Volume 22, Issue 27, pp. 9135 - 9138
An efficient and external oxidant-free, Cp*Co-III-catalyzed C(sp(3))-H bond amidation of 8-methylquinoline, using oxazolone as an efficient amidating agent, is... 
amidation | C-SP3-H BONDS | ROOM-TEMPERATURE | sp C-H activation | INTERMOLECULAR AMIDATION | cobalt | quinoline | NITRENE TRANSFER-REACTIONS | INTERNAL ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | H ACTIVATION | COBALT(III)-CATALYZED ARYL | MILD CONDITIONS | INDOLE SYNTHESIS | CARBON-CARBON
Journal Article
Organic Letters, ISSN 1523-7060, 08/2015, Volume 17, Issue 15, pp. 3702 - 3705
A direct intermolecular olefination of sp(3) C-H bond between 2-oxindoles and simple alkenes via a Cross-Dehydrogenative Coupling (CDC) strategy has been... 
FUNCTIONALIZATION | SP C-H | TETRAHYDROISOQUINOLINES | VINYLATION | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | BOND ACTIVATION | ENANTIOSELECTIVE ALPHA-ARYLATION | EFFICIENT | ALKENYLATION | MOLECULAR-OXYGEN
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2015, Volume 54, Issue 49, pp. 14638 - 14658
Journal Article
ORGANIC LETTERS, ISSN 1523-7060, 10/2014, Volume 16, Issue 20, pp. 5358 - 5361
A unique organocatalytic asymmetric oxidative cross-dehydrogenative coupling of a alpha-Csp(3)-H bond of tertiary amines with alpha,beta-unsaturated... 
CARBON BOND FORMATION | FUNCTIONALIZATION | SP C-H | ACTIVATION | ALKYLATION | CHEMISTRY | CHEMISTRY, ORGANIC | VINYLOGOUS MICHAEL ADDITION | ADJACENT | MANNICH-TYPE | MOLECULAR-OXYGEN
Journal Article