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spin oxoiron complex (71) 71
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2-his-1-carboxylate facial triad (13) 13
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INORGANIC CHEMISTRY, ISSN 0020-1669, 08/2015, Volume 54, Issue 16, pp. 7828 - 7839
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 11/2016, Volume 138, Issue 43, pp. 14312 - 14325
In biology, high valent oxo–iron­(IV) species have been shown to be pivotal intermediates for functionalization of C–H bonds in the catalytic cycles of a range... 
H BOND ACTIVATION | FE-IV=O | PARAMAGNETIC-RESONANCE | ACTIVE-SITE | VALENT IRON(IV)-OXO COMPLEXES | C-TERM SIGNS | TRANSITION-METAL | 2-STATE REACTIVITY | SPIN OXOIRON(IV) COMPLEX | DENSITY-FUNCTIONAL THEORY | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2017, Volume 56, Issue 46, pp. 14384 - 14388
The sluggish oxidants [FeIV(O)(TMC)(CH3CN)]2+ (TMC=1,4,8,11‐tetramethyl‐1,4,8,11‐tetraazacyclotetradecane) and [FeIV(O)(TMCN‐d12)(OTf)]+... 
oxoiron(IV) complexes | hydrogen atom transfer | spin state | O ligands | oxygen atom transfer | O ligands | OXIDATION | MECHANISM | ESCHERICHIA-COLI | OXO | STATE | KETOGLUTARATE DIOXYGENASE | CHEMISTRY, MULTIDISCIPLINARY | NONHEME (FEO)-O-IV COMPLEXES | INTERMEDIATE | TAUD | Enzymes | Hydroxylation | Oxalic acid | Hydrogen | Bonding strength | Ligands | Iron | Oxidants | Oxidizing agents
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2011, Volume 133, Issue 3, pp. 403 - 405
Rates of electron transfer from a series of one-electron reductants to a nonheme oxoiron(IV) complex, [(N4Py)FeIV(O)]2+, are enhanced as much as 108-fold by... 
OXIDATION | OXO | LEWIS | PHOTOSYSTEM-II | CHEMISTRY | INTERMEDIATE | REDOX | LIGAND | CHEMISTRY, MULTIDISCIPLINARY | IRON(IV) | WATER | Scandium - chemistry | Electron Transport | Electron Spin Resonance Spectroscopy | Heme - chemistry | Metals - chemistry | Iron Compounds - chemistry
Journal Article
Angewandte Chemie (International ed. in English), ISSN 1433-7851, 11/2017, Volume 56, Issue 46, pp. 14384 - 14388
The sluggish oxidants, [Fe IV (O)(TMC)(CH 3 CN)] 2+ (TMC = 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane) and [Fe IV (O)( d 12 -TMCN)(OTf)] + ( 3d ; d... 
Oxygen Atom Transfer | Hydrogen Atom Transfer | Oxoiron(IV) Complex | Oxygen-Based Ligands | Spin State Effect
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2017, Volume 56, Issue 46, p. n/a
Iron Oxo Complexes In their Communication on page 14384 ff., W. Nam, M. Swart, K. Ray, et al. show that the oxoiron(IV) center in [FeIV(O)(TMCO)(OTf)]+ (bottom... 
oxoiron(IV) complexes | hydrogen atom transfer | spin state | O ligands | oxygen atom transfer | Hydrogen | Coordination compounds | Iron
Journal Article
Chemical science, ISSN 2041-6520, 03/2014, Volume 5, Issue 3, pp. 1204 - 1215
Treatment of [Fe ( )](OTf) ( ), (where = 1,4,8-Me cyclam-11-CH C(O)NMe ) with iodosylbenzene yielded the corresponding = 1 oxoiron(IV) complex [Fe (O( )](OTf)... 
Journal Article
Chemical Science, ISSN 2041-6520, 2014, Volume 5, Issue 3, pp. 1204 - 1215
Treatment of [Fe-II(L)](OTf)(2) (4), (where L = 1,4,8-Me(3)cyclam-11-CH2C(O)NMe2) with iodosylbenzene yielded the corresponding S = 1 oxoiron(IV) complex... 
COPPER-COMPLEXES | NONHEME | CRYSTAL-STRUCTURE | SIDE-CHAIN | IRON-OXO COMPLEXES | X-RAY | 2-STATE REACTIVITY | FUNCTIONAL-GROUPS | SPIN FE(IV) COMPLEX | CHEMISTRY, MULTIDISCIPLINARY | CU-2+ COMPLEXES | Spectroscopy | Conjugates | Stability | Similarity | Mathematical analysis | X-rays | Rafts | Mass spectrometry
Journal Article
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 07/2017, Volume 56, Issue 31, pp. 9091 - 9095
Ceric ammonium nitrate (CAN) or Ce-IV(NH4)(2)- (NO3)(6) is often used in artificial water oxidation and generally considered to be an outer-sphere oxidant.... 
MOLECULAR CATALYSTS | ACTIVATION | EXCHANGE-ENHANCED REACTIVITY | cerium | CRYSTAL-STRUCTURE | spin crossover | CHEMISTRY, MULTIDISCIPLINARY | electron transfer | water oxidation | COUPLED ELECTRON-TRANSFER | IRON COMPLEXES | 2-STATE REACTIVITY | CHEMISTRY | iron | LIGAND
Journal Article
Dalton Transactions, ISSN 1477-9226, 2018, Volume 47, Issue 10, pp. 3248 - 3252
The present study describes the first example of the hydroxylation of benzaldehydes by synthetic nonheme oxoiron(IV) complexes, where the reactivity,... 
OXYGEN ACTIVATION | ANGSTROM RESOLUTION | PHENYLALANINE-HYDROXYLASE | TYROSINE-HYDROXYLASE | SELF-HYDROXYLATION | TRYPTOPHAN-HYDROXYLASE | IRON-OXO COMPLEXES | SPIN FE(IV) INTERMEDIATE | AMINO-ACID HYDROXYLASES | TAURINE/ALPHA-KETOGLUTARATE DIOXYGENASE | CHEMISTRY, INORGANIC & NUCLEAR | Oxidation | Hydroxylation | Aldehydes | Benzaldehyde
Journal Article
Dalton transactions (Cambridge, England : 2003), ISSN 1477-9226, 02/2018, Volume 47, Issue 10, pp. 3248 - 3252
The present study describes the first example of the hydroxylation of benzaldehydes by synthetic nonheme oxoiron(iv) complexes, where the reactivity,... 
Journal Article
Chemical science, ISSN 2041-6520, 2012, Volume 3, pp. 1680 - 1693
The pentadentate ligand (n)Bu-P2DA (2(b), (n)Bu-P2DA = N-(1',1'-bis(2-pyridyl)pentyl)iminodiacetate) was designed to bind an iron center in a carboxylate-rich... 
Journal Article
Chemical Science, ISSN 2041-6520, 05/2012, Volume 3, Issue 5, pp. 1680 - 1693
The pentadentate ligand Bu-n-P2DA (2(b), Bu-n-P2DA N-(1',1'-bis(2-pyridyl) pentyl)iminodiacetate) was designed to bind an iron center in a carboxylate-rich... 
H BOND-CLEAVAGE | ALPHA-KETOGLUTARATE DIOXYGENASE | EXCHANGE-ENHANCED REACTIVITY | HYDROGEN-ATOM ABSTRACTION | 2-HIS-1-CARBOXYLATE FACIAL TRIAD | ACTIVE-SITES | ESCHERICHIA-COLI | SPIN FE(IV) INTERMEDIATE | FE-IV=O COMPLEX | NONHEME IRON(IV)-OXO COMPLEX | CHEMISTRY, MULTIDISCIPLINARY
Journal Article