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chemistry, organic (201) 201
hydrosilylation (178) 178
chemistry, multidisciplinary (170) 170
stereoselective-synthesis (168) 168
catalysis (118) 118
stereoselective hydrosilylation (87) 87
alkynes (71) 71
index medicus (64) 64
organic-synthesis (64) 64
stereoselective synthesis (59) 59
chemistry, inorganic & nuclear (53) 53
reduction (52) 52
complexes (51) 51
terminal alkynes (50) 50
stereoisomerism (45) 45
alkenes (40) 40
silicon (40) 40
cross-coupling reactions (39) 39
ligands (39) 39
metal-catalyzed asymmetric synthesis and stereoselective reactions (39) 39
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palladium (37) 37
stereoselective reduction (35) 35
synthesis (33) 33
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hydrogenation (32) 32
ketones (32) 32
molecular structure (32) 32
alcohols (31) 31
chemistry, physical (30) 30
homogeneous catalysis (30) 30
olefins (30) 30
alkene hydrosilylation (28) 28
asymmetric hydrosilylation (27) 27
derivatives (27) 27
regioselectivity (26) 26
asymmetric catalysis (25) 25
chemical properties (25) 25
asymmetric-synthesis (24) 24
copper (24) 24
organic chemistry (24) 24
activation (23) 23
enantioselective synthesis (23) 23
hydrosilation (23) 23
silanes (23) 23
alkine (22) 22
efficient (22) 22
mechanism (22) 22
natural products (22) 22
silanes - chemistry (22) 22
internal alkynes (21) 21
imines (20) 20
silafunctional compounds (20) 20
cyclization (19) 19
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reagents (19) 19
rhodium (19) 19
transfer hydrogenation (19) 19
alkene (18) 18
analysis (18) 18
article (18) 18
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regio (18) 18
ruthenium complexes (18) 18
stereoselectivity (18) 18
total synthesis (18) 18
asymmetric synthesis (17) 17
chemical synthesis (17) 17
dehydrogenative silylation (17) 17
diels-alder reactions (17) 17
oxidation (17) 17
reactivity (17) 17
ruthenium (17) 17
selectivity (17) 17
amines (16) 16
esters (16) 16
synthetic methods (16) 16
vinylsilanes (16) 16
carbon (15) 15
chemical reactions (15) 15
chemistry (15) 15
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hydrogen (15) 15
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chemistry, applied (14) 14
cobalt (14) 14
enantioselective hydrosilylation (14) 14
kinetic resolution (14) 14
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asymmetric transfer hydrogenation (13) 13
cross-coupling (13) 13
n-heterocyclic carbene (13) 13
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stereocontrolled synthesis (13) 13
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Angewandte Chemie International Edition, ISSN 1433-7851, 04/2017, Volume 56, Issue 15, pp. 4328 - 4332
A cobalt‐catalyzed Z‐selective hydrosilylation of alkynes has been developed relying on catalysts generated from bench‐stable Co(OAc)2 and pyridine‐2,6‐diimine... 
hydrosilylation | cobalt | homogeneous catalysis | vinylsilanes | alkynes | HYDROBORATION | HYDROGENATION | MECHANISM | ISOMERIZATION | CHEMISTRY, MULTIDISCIPLINARY | REGIO | TRANS ADDITION | HYDROSILATION | STEREOSELECTIVE HYDROSILYLATION | ALKENE HYDROSILYLATION | RUTHENIUM COMPLEX | Pyridine | Catalysis | Cobalt | Isomerization | Pyridines | Transformation | Catalysts | Phenols | Hydrosilylation | Alkynes
Journal Article
Chemistry – An Asian Journal, ISSN 1861-4728, 09/2018, Volume 13, Issue 17, pp. 2307 - 2315
Over the past few decades, manganese‐catalyzed hydrosilylation of C=O or C=C/C≡C unsaturated bonds have undergone enormous developments. In this focus review,... 
hydrosilylation | alkenes | carbonyl bonds | manganese | alkynes | KETONE HYDROSILYLATION | WELL-DEFINED MANGANESE | 1,3-DICARBONYL COMPOUNDS | CARBONYL-COMPOUNDS | C-H ACTIVATION | CHEMISTRY, MULTIDISCIPLINARY | HETEROCYCLIC CARBENE COMPLEXES | MN-III CATALYST | PINCER COMPLEXES | STEREOSELECTIVE HYDROSILYLATION | ALKENE HYDROSILYLATION
Journal Article
ChemCatChem, ISSN 1867-3880, 08/2017, Volume 9, Issue 16, pp. 3111 - 3116
A new method for the hydrosilylation of alkynes controlled by a platinum catalyst with a monophosphine ligand (called TBSO‐MOP) was explored. The... 
hydrosilylation | multicomponent reactions | platinum | alcoholysis | alkynes | ASYMMETRIC HYDROSILYLATION | SILICON-CONTAINING COMPOUNDS | COMPLEXES | CHEMISTRY, PHYSICAL | INTERNAL ALKYNES | REGIOSELECTIVITY | MECHANISTIC INSIGHTS | CHEMISTRY | REGIO | STEREOSELECTIVE HYDROSILYLATION | EFFICIENT
Journal Article
Organic Letters, ISSN 1523-7060, 09/2018, Volume 20, Issue 17, pp. 5357 - 5361
A series of novel monothiolate-bridged dirhodium complexes, [Cp*Rh­(μ-SR)­(μ-Cl)2RhCp*]­[BF4] {Cp* = η5-C5Me5, R = tertiary butyl ( t Bu), 1a; R = ferrocenyl... 
NICKEL-IRON | N-HETEROCYCLIC CARBENE | Z-SELECTIVE HYDROSILYLATION | CP-ASTERISK | RHODIUM(I) COMPLEXES | RUTHENIUM COMPLEXES | CHEMISTRY, ORGANIC | (Z)-SELECTIVE HYDROSILYLATION | STEREOSELECTIVE HYDROSILYLATION | HYDRIDE COMPLEXES | MARKOVNIKOV HYDROSILYLATION
Journal Article
02/2015, Volume 5, Issue 26, pp. 263 - 2616
This review covers the recent advances in hydrosilylation chemistry mainly published in the last decade. Hydrosilylation of olefins is an important reaction... 
Journal Article
RSC Advances, ISSN 2046-2069, 2015, Volume 5, Issue 26, pp. 20603 - 20616
This review covers the recent advances in hydrosilylation chemistry mainly published in the last decade. Hydrosilylation of olefins is an important reaction... 
CATALYZED HYDROSILYLATION | DEHYDROGENATIVE SILYLATION | RUTHENIUM SILYLENE COMPLEX | STRUCTURAL-CHARACTERIZATION | N-HETEROCYCLIC CARBENES | IRON CATALYSTS | SELECTIVE HYDROSILYLATION | STEREOSELECTIVE HYDROSILYLATION | REGIOSELECTIVE HYDROSILYLATION | CHEMISTRY, MULTIDISCIPLINARY | ORGANOSILICON COMPOUND
Journal Article
ACS Catalysis, ISSN 2155-5435, 07/2016, Volume 6, Issue 7, pp. 4105 - 4109
Combination of the readily available α-diimine ligand, ((ArNC­(Me))2 Ar = 2,6-iPr2–C6H3), (iPrDI) with air-stable nickel­(II) bis­(carboxylates) generated a... 
diimine | nickel | silicone | hydride | hydrosilylation | mechanism | carboxylate | ACTIVATION | HYDROGENATION | ALKYL | CHEMISTRY, PHYSICAL | IRON CATALYSTS | HYDRIDE COMPLEXES | CARBONYL-COMPLEXES | ETHYLENE | DEHYDROGENATIVE SILYLATION | HYDROSILATION | STEREOSELECTIVE HYDROSILYLATION
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 10/2015, Volume 137, Issue 41, pp. 13244 - 13247
Alkene hydrosilylation is typically performed with Pt catalysts, but inexpensive base-metal catalysts would be preferred. We report a Co catalyst for... 
HYDROBORATION | TRANSITION-METAL-COMPLEXES | SILICON HYDRIDES | OLEFINIC DOUBLE BONDS | ISOMERIZATION | HOMOGENEOUS CATALYSIS | RECENT PROGRESS | IRON CATALYSTS | STEREOSELECTIVE HYDROSILYLATION | HYDROSILATION REACTION | CHEMISTRY, MULTIDISCIPLINARY | Metal catalysts | Usage | Isomerization
Journal Article
Chemical Communications, ISSN 1359-7345, 2018, Volume 54, Issue 87, pp. 12322 - 12325
Hydrofunctionalizations of unsaturated hydrocarbons are key strategies for the synthesis of functionalized building blocks. Here, we report highly versatile... 
Z-SELECTIVE HYDROSILYLATION | ANTI-MARKOVNIKOV HYDROSILYLATION | TERMINAL ALKYNES | (Z)-SELECTIVE HYDROSILYLATION | INTERNAL ALKYNES | STEREOSELECTIVE HYDROSILYLATION | REGIOSELECTIVE HYDROSILYLATION | INTERMOLECULAR HYDROSILYLATION | CHEMISTRY, MULTIDISCIPLINARY | ALKENE HYDROSILYLATION | RUTHENIUM COMPLEX
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2016, Volume 55, Issue 36, pp. 10839 - 10843
A pyridinebis(oxazoline) cobalt complex is a very efficient precatalyst for the hydrosilylation of terminal alkynes with Ph2SiH2, providing α‐vinylsilanes with... 
hydrosilylation | cobalt | hydroboration | vinylsilanes | alkynes | MECHANISM | SILICON | C(SP)-H BORYLATION | TERMINAL ALKYNES | IRON CATALYSTS | COPPER(I)-CATALYZED REACTION | CHEMISTRY, MULTIDISCIPLINARY | METHYL-GROUP | RUTHENIUM COMPLEXES | STEREOSELECTIVE HYDROSILYLATION | ALKENE HYDROSILYLATION | Cobalt | Pyridine | Pyridines | Hydroboration | Catalysts | Regioselectivity | Hydrosilylation | Selectivity | Cobalt compounds | Alkynes
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2011, Volume 50, Issue 27, pp. 6004 - 6011
In the last decade, an increasing number of useful catalytic reductions of carboxylic acid derivatives with hydrosilanes have been developed. Notably, the... 
hydrosilylation | amides | esters | reduction | synthetic methods | SELF-ENCAPSULATION | TERTIARY-AMINES | SILANE REDUCTION | TRANSFER HYDROGENATION | CHEMISTRY, MULTIDISCIPLINARY | TRIRUTHENIUM CARBONYL CLUSTER | STEREOSELECTIVE HYDROSILYLATION | FACILE TRANSFORMATION | RUTHENIUM COMPLEX
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 12/2015, Volume 137, Issue 47, pp. 14830 - 14833
Copper-catalyzed highly efficient hydrosilylation reaction of enynoates was developed. Under simple reaction conditions, various di-, tri-, and... 
ACTIVATION | ASYMMETRIC-SYNTHESIS | KETENES | ENANTIOSELECTIVE SYNTHESIS | CHIRALITY TRANSFER | KINETIC RESOLUTION | 2,3-ALLENOATES | SI-B BOND | STEREOSELECTIVE-SYNTHESIS | ALLENES | CHEMISTRY, MULTIDISCIPLINARY | Silicon compounds | Research | Catalysis | Chemical properties | Chemical synthesis
Journal Article
ACS Catalysis, ISSN 2155-5435, 07/2018, Volume 8, Issue 7, pp. 5896 - 5900
We report a regioselective and stereoselective hydrosilylation of terminal alkynes with catalysts generated from bench-stable Co­(acac)2 and bisphoshpine... 
hydrosilylation | cobalt | homogeneous catalysis | vinylsilanes | alkynes | Z-SELECTIVE HYDROSILYLATION | ACTIVATION | HYDROSILOXANES | CHEMISTRY, PHYSICAL | RUTHENIUM COMPLEXES | REGIO | STEREOSELECTIVE HYDROSILYLATION | EFFICIENT | ALKENE HYDROSILYLATION | TERTIARY SILANES
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2016, Volume 55, Issue 23, pp. 6671 - 6675
Journal Article