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sulfamate esters (47) 47
chemistry, organic (40) 40
chemistry, multidisciplinary (29) 29
catalysis (21) 21
index medicus (20) 20
sulfamate (17) 17
amination (16) 16
stereoselective-synthesis (16) 16
enantioselective intramolecular amidation (14) 14
pharmacology & pharmacy (13) 13
sulfonic acids - chemistry (13) 13
c-h amination (12) 12
derivatives (11) 11
hydrolysis (11) 11
sulfamates (11) 11
chemistry, medicinal (10) 10
amines (9) 9
aminolysis (9) 9
aziridination (9) 9
humans (9) 9
nitrogen-atom-transfer (9) 9
amidation (8) 8
animals (8) 8
biochemistry & molecular biology (8) 8
chemical properties (8) 8
complexes (8) 8
esters (8) 8
molecular structure (8) 8
organic chemistry (8) 8
rhodium (8) 8
ruthenium porphyrins (8) 8
analysis (7) 7
efficient synthesis (7) 7
activation (6) 6
cancer (6) 6
chemistry, applied (6) 6
intramolecular amidation (6) 6
models, molecular (6) 6
sulfatase (6) 6
synthesis (6) 6
alkenes (5) 5
article (5) 5
c-h insertion (5) 5
carbon - chemistry (5) 5
carbonic-anhydrase inhibitors (5) 5
catalyst (5) 5
catalysts (5) 5
chemical sciences (5) 5
dirhodium (5) 5
estradiol - analogs & derivatives (5) 5
estrone sulfatase (5) 5
hydrogen bonding (5) 5
inhibitors (5) 5
kinetics (5) 5
ligands (5) 5
manganese porphyrins (5) 5
mechanism (5) 5
nickel (5) 5
potent inhibitors (5) 5
steroid sulfatase inhibitors (5) 5
structure-activity relationship (5) 5
sulfonamides (5) 5
sulfonamides - pharmacology (5) 5
[ chim.orga ] chemical sciences/organic chemistry (4) 4
alkene aziridination (4) 4
amines - chemistry (4) 4
antineoplastic agents - pharmacology (4) 4
aromatic compounds (4) 4
asymmetric catalysis (4) 4
breast cancer (4) 4
chemical synthesis (4) 4
chemistry (4) 4
chemistry, physical (4) 4
cyclic sulfamate (4) 4
design (4) 4
drug design (4) 4
enzyme inhibitors - pharmacology (4) 4
estrone-3-o-sulfamate (4) 4
facile entry (4) 4
female (4) 4
glycosyl amino-acids (4) 4
highly efficient (4) 4
homogeneous catalysis (4) 4
hydrogen - chemistry (4) 4
inhibitor (4) 4
insertion (4) 4
intermolecular amination (4) 4
n bond formation (4) 4
nucleophilic displacements (4) 4
olefin aziridination (4) 4
olefins (4) 4
organic-synthesis (4) 4
oxidation (4) 4
rate-determining step (4) 4
reaction mechanisms (4) 4
research (4) 4
ruthenium (4) 4
site-directed inhibition (4) 4
steroid sulfatase (4) 4
steryl-sulfatase - antagonists & inhibitors (4) 4
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Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 01/2011, Volume 9, Issue 2, pp. 523 - 530
The kinetics of hydrolysis at medium acid strength (pH interval 2-5) of a series of phenylsulfamate esters 1 have been studied and they have been found to... 
STEROID SULFATASE INHIBITORS | TRANSITION-STATE STRUCTURES | REACTION-RATES | IN-VIVO | CHEMISTRY, ORGANIC | SULFAMATE ESTERS | AMINOLYSIS | BASE-CATALYZED-HYDROLYSIS | CARBONIC-ANHYDRASE INHIBITORS | DEUTERIUM OXIDE | WATER | Hydrolysis | Sulfonic Acids - chemistry | Ions - chemistry | Molecular Structure | Esters - chemistry | Hydrogen-Ion Concentration
Journal Article
Heterocycles, ISSN 0385-5414, 2012, Volume 84, Issue 2, pp. 1313 - 1323
A family of ruthenium(II) 2,6-bis(imino)pyridyl complexes have been developed as a novel catalyst framework for C-H amination. Their synthesis and evaluation... 
C-H Amination | LIGANDS | Sulfamate Ester | CHEMISTRY, ORGANIC | Ruthenium Catalyst | Catalysis | CATALYTIC-ACTIVITY | 2,6-Bis(imino)pyridyl Ligand
Journal Article
Chemical Society Reviews, ISSN 0306-0012, 04/2011, Volume 40, Issue 4, pp. 1926 - 1936
Catalytic C-H amination has recently emerged as a unique tool for the synthesis of amines. This tutorial review highlights the existing protocols catalyzed by... 
INTRAMOLECULAR AMIDATION | CHLORAMINE-T | HYDROCARBONS | NITROGEN-ATOM-TRANSFER | MANGANESE PORPHYRINS | CHIRAL DIRHODIUM(II) CARBOXYLATES | SILYL ENOL ETHERS | BOND OXIDATION | SULFAMATE ESTERS | CHEMISTRY, MULTIDISCIPLINARY | ENANTIOSELECTIVE AMINATION | Organic chemistry | Chemical Sciences
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 08/2011, Volume 133, Issue 31, pp. 12264 - 12273
The mechanism of cobalt(II) porphyrin-catalyzed benzylic C–H bond amination of ethylbenzene, toluene, and 1,2,3,4-tetrahydronaphthalene (tetralin) using a... 
FNWI top publication | ASYMMETRIC CYCLOPROPANATION | COMPLEXES | AMIDATION | ALLYLIC AMINATION | SULFAMATE ESTERS | BOND FORMATION REACTIONS | OLEFIN AZIRIDINATION | ARYL AZIDES | BASIS-SETS | METAL | CHEMISTRY, MULTIDISCIPLINARY | Azides | Usage | Electron paramagnetic resonance spectroscopy | Analysis | Density functionals | Chemical properties | Hydrogen bonding | Porphyrins
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 12/2014, Volume 55, Issue 49, pp. 6658 - 6661
[Display omitted] Sequential replacement of imidazole from sulfonyldiimidazole by phenols and then amines leads to O-arylsulfamate esters. Application of this... 
N-methylation | Sulfatase | Sulfamate ester | Sulfonyldiimidazole | Drug conjugate | Sulfonyldiimidazole Drug conjugate Sulfamate ester N-methylation Sulfatase | DESIGN | MECHANISM | CHEMISTRY, ORGANIC | ARYL IMIDAZOLYLSULFONATES | PHENYL | STEROID SULFATASE INHIBITORS | PRODRUGS | ESTERS | WATER | Hydrolysis | Conjugates | Sex hormones | Amines | Phenols | Esters | Buffers | Steroids
Journal Article
Heterocycles, ISSN 0385-5414, 12/2006, Volume 69, Issue 1, pp. 527 - 537
The chiral dirhodium(II) carboxylate-catalyzed enantioselective intramolecular C-H amidation reaction of sulfamate esters via in situ generated iminoiodinanes... 
CHEMISTRY, ORGANIC | RUTHENIUM | INSERTION | AMINATION | STEREOSELECTIVE-SYNTHESIS | RH(II) CATALYST
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 10/2014, Volume 79, Issue 20, pp. 9799 - 9811
The reaction mechanisms and chemoselectivity on the intramolecular allylic C–H amination versus alkene aziridination of 4-pentenylsulfamate promoted by four... 
PORPHYRINS | BOND FUNCTIONALIZATION | AMIDATION | CHEMISTRY, ORGANIC | SULFAMATE ESTERS | RUTHENIUM | DENSITY-FUNCTIONAL THEORY | SELECTIVITY | EFFICIENT | INSERTIONS | INSIGHTS | Chemical properties | Rhodium | Hydrogen | Carbon compounds
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2007, Volume 129, Issue 3, pp. 562 - 568
Journal Article
Journal of Physical Organic Chemistry, ISSN 0894-3230, 04/2014, Volume 27, Issue 4, pp. 358 - 366
This work presents a linear correlation between bond length sensitivity (Δr/ΔpKlg) and effective charge by comparing a series of the following ROX compounds... 
phosphoryl | effective charge | sulfonyl | sulfuryl | bond length | correlation | LFER | ester | EVIDENCE CONSISTENT | HYDROLYSIS | CHEMISTRY, ORGANIC | CHEMISTRY, PHYSICAL | SULFAMATE ESTERS | TRANSITION-STATE | MECHANISMS | REACTIVITY CORRELATIONS | PHOSPHATE | OXYGEN | PHOSPHOROTHIOATE | SULFATE MONOESTERS | Phosphates | Sulfates | Esters
Journal Article
Organic Chemistry Frontiers, ISSN 2052-4110, 12/2017, Volume 4, Issue 12, pp. 2500 - 2521
Journal Article
Organic Letters, ISSN 1523-7060, 12/2006, Volume 8, Issue 26, pp. 6031 - 6034
A copper-catalyzed amidation of allylic and benzylic C−H bonds with both primary and secondary sulfonamides is described. The reaction is applicable to the... 
OXIDATION | ALKENES | RUTHENIUM PORPHYRINS | AMINATION | MANGANESE PORPHYRINS | AZIRIDINATION | COMPLEXES | ENANTIOSELECTIVE INTRAMOLECULAR AMIDATION | CHEMISTRY, ORGANIC | SULFAMATE ESTERS | CARBON-HYDROGEN BONDS | Amides - chemistry | Copper - chemistry | Catalysis
Journal Article
Synthesis, ISSN 0039-7881, 08/2013, Volume 45, Issue 15, pp. 2125 - 2133
Abstract A highly efficient asymmetric arylation of cyclic N -sulfonyl aldimines with arylboronic acids catalyzed by a rhodium/ sulfur­–olefin ligand complex... 
special topic | ligands | heterocycles | asymmetric catalysis | sulfamidates | boron | cyclization | arylation | rhodium | RUTHENIUM PORPHYRINS | ALPHA-KETOESTERS | CHEMISTRY, ORGANIC | SULFAMATE ESTERS | SULFONAMIDE MOIETIES | INTRAMOLECULAR AMIDATION | NUCLEOPHILIC DISPLACEMENTS | H BOND OXIDATION | AMINE DERIVATIVES | CONJUGATE ADDITIONS | SULFUR-OLEFIN LIGANDS
Journal Article
Tetrahedron, ISSN 0040-4020, 2006, Volume 62, Issue 49, pp. 11331 - 11342
Unique alkoxysulfonyl aziridine heterocycles were prepared through selective intra- and intermolecular alkene oxidation reactions. These methods are general... 
AZIRIDINE-1-CARBOXYLATES | MANGANESE PORPHYRINS | AMIDATION | CHEMISTRY, ORGANIC | SULFAMATE ESTERS | SULFONAMIDES | RUTHENIUM | BOND FORMATION REACTIONS | OLEFIN AZIRIDINATION | DERIVATIVES | C-H AMINATION | Heterocyclic compounds | Oxidation-reduction reaction | Monomers
Journal Article