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chemistry, organic (29) 29
sulfenate anions (29) 29
sulfoxides (15) 15
sulfoxide (12) 12
oxidation (11) 11
chemistry, multidisciplinary (10) 10
anions (9) 9
arylation (9) 9
organosulfur compounds (9) 9
alkylation (8) 8
enantioenriched sulfoxides (8) 8
palladium-catalyzed arylation (8) 8
sulfides (8) 8
aryl benzyl sulfoxides (7) 7
aryl sulfoxides (7) 7
enantioselective synthesis (7) 7
asymmetric-synthesis (6) 6
ligands (6) 6
sulfenates (6) 6
chemistry (5) 5
chemistry, inorganic & nuclear (5) 5
derivatives (5) 5
diaryl sulfoxides (5) 5
palladium (5) 5
sulfenate (5) 5
sulfoxid (5) 5
sulfur (5) 5
acid (4) 4
anion (4) 4
asymmetric catalysis (4) 4
catalysis (4) 4
chemistry, applied (4) 4
chemistry, physical (4) 4
chiral sulfoxides (4) 4
enantiomers (4) 4
allylic sulfoxides (3) 3
aromatic compounds (3) 3
asymmetric oxidation (3) 3
catalysts (3) 3
chemical synthesis (3) 3
coupling reactions (3) 3
enantiopure sulfoxides (3) 3
enantioselective arylation (3) 3
halides (3) 3
hydrogen-peroxide (3) 3
index medicus (3) 3
organic chemistry (3) 3
organic-synthesis (3) 3
photoredox catalysis (3) 3
reactivity (3) 3
substitution (3) 3
substrates (3) 3
sulfenate anion (3) 3
sulfones (3) 3
activation (2) 2
active sulfoxides (2) 2
alkenes (2) 2
alkenylation (2) 2
allyl sulfoxides (2) 2
alpha-arylation (2) 2
amination (2) 2
analysis (2) 2
aryl sulfenate anions (2) 2
arylierung (2) 2
benzaldehyde (2) 2
bond (2) 2
bond formation (2) 2
bonding (2) 2
c-h activation (2) 2
catalyzed asymmetric sulfinylzincation (2) 2
catalyzed enantioselective arylation (2) 2
chemical properties (2) 2
complexes (2) 2
copper (2) 2
cross-coupling (2) 2
cross-coupling reactions (2) 2
diastereoselective alkylation (2) 2
diastereoselectivity (2) 2
diphenylethylene (2) 2
electron transfer (2) 2
electron transport (2) 2
enantio-selectivity (2) 2
enantioselektivität (2) 2
esomeprazole (2) 2
functionalisation (2) 2
functionalization (2) 2
funktionalisierung (2) 2
halogenid (2) 2
halogenides (2) 2
heterocycles (2) 2
hydrobenzoin (2) 2
letter (2) 2
ligand (2) 2
mechanisms (2) 2
metal-free conditions (2) 2
mislow-evans rearrangement (2) 2
models, molecular (2) 2
molecular-oxygen (2) 2
nuclear magnetic resonance (2) 2
olefins (2) 2
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Angewandte Chemie International Edition, ISSN 1433-7851, 09/2014, Volume 53, Issue 40, pp. 10755 - 10758
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 03/2018, Volume 360, Issue 6, pp. 1123 - 1127
A method for the construction of sulfinamides via the copper‐catalyzed electrophilic amination of sulfenate anions using N‐benzoyloxyamines as the amination... 
copper | N-benzoyloxyamine | sulfinamide | electrophilic amidation | sulfenate anion | ASYMMETRIC-SYNTHESIS | ARYL BENZYL SULFOXIDES | ARYLATION | ALLYLIC ALKYLATION | CHEMISTRY, ORGANIC | TERT-BUTYL SULFOXIDES | THIOOXIME S-OXIDES | DIARYL SULFOXIDES | CHIRAL SULFOXIDES | CHEMISTRY, APPLIED | EFFICIENT | SULFINYL KETIMINES | Copper | Esters | Anions | Chemical synthesis | Construction methods | Reagents
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 01/2019, Volume 2019, Issue 2-3, pp. 519 - 526
Sulfenic acid anions (RSO–) represent an untapped functional group for the formation of sulfoxides and other organic compounds. Their stereoselective... 
Sulfenates | Computational chemistry | Density functional calculations | Organosulfur compounds | Diastereoselectivity | OXIDATION | COMPLEX | STABLE SULFENIC ACID | CHEMISTRY, ORGANIC | SULFOXIDES | PHASE | THIOL | ORGANOCATALYSTS | CATALYZED ENANTIOSELECTIVE ARYLATION | CHEMISTRY | INSIGHTS
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 04/2018, Volume 360, Issue 8, pp. 1685 - 1692
A new organocatalyst, the selenolate anion [RSe]–, generated from bench‐stable and commercially available diphenyl diselenide or from phenyl benzyl selenide... 
Substrate | Screening | Selenium | Organocatalyst | Selenolate anion | ARYL BENZYL SULFOXIDES | SULFENATE ANIONS | EFFICIENT SYNTHESIS | CHEMISTRY, ORGANIC | N-CHLOROSUCCINIMIDE | ALKENES | DIHYDROXYLATION | AMINATION | ORGANOSELENIUM-CATALYZED SYNTHESIS | CHEMISTRY, APPLIED | SELENIUM-CATALYSIS | CHLORINATION | Anions
Journal Article
Organic Letters, ISSN 1523-7060, 08/2011, Volume 13, Issue 16, pp. 4192 - 4195
A series of Boc-protected β-amino sulfoxides were prepared by the reaction of arenesulfenate anions with chiral Boc-protected β-amino iodides. The... 
ASYMMETRIC-SYNTHESIS | ENANTIOSELECTIVE SYNTHESIS | SULFENATE ANIONS | ENANTIOENRICHED SULFOXIDES | PALLADIUM-CATALYZED ARYLATION | CHEMISTRY, ORGANIC | CHIRAL SULFUR LIGANDS | ARYL SULFOXIDES | BETA-AMINO SULFOXIDES | STEREOSELECTIVE-SYNTHESIS | HIV-PROTEASE INHIBITOR
Journal Article
Phosphorus, Sulfur, and Silicon and the Related Elements, ISSN 1042-6507, 07/2019, Volume 194, Issue 7, pp. 692 - 697
Selected sulfenate anions can be alkylated with diastereoselectivities near 9:1 when there is appropriately positioned carbon chirality in the sulfenate... 
Sulfenate anion | alkylation | computations | stereoselection | pyrrolidines | SULFOXIDES | CATALYZED ENANTIOSELECTIVE ARYLATION | CHEMISTRY, ORGANIC | ACCESS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Phosphorus, Sulfur, and Silicon and the Related Elements, ISSN 1042-6507, 04/2013, Volume 188, Issue 4, pp. 275 - 286
Sulfenates, the conjugate bases of sulfenic acids are nucleophilic species that can be alkylated at sulfur to create sulfoxides. Sulfenates are generally not... 
Sulfenates | sulfur nucleophile | alkylation | diastereoselection | CATALYZED ASYMMETRIC SULFINYLZINCATION | SUBSTITUTION | ENANTIOENRICHED SULFOXIDES | CHEMISTRY, ORGANIC | IONS | SALTS | CHEMISTRY, INORGANIC & NUCLEAR | DIASTEREOSELECTIVE ALKYLATION | ARENESULFENATE ANIONS | GENERATION | BOND | DERIVATIVES
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 1900, Volume 137, Issue 32, pp. 10346 - 10350
Carbon–carbon triple bonds of alkynes are ubiquitous. They serve as valuable starting materials that can be transformed into a vast array of diverse materials,... 
OXIDATION | REARRANGEMENT | HETEROCYCLES | ACID BEARING | ARYL BENZYL SULFOXIDES | SULFENATE ANIONS | ARYLATION | REACTIVITY | CHEMISTRY, MULTIDISCIPLINARY | CYCLIZATION | METATHESIS | Chemical bonds | Usage | Metal catalysts | Analysis
Journal Article
Tetrahedron, ISSN 0040-4020, 07/2016, Volume 72, Issue 27-28, pp. 4068 - 4075
The K CO -mediated benzylation of β-ketosulfoxides with 2.0 equiv of benzylic halides affords benzylic arylsulfoxides in moderate yields along with trace... 
Sulfenate anion | Benzylic halides | β-Ketosulfoxides | beta-Ketosulfoxides | ESOMEPRAZOLE | ENANTIOSELECTIVE SYNTHESIS | SULFIDES | ALKYLATION | SULFENATE ANIONS | CHEMISTRY, ORGANIC | ARYL SULFOXIDES | ASYMMETRIC OXIDATION | DIARYL SULFOXIDES | PALLADIUM-CATALYZED ARYLATION | ALLYL SULFOXIDES | Tetrahedrons | Anions | Halides | Bonding
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 2003, Volume 44, Issue 33, pp. 6293 - 6296
Methyl acrylate esters bearing alkane- and arenesulfinyl units on the 2-carbon liberate sulfenate anions upon nucleophilic attack. The sulfenates are readily... 
alkylation | sulfenate | sulfinylcysteine | sulfoxide | Sulfoxide | Sulfinylcysteine | Sulfenate | Alkylation | OXIDATION | SUBSTITUTION | ACID | EPISULFOXIDES | OXYGENATION | SULFENATE ANIONS | CHEMISTRY, ORGANIC | SULFOXIDES | THIOLS | CATALYTIC-ACTIVITY | DERIVATIVES
Journal Article
Synthesis, ISSN 0039-7881, 5/2007, Volume 2007, Issue 9, pp. 1315 - 1324
Abstract The present report describes the novel and smooth generation of sulfenate salts by fluoride-mediated cleavage of 2-(tri­methylsilyl)ethyl sulfoxides.... 
paper | Sulfoxides | Silicon | Sulfenate salts | Fluorine | Alkylation | OXIDATION | SELF-ASSEMBLED MONOLAYERS | sulfenate salts | SULFIDES | ENANTIOENRICHED SULFOXIDES | CHEMISTRY, ORGANIC | MOLECULES | ALCOHOLS | silicon | DIASTEREOSELECTIVE ALKYLATION | PROTECTING GROUP | PD-CATALYZED SULFINYLZINCATION | alkylation | SELECTIVE SYNTHESIS | sulfoxides | fluorine
Journal Article
Journal of Sulfur Chemistry, ISSN 1741-5993, 04/2004, Volume 25, Issue 2-3, pp. 183 - 211
A comprehensive review of recent chemistry of sulfenate anions is presented. Compound structure, methods of generation and reaction of sulfenates are all... 
Sulfur acids | Theoretical chemistry | Sulfenate | Alkylation | S-O bond | Sulfenic acid
Journal Article
Organic Letters, ISSN 1523-7060, 02/2018, Volume 20, Issue 3, pp. 764 - 767
An efficient one-pot approach for the synthesis of diaryl sulfoxides and diaryl sulfones using aryl thiols and aryl diazonium salts was developed. The use of a... 
OXIDATION | ORGANIC-SYNTHESIS | ARYLATIONS | SINGLET MOLECULAR-OXYGEN | SULFIDES | REVERSE-TRANSCRIPTASE | SULFENATE ANIONS | COMPLEXES | CHEMISTRY, ORGANIC | PYRROLYL ARYL SULFONES | PHOTOREDOX CATALYSIS
Journal Article
Organic Letters, ISSN 1523-7060, 05/2018, Volume 20, Issue 9, pp. 2522 - 2525
A palladium-catalyzed direct arylation of (3-thiophene)­S­(O)­Me derivatives has been developed. This protocol is effective for the selective synthesis of... 
FUNCTIONALIZATION | SULFOXIDES | INHIBITION | BOND ARYLATION | COUPLING REACTIONS | SUBSTITUENTS | ARYL SULFENATE ANIONS | CHEMISTRY, ORGANIC | DISCOVERY | THIOPHENE DERIVATIVES
Journal Article
Canadian Journal of Chemistry, ISSN 0008-4042, 09/2005, Volume 83, Issue 9, pp. 1473 - 1482
Journal Article
Accounts of Chemical Research, ISSN 0001-4842, 04/2017, Volume 50, Issue 4, pp. 842 - 856
Catalysts accelerate biological processes and organic reactions in a controlled and selective fashion. There are continuing efforts in asymmetric catalysis to... 
ASYMMETRIC CATALYSIS | MICHAEL REACTION | OXIDATION | SULFOXIDES | CHIRAL BICYCLIC GUANIDINE | VINYL SULFONE | ENANTIOSELECTIVE SYNTHESIS | SULFENATE ANIONS | 30-PERCENT HYDROGEN-PEROXIDE | CHEMISTRY, MULTIDISCIPLINARY | MOLECULAR-OXYGEN
Journal Article
Organic Letters, ISSN 1523-7060, 03/2015, Volume 17, Issue 5, pp. 1168 - 1171
Diaryl sulfoxides are synthesized from aryl benzyl sulfoxides and aryl chlorides via three sequential catalytic cycles all promoted by a NiXantPhos-based... 
HALIDES | CROSS-COUPLING REACTIONS | PRECATALYSTS | LIGANDS | ALPHA-ARYLATION | SULFENATE ANIONS | COMPLEXES | CHEMISTRY, ORGANIC | BOND FORMATION | OLEFINS | COPPER
Journal Article
ACS Catalysis, ISSN 2155-5435, 11/2017, Volume 7, Issue 11, pp. 7587 - 7592
Sulfoxides and sulfides are two important functional groups in organic molecules, containing different valence states of sulfur. Both sulfoxidation and... 
energy transfer | sulfoxidation | sulfenylation | electron transfer | photocatalysis | SULFENATE ANIONS | CHEMISTRY, PHYSICAL | ARYL SULFOXIDES | SULFUR | VISIBLE-LIGHT | S BOND FORMATION | COUPLING REACTION | PALLADIUM-CATALYZED ARYLATION | LIGHT PHOTOREDOX CATALYSIS | SINGLET-OXYGEN | MOLECULAR-OXYGEN
Journal Article
Organic Letters, ISSN 1523-7060, 04/2018, Volume 20, Issue 7, pp. 2076 - 2079
A copper-catalyzed sulfoxidation of benzylic C–H bonds by nondirected oxidative C­(sp3)-H activation was developed. The process proceeds via sulfenate anions,... 
N-FLUOROBENZENESULFONIMIDE | ASYMMETRIC CATALYSIS | DIARYL SULFOXIDES | METAL-FREE CONDITIONS | ENANTIOSELECTIVE SYNTHESIS | COUPLING REACTIONS | SULFENATE ANIONS | C(SP)-H ACTIVATION | CHEMISTRY, ORGANIC | ARYL SULFOXIDES | PHOTOREDOX CATALYSIS
Journal Article
Tetrahedron, ISSN 0040-4020, 04/2019, Volume 75, Issue 16, pp. 2406 - 2412
A fruitful switch from -butyl to cumene hydroperoxide was able to overcome a difficulty arose in the enantioselective oxidation of fluorinated aryl benzyl... 
Sulfoxide | Catalysis | Hydrobenzoin | Oxidation mechanism | Circular dichroism | SUBSTITUTION | ASYMMETRIC-SYNTHESIS | PHASE-TRANSFER | SULFENATE ANIONS | ARYLATION | RESOLUTION | CHEMISTRY, ORGANIC | CHIRAL SULFOXIDES | Sulfides | Oxidation-reduction reaction | Enantiomers | Organosulfur compounds
Journal Article
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