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sulfonylmethyl isocyanides (68) 68
chemistry (50) 50
chemistry, organic (44) 44
tosylmethyl isocyanide (14) 14
chemistry, multidisciplinary (13) 13
pyrroles (12) 12
efficient synthesis (10) 10
cycloaddition (9) 9
imidazoles (9) 9
alpha-metalated isocyanides (8) 8
michael acceptors (7) 7
derivatives (5) 5
electrocyclic ring-closure (5) 5
index medicus (5) 5
molecular structure (5) 5
potent (5) 5
acids (4) 4
asymmetric aldol reaction (4) 4
cyanides - chemistry (4) 4
heterocycles (4) 4
k ee chemistry, organic (4) 4
one-pot synthesis (4) 4
organic-synthesis (4) 4
paper (4) 4
pharmacology & pharmacy (4) 4
substituted pyrroles (4) 4
1,3-dipolar cycloaddition (3) 3
aldehydes (3) 3
alkaloids (3) 3
chiral sulfonylmethyl isocyanides (3) 3
efficient (3) 3
isocyanides (3) 3
k dy chemistry (3) 3
p-toluenesulfonylmethyl isocyanide (3) 3
pyrroles - chemical synthesis (3) 3
pyrroles - chemistry (3) 3
reagents (3) 3
regioselective synthesis (3) 3
selective ketone pyrolysis (3) 3
synthesis (3) 3
tosmic (3) 3
trisubstituted olefins (3) 3
3-arylpyrroles (2) 2
3-substituted pyrroles (2) 2
acid (2) 2
agriculture (2) 2
amino-acids (2) 2
asymmetric induction (2) 2
base-induced cycloaddition (2) 2
carbonyl-compounds (2) 2
catalysis (2) 2
catalyzed reaction (2) 2
chemistry, applied (2) 2
chemistry, medicinal (2) 2
chiral ferrocenylphosphine-gold complex (2) 2
chiral heterocycle (2) 2
conformation (2) 2
cyclisation (2) 2
cyclization (2) 2
enantioselective synthesis (2) 2
highly regioselective synthesis (2) 2
humans (2) 2
imidazole (2) 2
imidazoles - chemical synthesis (2) 2
inhibitors (2) 2
intermolecular cyclization (2) 2
isocyanide (2) 2
letter (2) 2
ligands (2) 2
metacyclophanes (2) 2
molybdenum (2) 2
multicomponent reaction (2) 2
nitriles (2) 2
nitroalkenes (2) 2
olefins (2) 2
oligosubstituted pyrroles (2) 2
pyrrolylimido complexes (2) 2
research (2) 2
rings (2) 2
route (2) 2
stereoselective synthesis (2) 2
substituents (2) 2
synthetic reactions (2) 2
system (2) 2
-l-histidine, (1) 1
-marinopyrrole (1) 1
1,3-dicarbonyl compounds (1) 1
1,3-dithiane derivatives (1) 1
1,3′-bipyrrole (1) 1
1,5-disubstituted imidazole (1) 1
1,5-disubstituted imidazoles (1) 1
1.3'-bipyrrole (1) 1
2,3,4-trisubstituted pyrroles (1) 1
2,5-disubstituted derivatives (1) 1
2-acylchromeno[3,4-c]pyrrol-4-one (1) 1
2-acylchromeno[34- c ]pyrrol-4-one (1) 1
21-fluoro-16-alpha-ethyl-19-norprogesterone (1) 1
2h-chromenes (1) 1
3,4-disubstituted pyrroles (1) 1
3-alkanoyl-4-nitropyrroles (1) 1
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Angewandte Chemie International Edition, ISSN 1433-7851, 09/2005, Volume 44, Issue 35, pp. 5664 - 5667
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2017, Volume 56, Issue 15, pp. 4310 - 4313
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 11/2013, Volume 11, Issue 42, pp. 7393 - 7399
A new reaction model, tandem Michael addition/formal isocyanide insertion into the acyl C-C bond, has been developed. Thus, a series of 2-acylpyrroles and... 
TOSYLMETHYL ISOCYANIDE | CATALYZED 3-COMPONENT REACTION | COMPLEX CATALYST | OLIGOSUBSTITUTED PYRROLES | SYNTHETIC REACTIONS | SULFONYLMETHYL ISOCYANIDES | REGIOSELECTIVE SYNTHESIS | CHEMISTRY, ORGANIC | TERMINAL ALKYNES | ISOCYANIDE INSERTION | H ACTIVATION
Journal Article
by Geng, X and Wang, C and Huang, C and Bao, Y and Zhao, P and Zhou, Y and Wu, YD and Feng, LL and Feng, AX
ORGANIC LETTERS, ISSN 1523-7060, 01/2020, Volume 22, Issue 1, pp. 140 - 144
We report an I-2/FeCl3-co-promoted formal [2 + 2+1] annulation of aryl methyl ketones, 2-aminobenzyl alcohols, and p-toluenesulfonylmethyl isocyanide (TosMIC)... 
TOSYLMETHYL ISOCYANIDE | METHYLENE ISOCYANIDES | CYCLOADDITION | ONE-POT SYNTHESIS | SULFONYLMETHYL ISOCYANIDES | CHEMISTRY, ORGANIC | TANDEM REACTION | P-TOLUENESULFONYLMETHYL ISOCYANIDE | DERIVATIVES TOTAL-SYNTHESIS | ALDOL-TYPE CONDENSATION | DUAL ROLES
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 2012, Volume 53, Issue 4, pp. 446 - 448
A novel and effective route for the synthesis of 1,3′-bipyrrole derivatives by multisubstituted olefins with TosMIC was developed. Moreover, the synthetic... 
1,3′-Bipyrrole | Toluenesulfonyl-methyl isocyanide (TosMIC) | Trisubstituted olefins | (+/-)-MARINOPYRROLE | Toluenesulfonyl-methyl isocyanide | 3-NITROPYRROLES | TosMIC | SULFONYLMETHYL ISOCYANIDES | CHEMISTRY | CHEMISTRY, ORGANIC | PYRROLES | MARINOPYRROLE | 1.3'-Bipyrrole | Olefins
Journal Article
Synlett, ISSN 0936-5214, 2/2005, Volume 2005, Issue 2, pp. 363 - 364
(A) Most ketones are converted in one operation into cyanides with TosMIC in the presence of potassium tert-butoxide in non-protic solvents (DME, DMSO).(2) The... 
spotlight | TOSYLMETHYL ISOCYANIDE | SULFONYLMETHYL ISOCYANIDES | CHEMISTRY | CHEMISTRY, ORGANIC | NITRILES | ONE-CARBON UNIT
Journal Article
New Journal of Chemistry, ISSN 1144-0546, 06/2015, Volume 39, Issue 6, pp. 4631 - 4639
A copper catalyzed regioselective synthesis of 2,3,4-trisubstituted 1H-pyrroles using a novel three-component coupled domino reaction of aldehydes, ketones and... 
TOSYLMETHYL ISOCYANIDE | SOLID-SUPPORTED REAGENTS | ASYMMETRIC ALDOL REACTION | CLEAVAGE FACILE SYNTHESIS | ONE-POT SYNTHESIS | SUBSTITUTED PYRROLES | SULFONYLMETHYL ISOCYANIDES | CHEMISTRY, MULTIDISCIPLINARY | ALPHA-METALATED ISOCYANIDES | HIGHLY EFFICIENT | PYRROLE-IMIDAZOLE ALKALOIDS
Journal Article
Canadian Journal of Chemistry, ISSN 0008-4042, 02/2012, Volume 90, Issue 2, pp. 214 - 221
Journal Article
Synlett, ISSN 0936-5214, 10/2013, Volume 24, Issue 16, pp. 2124 - 2126
Journal Article
Organic Letters, ISSN 1523-7060, 10/2002, Volume 4, Issue 20, pp. 3537 - 3539
A one-step synthesis of 3-aryl and 3,4-diaryl-(1H)-pyrroles from TOSMIC and commercially available or readily synthesized arylalkenes is reported. Optimal... 
SULFONYLMETHYL ISOCYANIDES | CHEMISTRY | CHEMISTRY, ORGANIC | 3-ARYLPYRROLES | PYRROLES | Porphyrins - chemical synthesis | Pyrroles - chemistry | Molecular Structure | Pyrroles - chemical synthesis | Cyanides - chemistry | Porphyrins - chemistry
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 06/2005, Volume 70, Issue 12, pp. 4879 - 4882
An efficient synthesis of substituted azolopyrimidines such as pyrido[3‘,2‘:4,5]pyrrolo[1,2-c]pyrimidines, pyrimido[1,6-a]indoles,... 
PHASE-TRANSFER-CATALYSIS | ION INITIATED REACTIONS | SULFONYLMETHYL ISOCYANIDES | CHEMISTRY | CHEMISTRY, ORGANIC | SPONGE KIRKPATRICKIA-VARIALOSA | MICHAEL ACCEPTORS | IMIDAZOLES | BASE-INDUCED CYCLOADDITION | IMIDOYL CHLORIDES | ALKALOIDS
Journal Article
Journal of Organic Chemistry, ISSN 0022-3263, 08/1998, Volume 63, Issue 16, pp. 5332 - 5338
A series of 2-(trimethylstannyl)pyrroles 3, with substituents at the 3- and 4-positions, is synthesized efficiently by a base-induced reaction of stannylated... 
HALIDES | COUPLING REACTION | SULFONYLMETHYL ISOCYANIDES | EFFICIENT SYNTHESIS | CHEMISTRY | PYRROLES | ARYL | BASE-INDUCED CYCLOADDITION | INDOLES | CHEMISTRY, ORGANIC
Journal Article
Synlett, ISSN 0936-5214, 02/2011, Volume 2011, Issue 3, pp. 308 - 310
Abstract A simple synthesis of 2-imino-3-aminobenzofurans was developed based on multicomponent reactions from P-toluenesulfonylmethylisocyanide,... 
letter | multicomponent reactions | imines | furans | TosMIC | isocyanide | HETEROCYCLES | SULFONYLMETHYL ISOCYANIDES | CHEMISTRY | CHEMISTRY, ORGANIC | DERIVATIVES | SECONDARY AMINE
Journal Article
Synthesis, ISSN 0039-7881, 11/2004, Volume 2004, Issue 16, pp. 2697 - 2703
Abstract Reaction of 1,4-benzodiazepinic N-nitrosoamidines, used as synthetic equivalents of imidoyl chlorides, with the mono-anion of tosylmethyl isocyanide... 
paper | Reductions | Heterocycles | Cyclizations | Isocyanides | Benzodiazepines | ANTI-DEPRESSANT ACTIVITY | benzodiazepines | IMIDAZO<1,5-A><1,4>BENZODIAZEPINES | reductions | CHEMISTRY, ORGANIC | TOSMIC REAGENT | PAUSON-KHAND REACTIONS | ANTIANXIETY | cyclizations | isocyanides | POTENT | heterocycles | OXYTOCIN ANTAGONIST | SULFONYLMETHYL ISOCYANIDES | GPIIB/IIIA RECEPTOR ANTAGONIST | QUINAZOLINES
Journal Article
Tetrahedron, ISSN 0040-4020, 1997, Volume 53, Issue 33, pp. 11355 - 11368
4(5)-Monosubstituted imidazoles ( 9) have been prepared via base-induced cycloaddition of tosylmethyl isocyanide (TosMIC) to N-(dimethylsulfamoyl)aldimines (... 
SULFONYLMETHYL ISOCYANIDES | CHEMISTRY | CHEMISTRY, ORGANIC | K EE CHEMISTRY, ORGANIC
Journal Article
Synthesis, ISSN 0039-7881, 1993, Volume 1993, Issue 1, pp. 45 - 47
Alpha-morpholinobenzyl isocyanide and three 1-(aryl]or alkyl]thio)alkyl isocyanides are synthesized in good yields by the dehydration of... 
short paper | AMIDOALKYLATION REAGENTS | CHEMISTRY | CHEMISTRY, ORGANIC | ACIDS | CHIRAL SULFONYLMETHYL ISOCYANIDES | ASYMMETRIC INDUCTION
Journal Article
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