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1. Full Text Palladium/PC-Phos-Catalyzed Enantioselective Arylation of General Sulfenate Anions: Scope and Synthetic Applications
by Wang, Lei and Chen, Mingjie and Zhang, Peichao and Li, Wenbo and Zhang, Junliang
Journal of the American Chemical Society, ISSN 0002-7863, 03/2018, Volume 140, Issue 9, pp. 3467 - 3473
Herein we reported an efficient palladium-catalyzed enantioselective arylation of both alkyl and aryl sulfenate anions to deliver various chiral sulfoxides in... 
DIARYL SULFOXIDES | ION-PAIR | LIGANDS | AQUEOUS HYDROGEN-PEROXIDE | ARYL BENZYL SULFOXIDES | ENANTIOENRICHED SULFOXIDES | PROTON PUMP INHIBITORS | CHIRAL SULFOXIDES | CHEMISTRY, MULTIDISCIPLINARY | ASYMMETRIC SULFIDE OXIDATION | ACTIVE SULFOXIDES | Palladium catalysts | Arylation | Usage | Anions | Chemical properties
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2. Full Text Facile Synthesis of Stereodefined α-Iodovinyl Sulfoxides, Versatile Platform to Trisubstituted Olefins
by Jung, Sunna and Ueda, Yasuyuki and Suzuki, Keisuke and Ohmori, Ken
Synlett, ISSN 0936-5214, 08/2016, Volume 27, Issue 13, pp. 2024 - 2028
Abstract Stereodefined α-iodovinyl sulfoxides bearing a sulfinyl group and an iodo group were prepared by a one-pot iodination/Horner–Wadsworth–Emmons reaction... 
letter | vinyl sulfoxides | Horner-Wadsworth-Emmons reaction | sulfinyl phosphonates | trisubstituted olefins | sulfoxides | vinyl iodide | halovinyl sulfoxides | olefination | CHEMISTRY, ORGANIC | PHOSPHORYL SULFOXIDES | VINYL | REARRANGEMENT | CYCLIC SULFITES | 1-CHLOROVINYL SULFOXIDES | PARA-TOLYL SULFOXIDE | 1-HALOVINYL SULFOXIDES | MAGNESIUM ALKYLIDENE CARBENOIDS | ALPHA,BETA-UNSATURATED SULFOXIDES | GRIGNARD-REAGENTS
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3. Full Text Prochiral Diheteroaryl Sulfoxides and Their Reactions with (S)-Li-2-BINOLate-Activated Diisobutylmagnesium
by Ruppenthal, S and Bruckner, R
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, ISSN 1434-193X, 01/2018, Issue 1, pp. 89 - 98
5-Membered ring heterocycles were -lithiated or -magnesiated so that they attacked SOCl2 or SO(OMe)(2) forming symmetric - i.e. prochiral - diheteroaryl... 
Heterocycles | ROUTE | Enantioselectivity | Desymmetrization | LIGAND-EXCHANGE | CHEMISTRY, ORGANIC | Sulfoxides | ENANTIOPURE SULFOXIDES | ASYMMETRIC OXIDATION | ARYL ALKYL | DIARYL SULFOXIDES | DIALKYL SULFOXIDES | CONVENIENT PREPARATION | CHIRAL SULFOXIDES | Exchange interactions | GRIGNARD-REAGENTS
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4. Full Text One-Pot Sulfoxide Synthesis Exploiting a Sulfinyl-Dication Equivalent Generated from a DABSO/Trimethylsilyl Chloride Sequence
by Lenstra, Danny C and Vedovato, Vincent and Ferrer Flegeau, Emmanuel and Maydom, Jonathan and Willis, Michael C
Organic Letters, ISSN 1523-7060, 05/2016, Volume 18, Issue 9, pp. 2086 - 2089
A one-pot process for the synthesis of unsymmetrical sulfoxides using organometallic nucleophiles is described. Sulfur dioxide, delivered from the surrogate... 
3-COMPONENT SYNTHESIS | DIARYL SULFOXIDES | ASYMMETRIC-SYNTHESIS | BIS-SULFOXIDE | SULFONE SYNTHESIS | ARYL HALIDES | SULFUR-DIOXIDE SURROGATE | CHEMISTRY, ORGANIC | PALLADIUM-CATALYZED AMINOSULFONYLATION | CHIRAL SULFOXIDES | ACTIVE SULFOXIDES
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5. Full Text Visible‐Light‐Accelerated C−H Sulfinylation of Heteroarenes
by Meyer, Andreas Uwe and Wimmer, Alexander and König, Burkhard
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2017, Volume 56, Issue 1, pp. 409 - 412
Heteroaromatic sulfoxides are a frequent structural motif in natural products, drugs, catalysts, and materials. We report a metal‐free... 
Friedel–Crafts reaction | sulfinylation | visible light | metal-free conditions | sulfoxide | ASYMMETRIC CATALYSIS | TRANSITION-METAL CATALYSIS | ENANTIOSELECTIVE SYNTHESIS | ARYL BENZYL SULFOXIDES | SULFENATE ANIONS | ENANTIOENRICHED SULFOXIDES | CHEMISTRY, MULTIDISCIPLINARY | PHOTOREDOX CATALYSIS | DIARYL SULFOXIDES | PALLADIUM-CATALYZED ARYLATION | NUCLEOPHILIC REACTIVITIES | Friedel-Crafts reaction | Substitution reactions | Organosulfur compounds | Light irradiation | Catalysts | Natural products | Pyrroles | Radiation | Irradiation | Sulfoxides | Indoles | Nucleophiles | Chemical synthesis | Substrates
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6. Full Text Diastereoselective Synthesis of Enantiopure Acyclic β,β′-Disubstituted Vinylsulfoxides
by Brebion, Franck and Goddard, Jean-Philippe and Fensterbank, Louis and Malacria, Max
Organic Letters, ISSN 1523-7060, 05/2008, Volume 10, Issue 10, pp. 1917 - 1920
Thermal elimination of sulfenic acid from enantiopure β,β′-disubstituted bis-sulfoxides allows the stereoselective synthesis of enantiopure acyclic... 
ASYMMETRIC-SYNTHESIS | VINYL SULFOXIDES | 1,3-DIPOLAR CYCLOADDITION | BETA-ELIMINATION | ACETYLENIC SULFOXIDES | CHEMISTRY, ORGANIC | BIS-SULFOXIDES | CHIRAL SULFOXIDES | ALKYL SULFOXIDES | 1-ALKYNYL SULFOXIDES | CONJUGATE ADDITION | Sulfoxides - chemistry | Sulfoxides - chemical synthesis | Temperature | Stereoisomerism | Molecular Conformation
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7. Full Text Studies on the diastereoselective oxidation of 1-thio-β-D-glucopyranosides: Synthesis of the usually less favoured R S sulfoxide as a single diastereoisomer
by Moya-López, Juan Francisco and Elhalem, Eleonora and Recio, Rocío and Álvarez, Eleuterio and Fernández, Inmaculada and Khiar, Noureddine
Organic and Biomolecular Chemistry, ISSN 1477-0520, 02/2015, Volume 13, Issue 6, pp. 1904 - 1914
A detailed study on the diastereoselective oxidation of 1-thio-beta-D-glucopyranosides is reported. It has been shown that the sense and the degree of... 
GLYCOSYL SULFOXIDES | BETA-MANNOPYRANOSIDES | XYLOPYRANOSYL SULFOXIDE | ABSOLUTE-CONFIGURATION | CONFORMATIONAL PROPERTIES | CHEMISTRY, ORGANIC | BIS-SULFOXIDES | SULFUR | CHIRAL SULFOXIDES | ASYMMETRIC ALLYLATION | ENANTIOPURE SULFOXIDES
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8. Full Text An attempt for fast separation of enantiomers in nano‐liquid chromatography and capillary electrochromatography
by D'Orazio, Giovanni and Kakava, Rusudan and Volonterio, Alessandro and Fanali, Salvatore and Chankvetadze, Bezhan
ELECTROPHORESIS, ISSN 0173-0835, 08/2017, Volume 38, Issue 15, pp. 1932 - 1938
In the present study, an attempt was made to achieve separation of enantiomers within a minute in nano‐LC and CEC. In order to achieve this goal several... 
CEC | Sulfoxides | Fast enantioseparation | Chiral | Nano‐LC | Nano-LC | CORE-SHELL | CHEMISTRY, ANALYTICAL | PARTICLES | CHIRAL STATIONARY PHASES | PERFORMANCE | BIOCHEMICAL RESEARCH METHODS | CELLULOSE | Sulfoxides - chemistry | Models, Chemical | Time Factors | Nanotechnology - methods | Stereoisomerism | Sulfoxides - analysis | Sulfoxides - isolation & purification | Capillary Electrochromatography - methods | Chromatography, Liquid - methods | Enantiomers | Analysis | Liquid chromatography | Separation | Barriers | Scientific apparatus & instruments | Electrochromatography
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9. Full Text Onions—A global benefit to health
by Griffiths, Gareth and Trueman, Laurence and Crowther, Timothy and Thomas, Brian and Smith, Brian
Phytotherapy Research, ISSN 0951-418X, 11/2002, Volume 16, Issue 7, pp. 603 - 615
Onion (Allium cepa L.) is botanically included in the Liliaceae and species are found across a wide range of latitudes and altitudes in Europe, Asia, N.... 
Allium cepa | quercetin | cysteine sulphoxides | flavonoids | health benefits | Allium sativum | Flavonoids | Cysteine sulphoxides | Quercetin | Health benefits | CHEMISTRY, MEDICINAL | ALLIUM-CEPA L | MACERATED GARLIC EXTRACT | DRUG-METABOLIZING-ENZYMES | WELSH ONION | SULFOXIDES FLAVOR PRECURSORS | S-ALK(EN)YL-L-CYSTEINE SULFOXIDES | ORGANOSULFUR COMPOUNDS | IN-VITRO | CYSTEINE SULFOXIDES | ANTIPLATELET ACTIVITY | PHARMACOLOGY & PHARMACY | Plant Extracts - chemistry | Quercetin - chemistry | Global Health | Quercetin - therapeutic use | Humans | Onions - chemistry | Flavonoids - therapeutic use | Sulfoxides - chemistry | Onions - growth & development | Sulfoxides - therapeutic use | Phytotherapy | Flavonoids - chemistry | Plant Extracts - therapeutic use
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10. Full Text Direct Synthesis of Sulfinamides by the Copper‐Catalyzed Electrophilic Amidation of Sulfenate Anions
by Dai, Qiang and Zhang, Junliang
Advanced Synthesis & Catalysis, ISSN 1615-4150, 03/2018, Volume 360, Issue 6, pp. 1123 - 1127
A method for the construction of sulfinamides via the copper‐catalyzed electrophilic amination of sulfenate anions using N‐benzoyloxyamines as the amination... 
copper | N-benzoyloxyamine | sulfinamide | electrophilic amidation | sulfenate anion | ASYMMETRIC-SYNTHESIS | ARYL BENZYL SULFOXIDES | ARYLATION | ALLYLIC ALKYLATION | CHEMISTRY, ORGANIC | TERT-BUTYL SULFOXIDES | THIOOXIME S-OXIDES | DIARYL SULFOXIDES | CHIRAL SULFOXIDES | CHEMISTRY, APPLIED | EFFICIENT | SULFINYL KETIMINES | Copper | Esters | Anions | Chemical synthesis | Construction methods | Reagents
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11. Full Text Symmetric Diarylsulfoxides as Asymmetric Sulfinylating Reagents for Dialkylmagnesium Compounds
by Ruppenthal, Simon and Brückner, Reinhard
The Journal of Organic Chemistry, ISSN 0022-3263, 01/2015, Volume 80, Issue 2, pp. 897 - 910
At −78 °C, primary dialkylmagnesium compounds reacted with diarylsulfoxides when 1.5 equiv of the dilithium salt of (S)-BINOL was added as a promotor. Alkyl... 
ORGANIC-SYNTHESIS | LIGAND-EXCHANGE REACTION | ENANTIOSELECTIVE SYNTHESIS | DIALKYL SULFOXIDES | PHENYL SULFOXIDES | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | CHIRAL SULFOXIDES | GRIGNARD-REAGENTS | ENANTIOPURE SULFOXIDES | PARA-DIFUNCTIONALIZATION | Sulfoxides - chemistry | Magnesium Compounds - chemistry | Stereoisomerism | Naphthols - chemistry | Molecular Structure | Catalysis | Indicators and Reagents - chemistry | Thermal properties | Measurement | Analysis | Magnesium | Chemical properties | Surface energy
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12. Full Text Graphite oxide: A selective and highly efficient oxidant of thiols and sulfides
by Dreyer, Daniel R and Jia, Hong-Peng and Todd, Alexander D and Geng, Jianxin and Bielawski, Christopher W
Organic and Biomolecular Chemistry, ISSN 1477-0520, 11/2011, Volume 9, Issue 21, pp. 7292 - 7295
The selective oxidation of thiols to disulfides and sulfides to sulfoxides using graphite oxide (GO), a heterogeneous carbocatalyst obtained from low cost,... 
OXIDATION | OXYGEN | GRAPHENE OXIDE | ROOM-TEMPERATURE | SULFOXIDES | COMPLEXES | CHEMISTRY | CHEMISTRY, ORGANIC | HETEROGENEOUS CATALYSIS | HYDROGEN-PEROXIDE | DISULFIDES | Sulfoxides - chemistry | Sulfoxides - chemical synthesis | Oxidants - chemistry | Oxidation-Reduction | Stereoisomerism | Oxides - chemistry | Sulfides - chemistry | Substrate Specificity | Sulfhydryl Compounds - chemistry | Sulfides - chemical synthesis | Molecular Structure | Graphite - chemistry
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13. Full Text A Phase I and Pharmacological Study with Imidazolium-trans-DMSO-imidazole-tetrachlororuthenate, a Novel Ruthenium Anticancer Agent
by Jeany M. Rademaker-Lakhai and Desiree van den Bongard and Dick Pluim and Jos H. Beijnen and Jan H. M. Schellens
Clinical Cancer Research, ISSN 1078-0432, 06/2004, Volume 10, Issue 11, pp. 3717 - 3727
Purpose: NAMI-A {H 2 Im[ trans- RuCl 4 (DMSO)HIm] or imidazolium- trans- DMSO-imidazole-tetrachlororuthenate} is a novel ruthenium-containing compound that has... 
NAMI-A | CELLS | COMPLEX | INHIBITION | LUNG METASTASES | SOLID TUMORS | ONCOLOGY | PLATINUM-DNA ADDUCTS | TOXICITY | MOUSE-TUMORS | NA | Models, Chemical | Area Under Curve | Dimethyl Sulfoxide - chemistry | Humans | Middle Aged | Dimethyl Sulfoxide - pharmacology | Male | Antineoplastic Agents - therapeutic use | Ruthenium - chemistry | Dose-Response Relationship, Drug | DNA Adducts | Time Factors | Antineoplastic Agents - adverse effects | Organometallic Compounds - therapeutic use | Adult | Female | Antineoplastic Agents - pharmacology | Dimethyl Sulfoxide - therapeutic use | Dimethyl Sulfoxide - adverse effects | Organometallic Compounds - adverse effects | Treatment Outcome | Maximum Tolerated Dose | Aged | Dimethyl Sulfoxide - analogs & derivatives | Organometallic Compounds - pharmacology
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14. Full Text Enantiopure sulfoxides: Recent applications in asymmetric synthesis
by Carmen Carreño, M and Hernández-Torres, Gloria and Ribagorda, María and Urbano, Antonio
Chemical Communications, ISSN 1359-7345, 2009, Issue 41, pp. 6129 - 6144
Sulfoxides are nowadays recognised as powerful chiral auxiliaries that may participate in a wide range of asymmetric reactions. Their high configurational... 
STEREOSELECTIVITY CONTROL | ALPHA-SULFINYL CARBANIONS | DIELS-ALDER REACTIONS | VINYL SULFOXIDES | P-QUINAMINES | CARBONYL ALLYLATION REACTIONS | PARA-TOLYL SULFOXIDE | BETA-ALKOXYVINYL SULFOXIDES | CHIRAL QUATERNARY CENTERS | CHEMISTRY, MULTIDISCIPLINARY | DIRECTED ENANTIOSELECTIVE SYNTHESIS
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15. Full Text Desymmetrization of Prochiral Diaryl Sulfoxides by an Asymmetric Sulfoxide–Magnesium Exchange
by Hampel, Thomas and Ruppenthal, Simon and Sälinger, Daniel and Brückner, Reinhard
Chemistry – A European Journal, ISSN 0947-6539, 03/2012, Volume 18, Issue 11, pp. 3136 - 3140
The first desymmetrizations of prochiral diaryl sulfoxides 1 by an asymmetric sulfoxide–magnesium exchange reaction are reported. The respective substrate (1),... 
organomagnesium compounds | sulfoxide–magnesium exchange | asymmetric synthesis | desymmetrization | sulfoxides | sulfoxide-magnesium exchange | ROUTE | REAGENTS | ENANTIOSELECTIVE SYNTHESIS | ARENES | CHEMISTRY, MULTIDISCIPLINARY | PARA-DIFUNCTIONALIZATION | ARYL ALKYL | SULFINYL GROUP | CONVENIENT PREPARATION | DIALKYL SULFOXIDES | CHIRAL SULFOXIDES | Sulfoxides - chemistry | Naphthols - chemistry | Magnesium - chemistry | Molecular Structure | Catalysis | Stereoisomerism | Organosulfur compounds | Synthesis | Organic compounds | Exchange | Asymmetry | Aromatic compounds | Substrates
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