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science & technology (23) 23
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1. Full Text SiH Bond Activation: Bridging Lewis Acid Catalysis with Brookhart’s Iridium(III) Pincer Complex and B(C6F5)3
by Robert, Tobias and Oestreich, Martin
Angewandte Chemie (International ed.), ISSN 1433-7851, 05/2013, Volume 52, Issue 20, pp. 5216 - 5218
deoxygenation | Lewis acids | silicon | SiH bond activation | pincer complexes | Si-H bond activation
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2. Full Text AlCp as a Directing Ligand: CH and SiH Bond Activation at the Reactive Intermediate [Ni(AlCp)3]
by Steinke, Tobias and Gemel, Christian and Cokoja, Mirza and Winter, Manuela and Fischer, Roland A
Angewandte Chemie (International ed.), ISSN 1433-7851, 04/2004, Volume 43, Issue 17, pp. 2299 - 2302
nickel | CH activation | aluminum | Group 13 elements | SiH activation | Nickel | C-H activation | Aluminum | Si-H activation | Physical Sciences | Chemistry | Chemistry, Multidisciplinary | Science & Technology
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3. Full Text Synthesis and reactivity of silyl cobalt complexes bearing a tetradentate phosphino silyl ligand via Si–H bond activation
by Zhang, Peng and Xu, Shilu and Li, Xiaoyan and Qi, Xinghao and Sun, Hongjian and Fuhr, Olaf and Fenske, Dieter
Polyhedron, ISSN 0277-5387, 03/2018, Volume 143, pp. 165 - 170
Kumada coupling | Silyl cobalt complex | Pincer lignad | Si–H activation | Cobalt hydride | Methane | Cobalt
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4. Full Text Activation of Si–Si and Si–H Bonds at a Platinum Bis(diphenylphos­phanyl)ferrocene (dppf) Complex: Key Steps for the Catalytic Hydro­genolysis of Disilanes
by Kalläne, Sabrina I and Laubenstein, Reik and Braun, Thomas and Dietrich, Maren
European journal of inorganic chemistry, ISSN 1434-1948, 02/2016, Volume 2016, Issue 4, pp. 530 - 537
Silicon | Platinum | Hydrogenolysis | Si–H activation | Si–Si activation | Catalysts | pH | Activation | Formations | Catalysis | Conversion
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5. Full Text Synthesis and characterization of bissilyl cobalt and iron hydrides bearing disilazane ligands via Si-H bond activation
by Dong, Yanhong and Shi, Yaomin and Geng, Yizheng and Zheng, Tingting and Li, Xiaoyan and Sun, Hongjian and Fuhr, Olaf and Fenske, Dieter
Inorganica Chimica Acta, ISSN 0020-1693, 02/2018, Volume 471, pp. 99 - 103
Si-H bond activation | Silyl iron hydride | Trimethylphosphine | Silyl cobalt hydride | Disilazane ligand | Physical Sciences | Chemistry, Inorganic & Nuclear | Chemistry | Science & Technology | Methane | Pyridine | Cobalt | Bonds | Nuclear magnetic resonance--NMR | Carbon dioxide | X-ray diffraction | Activation | Iron | Hydrides | Nitrogen | Molecular chains | Studies | Single crystals | Acetylacetone | Hydrogen bonds | Chemical bonds | Ligands | Chemical synthesis
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6. Full Text Radical Activation of SiH Bonds by Organozinc and Silylzinc Reagents: Synthesis of Geminal Dizinciosilanes and Zinciolithiosilanes
by Dobrovetsky, Roman and Kratish, Yosi and Tumanskii, Boris and Botoshansky, Mark and Bravo‐Zhivotovskii, Dmitry and Apeloig, Yitzhak
Angewandte Chemie (International ed.), ISSN 1433-7851, 05/2012, Volume 51, Issue 19, pp. 4671 - 4675
silyl radicals | dialkyl zinc compounds | silicon | SiH activation | zinc | Si-H activation
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7. Full Text 3‐Silylated Cyclohexa‐1,4‐dienes as Precursors for Gaseous Hydrosilanes: The B(C6F5)3‐Catalyzed Transfer Hydrosilylation of Alkenes
by Simonneau, Antoine and Oestreich, Martin
Angewandte Chemie (International ed.), ISSN 1433-7851, 11/2013, Volume 52, Issue 45, pp. 11905 - 11907
boranes | hydrosilylation | Lewis acids | silane transfer | SiH bond activation | Si-H bond activation
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8. Full Text Catalytic Electrophilic CH Silylation of Pyridines Enabled by Temporary Dearomatization
by Wübbolt, Simon and Oestreich, Martin
Angewandte Chemie (International ed.), ISSN 1433-7851, 12/2015, Volume 54, Issue 52, pp. 15876 - 15879
hydrosilylation | CH activation | N‐heterocycles | SiH bond activation | electrophilic substitution | Si-H bond activation | C-H activation | N-heterocycles
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9. Full Text Activation of Si-Si and Si-H Bonds at a Platinum Bis(diphenylphosphanyl)ferrocene (dppf) Complex: Key Steps for the Catalytic Hydrogenolysis of Disilanes
by Kalläne, Sabrina I and Laubenstein, Reik and Braun, Thomas and Dietrich, Maren
European journal of inorganic chemistry, ISSN 1434-1948, 02/2016, Volume 2016, Issue 4, pp. 530 - 537
Silicon | Hydrogenolysis | Platinum | Si-Si activation | Si-H activation | Physical Sciences | Chemistry, Inorganic & Nuclear | Chemistry | Science & Technology
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10. Full Text B(C6F5)3‐Catalyzed Reduction of Aromatic and Aliphatic Nitro Groups with Hydrosilanes
by Porwal, Digvijay and Oestreich, Martin
European journal of organic chemistry, ISSN 1434-193X, 07/2016, Volume 2016, Issue 20, pp. 3307 - 3309
Lewis acids | Boron | Reduction | Silicon | Si‐H bond activation | Si-H bond activation
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11. Full Text A Tethered Ru–S Complex with an Axial Chiral Thiolate Ligand for Cooperative Si–H Bond Activation: Application to Enantioselective Imine Reduction
by Wübbolt, Simon and Maji, Modhu Sudan and Irran, Elisabeth and Oestreich, Martin
Chemistry : a European journal, ISSN 0947-6539, 05/2017, Volume 23, Issue 25, pp. 6213 - 6219
hydrosilylation | Lewis acids | Si–H bond activation | asymmetric catalysis | homogeneous catalysis | Ligands | Selectivity | Hydrosilylation | Imines
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12. Full Text Outer‐Sphere Ionic Hydrosilylation Catalysis
by Iglesias, Manuel and Fernández‐Alvarez, Francisco J and Oro, Luis A
ChemCatChem, ISSN 1867-3880, 09/2014, Volume 6, Issue 9, pp. 2486 - 2489
iridium | hydrosilylation | reaction mechanisms | homogeneous catalysis | SiH bond activation | Si-H bond activation | Hydrosilylation | Iridium | Reaction mechanisms | Homogeneous catalysis | Physical Sciences | Chemistry | Chemistry, Physical | Science & Technology | Catalysis
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13. Full Text Catalytic 1,4‐Selective Hydrosilylation of Pyridines and Benzannulated Congeners
by Königs, C. David F and Klare, Hendrik F. T and Oestreich, Martin
Angewandte Chemie (International ed.), ISSN 1433-7851, 09/2013, Volume 52, Issue 38, pp. 10076 - 10079
regioselectivity | hydrosilylation | N‐heterocycles | homogeneous catalysis | SiH bond activation | SiH bond activation | N-heterocycles | Silanes - chemistry | Molecular Structure | Catalysis | Pyridines - chemistry | Stereoisomerism | Silanes - chemical synthesis | Pyridine | Index Medicus | Pyridines | Catalysts | Congeners | Quinoline | Hydrides | Hydrosilylation | Radicals
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14. Full Text Direct Acetophenone–Acetophenone Crossed Aldol Reaction and Aldol Self‐Reaction Promoted by a Tethered Ru–S Complex
by Pommerening, Phillip and Stahl, Timo and Oestreich, Martin
European journal of organic chemistry, ISSN 1434-193X, 05/2018, Volume 2018, Issue 19, pp. 2290 - 2293
Si–H bond activation | Ruthenium | Cooperativity | Aldol reactions | C–C bond formation | Acetophenone | Boron | Ketones | Aldehydes | Dehydrogenation | Reagents
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15. Full Text Electrophilic Aromatic Substitution with Silicon Electrophiles: Catalytic Friedel–Crafts C−H Silylation
by Bähr, Susanne and Oestreich, Martin
Angewandte Chemie (International ed.), ISSN 1433-7851, 01/2017, Volume 56, Issue 1, pp. 52 - 59
C−H functionalization | cations | homogeneous catalysis | electrophilic aromatic substitution | Si−H activation | Physical Sciences | Chemistry | Chemistry, Multidisciplinary | Science & Technology | Substitution reactions | Silicon | Catalysis | Protons | Aromatic compounds | Chemical bonds | Protonation | Intermediates
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