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Pure and Applied Chemistry, ISSN 0033-4545, 01/1982, Volume 54, Issue 12, pp. 2285 - 2296
Journal Article
Chemical Communications: Chem Comm, ISSN 1359-7345, 04/2017, Volume 53, Issue 28, pp. 3971 - 3973
Triflates of myo-inositol undergo facile solvolysis in DMSO and DMF yielding SN2 products substituted with O-nucleophiles; DMF showed slower kinetics. Axial... 
Solvolysis | Synthesis | Reaction kinetics
Journal Article
Organic Letters, ISSN 1523-7060, 10/2015, Volume 17, Issue 20, pp. 5080 - 5083
The reversible formation of covalent bonds enabled by the remarkably high Lewis acidity of our calcium-based catalyst system was used for the development of a... 
CHEMISTRY | CHEMISTRY, ORGANIC | SOLVOLYSIS | HETEROCYCLES
Journal Article
Organic Letters, ISSN 1523-7060, 06/2019, Volume 21, Issue 12, pp. 4694 - 4697
1,1-Disubstituted vinyl triflates are synthesized by direct hydrotriflation of terminal alkynes employing a combination of TfOH and TMSN3 in DCM at room... 
CHEMISTRY | CHEMISTRY, ORGANIC | SOLVOLYSIS | COUPLING REACTIONS | ACIDS
Journal Article
Fuel Processing Technology, ISSN 0378-3820, 01/2020, Volume 197, p. 106200
This study investigated the non-catalyzed solvolysis of sulphur free organosolv lignin using mixtures of organic solvents (methanol, ethanol and... 
2-Methyltetrahydrofuran | Lignin | Solvolysis | Monoaromatics | Green solvents
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 09/2016, Volume 81, Issue 17, pp. 8091 - 8094
Amide N–C­(O) bonds are generally unreactive in cross-coupling reactions employing low-valent transition metals due to nN → π*CO resonance. Herein we... 
SOLVOLYSIS | ROTATIONAL PATHWAY | RESONANCE | NITROGEN | REACTIVITY | ENERGETICS | CHEMISTRY, ORGANIC | BOND ACTIVATION | CLEAVAGE | TETRAFLUOROBORATE | BRIDGEHEAD BICYCLIC LACTAMS
Journal Article
Journal of Molecular Structure, ISSN 0022-2860, 09/2019, Volume 1192, pp. 76 - 81
The present work describes the synthesis, solvolysis and cytotoxic activity of Pt (II) complexes of the type -[PtCl (DMSO) (L)] and -[PtCl (L) ], where... 
Solvolysis | Hydrazide | Pt(II) complexes | Cytotoxic activity
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2015, Volume 54, Issue 47, pp. 13856 - 13858
Breaking good: The amide bond is widely recognized as the strongest bond among the carboxylic acid derivatives. Therefore, the potential of amides to serve as... 
nickel | amides | homogenous catalysis | solvolysis | esters | ACTIVATION | CONVERSION | ACIDS | HYDROLYSIS | CLEAVAGE | CHEMISTRY, MULTIDISCIPLINARY | Amides | Catalysis
Journal Article
Journal of Organic Chemistry, ISSN 0022-3263, 08/2015, Volume 80, Issue 16, pp. 7837 - 7848
Over the past two decades, organotrifluoroborates have evolved from being chemical curiosities to important reagents for the elaboration of organic molecules.... 
SUZUKI | SOLVOLYSIS | CROSS-COUPLING REACTIONS | BORONIC ACID | AMINOMETHYLATIONS | SCOPE | POTASSIUM ARYL | CHEMISTRY, ORGANIC | SINGLE-ELECTRON TRANSMETALATION | SALTS | ACCESS
Journal Article
Carbohydrate Polymers, ISSN 0144-8617, 11/2019, p. 115530
Journal Article
Biomass and Bioenergy, ISSN 0961-9534, 09/2015, Volume 80, pp. 147 - 161
The catalytic conversion of Alcell lignin in iso-propanol/formic acid mixtures (1:1 mass ratio) was explored in a batch set-up using Ru/C as the catalyst... 
Catalytic | Solvolysis | Heterogeneous | lignin | Ruthenium | Hydrotreatment | FAST PYROLYSIS OIL | FORMIC-ACID | STANDARDIZATION | HYDROGENOLYSIS | CONVERSION | DEPOLYMERIZATION | CHEMICALS | PHENOLS | BIOMASS | DEGRADATION | Solvolysis lignin | Lignin | ENERGY & FUELS | AGRICULTURAL ENGINEERING | BIOTECHNOLOGY & APPLIED MICROBIOLOGY
Journal Article
Croatica Chemica Acta, ISSN 0011-1643, 2019, Volume 92, Issue 2, p. P1
The electrofugality scale has been extended with new substituted ferrocenylphenylmethyl cations 1-4. Ef values were determined by applying the linear free... 
electrofugality | substituent effect | solvolysis | ferrocenylphenylmethyl cation | nucleofugalty
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 2009, Volume 50, Issue 26, pp. 3182 - 3184
An unusual loss of CO was observed during a key cyclization event in efforts toward the total synthesis of zoanthenol. The synthesis of the cyclization... 
CHEMISTRY, ORGANIC | SOLVOLYSIS
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 07/2010, Volume 132, Issue 27, pp. 9286 - 9288
Primary aminothiourea derivatives are shown to catalyze enantioselective alkylation of alpha-arylpriopionaldehdyes with diarylbromomethane. Evidence for a... 
SOLVOLYSIS | CARBONIUM IONS | DIRECT CONJUGATE ADDITION | TRANSITION-METAL | ALLYLATION | ASYMMETRIC ALKYLATION | ORGANOCATALYSIS | CHLORIDES | AMINE-THIOUREA CATALYST | CHEMISTRY, MULTIDISCIPLINARY | NITROALKENES
Journal Article
ACS Catalysis, ISSN 2155-5435, 01/2015, Volume 5, Issue 1, pp. 365 - 379
It is imperative to develop an efficient and environmentally benign pathway to valorize profusely available lignin, a component of nonedible lignocellulosic... 
Depolymerization | Lignin | Biomass | Column chromatography | Aromatic monomers | Solid acid catalysts | biomass | aromatic monomers | HYDROGENOLYSIS | CONVERSION | KRAFT LIGNIN | CHEMISTRY, PHYSICAL | lignin | FAST PYROLYSIS | WOOD LIGNIN | depolymerization | DIMETHYL ETHER DME | CHEMISTRY | solid acid catalysts | DEGRADATION | column chromatography | SOLVOLYSIS LIGNIN
Journal Article
Journal of Physical Organic Chemistry, ISSN 0894-3230, 01/2017, Volume 30, Issue 1, pp. e3585 - n/a
A simple linear regression (Q equation) is devised to position solvolyses within the established SN2‐SN1 spectrum of solvolysis mechanisms. Using 2‐adamantyl... 
acid chlorides | solvolysis | kinetics | mechanistic spectrum | tosylates
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 05/2017, Volume 82, Issue 10, pp. 5345 - 5353
The influence of the electron-withdrawing azide group on the reduction of O-(1-acyloxy-ω-azido)­hydroxylamines by triethylsilane in the presence of boron... 
RING INVERSION | ROTATION | SOLVOLYSIS | NITROGEN INVERSION | BARRIER | CHEMISTRY, ORGANIC | BOND
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2009, Volume 48, Issue 47, pp. 8931 - 8934
Last of the cyclic vinyl cations: The simple solvolysis of cyclopent‐1‐enyl‐λ3‐bromane efficiently generates the highly strained cyclopent‐1‐enyl cation at... 
bromine | isotope effects | iodine | solvolysis | vinyl cations | Bromine | Isotope effects | Solvolysis vinyl cations | Iodine
Journal Article
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