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stannylation (62) 62
chemistry, organic (60) 60
reagents (21) 21
chemistry (17) 17
derivatives (17) 17
chemistry, multidisciplinary (15) 15
tin (15) 15
palladium (13) 13
stannylation-destannylation (13) 13
chemistry, inorganic & nuclear (12) 12
biochemistry & molecular biology (8) 8
catalysis (8) 8
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halides (8) 8
stannylation reactions (8) 8
alkylation (7) 7
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generation (7) 7
lithiation (7) 7
synthesis (7) 7
activation (6) 6
alcohols (6) 6
chemistry, applied (6) 6
organic-synthesis (6) 6
stannanes (6) 6
aldehydes (5) 5
chemistry, medicinal (5) 5
desulfurizative stannylation (5) 5
index medicus (5) 5
ligands (5) 5
pharmacology & pharmacy (5) 5
stille coupling (5) 5
acids (4) 4
analysis (4) 4
aryl (4) 4
asymmetric-synthesis (4) 4
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electrophilic substitution (4) 4
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letter (4) 4
mediated fluorination (4) 4
nickel (4) 4
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route (4) 4
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stereochemistry (4) 4
analogs (3) 3
aromatic compounds (3) 3
aryl bromides (3) 3
arylation (3) 3
bond formation (3) 3
bond stannylation (3) 3
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carbonyl-compounds (3) 3
catalyzed stannylation (3) 3
chemical reactions (3) 3
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esters (3) 3
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k ee chemistry, organic (3) 3
ketones (3) 3
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magnetic resonance spectroscopy (3) 3
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Organic Letters, ISSN 1523-7060, 01/2018, Volume 20, Issue 2, pp. 385 - 388
An unprecedented conversion of methyl esters to stannanes was realized, providing access to a series of arylstannanes via nickel catalysis. Various common... 
ORGANOZINC REAGENTS | AZOLES | O BOND ACTIVATION | MEDIATED FLUORINATION | C-O | NICKEL | ALPHA-ARYLATION | ARYL ESTERS | STANNYLATION | CHEMISTRY, ORGANIC | PHENOL DERIVATIVES
Journal Article
Synthesis, ISSN 0039-7881, 08/2016, Volume 48, Issue 16, pp. 2540 - 2552
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 2016, Volume 22, Issue 20, pp. 6740 - 6745
Journal Article
Synlett, ISSN 0936-5214, 08/2014, Volume 25, Issue 13, pp. 1904 - 1908
Abstract Various alkoxy-substituted heterocyclic stannanes provide access to the corresponding substituted ‘pyridone’ moieties via Stille cross-coupling. Both... 
letter | pyridine | Stille coupling | heterocyclic stannane | STANNYLATION REACTIONS | CYTISINE | CHEMISTRY, ORGANIC | (-)-CYTISINE | ARYL | EXCHANGE-REACTIONS
Journal Article
Chemical communications (Cambridge, England), ISSN 1364-548X, 2015, Volume 51, Issue 30, pp. 6508 - 6511
The first nickel-catalyzed method for the borylation of carbon–hydrogen bonds in arenes and indoles is described. The use of an N-heterocyclic carbene ligand... 
FUNCTIONALIZATION | SN BONDS | ACTIVATION | ETHERS | STANNYLATION | ALKYLATION | CONSTRUCTION | F BOND | INTERMEDIATE | PINACOLBORANE | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 01/2018, Volume 2018, Issue 1, pp. 120 - 125
Solvent‐free protocols for palladium‐catalyzed stannylation of aryl halides, Stille cross‐coupling, and one‐pot, two‐step stannylation/Stille cross‐coupling... 
Stille coupling | Palladium | Stannylation | Cross‐coupling | Solvent‐free reactions | Cross-coupling | Solvent-free reactions | STANNANES | RAPAMYCIN | REAGENTS | CHLORIDES | CHEMISTRY, ORGANIC | FLUORINATION | Chemical tests and reagents | Halides
Journal Article
Molecules (Basel, Switzerland), ISSN 1420-3049, 2019, Volume 24, Issue 9, p. 1671
Nickel-catalyzed decarbonylative stannylation of acyl fluorides under ligand-free conditions was disclosed. A variety of aromatic acyl fluorides are capable of... 
ORGANOZINC REAGENTS | HALIDES | nickel | acyl fluorides | carbon-tin bond formation | BIOCHEMISTRY & MOLECULAR BIOLOGY | stannylation | BOND FORMATION | decarbonylation | ARYL | CHEMISTRY, MULTIDISCIPLINARY | Fluorides - chemistry | Nickel - chemistry | Cesium - chemistry | Ligands | Molecular Structure | Catalysis | Carbon - chemistry
Journal Article
Synlett, ISSN 0936-5214, 12/2016, Volume 27, Issue 20, pp. 2836 - 2840
Abstract The preparation of 2-bromo-3-(tri- n -butylstannyl)-1-propene is described. This study characterizes the reactivity of 2-bromo-3-(tri- n... 
letter | radical reaction | reactions | bifunctional reagent | organostannane preparation | alkenyl bromides | S-E' reactions | ASYMMETRIC-SYNTHESIS | REAGENTS | STRATEGY | CHEMISTRY, ORGANIC | STEREOCONTROLLED ALLYLATION REACTIONS | ALDEHYDES | LEUCASCANDROLIDE | ALCOHOLS | STANNYLATION | ACCESS
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 05/2016, Volume 358, Issue 10, pp. 1664 - 1670
Journal Article
Advanced synthesis & catalysis, ISSN 1615-4150, 2017, Volume 359, Issue 5, pp. 832 - 840
Herein, we report on a comparative Stille and Suzuki cross‐coupling study of steroidal vinyl (pseudo)halides with different boronic acids and tributyltin... 
Suzuki coupling | Stille coupling | steroids | stannylation | (+)-CORTISTATIN-A | OUABAGENIN | VINYLATION | CHEMISTRY, ORGANIC | PALLADIUM-CATALYZED REACTION | SCALABLE SYNTHESIS | ORGANIC HALIDES | ARYL | INHIBITORS | CHEMISTRY, APPLIED | HECK REACTION | GRIGNARD-REAGENTS | Tributylin | Tributyltin | Bromides | Residues | Chemical reactions | Military aircraft | Cross coupling | Halides | Screening | Synthesis | Military planes | Inverse | Steroids
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2013, Volume 52, Issue 44, pp. 11620 - 11623
A versatile route to trisubstituted alkenylstannanes is presented. The alkyl and Sn moieties were introduced at the β and α carbon atoms of alkynoates,... 
alkylboranes | copper | trisubstituted alkenylstannanes | stannylation | SUBSTITUTION | ALLYLIC PHOSPHATES | ACIDS | PROPARGYLIC PHOSPHATES | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | STEREOSELECTIVE-SYNTHESIS | CARBOSTANNYLATION | ALLYLSTANNYLATION | CONJUGATE ADDITION | Tributylin | Copper | Tributyltin | Tin | Joining | Synthesis | Carbon | Functional groups
Journal Article
Advanced synthesis & catalysis, ISSN 1615-4150, 2015, Volume 357, Issue 14-15, pp. 3303 - 3308
Herein, the synthesis of heteromeric tetrahydroxanthone biaryls is described, a widespread core structure of many natural products. The development of both... 
Stille coupling | tetrahydroxanthones | heteromeric biaryls | stannylation | HALIDES | NATURAL-PRODUCTS | CHEMISTRY, ORGANIC | DIVERSONOL | BULKY | LIGANDS | BLENNOLIDE-C | CHEMISTRY, APPLIED | ENANTIOSELECTIVE TOTAL-SYNTHESIS | CATALYSTS | Joining | Synthesis | Derivatives | Catalysis | Natural products | Benzene
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 06/2016, Volume 22, Issue 27, pp. 9130 - 9134
A practical and scalable nickel‐catalyzed allylic stannylation of allyl acetates with Bu3SnOMe is described. A variety of acyclic and cyclic allyl acetates,... 
allyl stannanes | stannyl alkoxide | nickel | synthetic method | stannylation | HALIDES | ORGANIC-SYNTHESIS | SUBSTITUTION | REAGENTS | 1ST OBSERVATION | STEREOCHEMISTRY | ALLYLNICKEL BROMIDE COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY | REMARKABLE REACTIVITY | STANNANES | TIN | Palladium catalysts | Palladium | Nickel | Acetates
Journal Article
Bioorganic and Medicinal Chemistry Letters, ISSN 0960-894X, 04/2015, Volume 25, Issue 8, pp. 1761 - 1764
Trialkylstannanes are versatile precursors for chemical transformations, including radiolabeling with a variety of halogens, particularly iodine. In the... 
Opioid | Radioiodination | Stannylation | Radioligand binding | Sigma receptor | CHEMISTRY, MEDICINAL | REAGENTS | CHEMISTRY, ORGANIC | IODIDES | CROSS-COUPLING REACTIONS | TIN | LIGAND | BINDING | Brain - metabolism | Iodine - chemistry | Piperidines - chemistry | Pyrazoles - chemistry | Animals | Iodine Radioisotopes - chemistry | Isotope Labeling | Mice | Catalysis | Palladium - chemistry | Palladium
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 02/2013, Volume 54, Issue 8, pp. 811 - 813
Conversion of chromane-6-triflate 5 to chromane-6-dehydroalanine 9 or 10 via its Bpin-derivative 6 followed by Suzuki coupling with protected dehydroalanine... 
Aryl triflate | Suzuki coupling | Palladium-catalyzed coupling | Stannylation | Boronation | ACID | REAGENTS | CROSS-COUPLING REACTION | COMPLEXES | CHEMISTRY, ORGANIC | ARYL | ASYMMETRIC HYDROGENATION | Palladium | Aryl Triflate
Journal Article
Organic letters, ISSN 1523-7060, 07/2019, Volume 21, Issue 13, pp. 5187 - 5191
The visible-light-driven preparation of (hetero)­aryl stannanes was carried out under both photocatalyst- and metal-free conditions via irradiation of arylazo... 
STANNANES | CROSS-COUPLING REACTIONS | MEDIATED FLUORINATION | GERMANIUM | ARYLATION | PERSPECTIVES | DECOMPOSITION | CHEMISTRY, ORGANIC | CATALYZED STANNYLATION | GENERATION | TRANSFORMATIONS
Journal Article
Synthesis, ISSN 0039-7881, 01/2012, Volume 44, Issue 2, pp. 194 - 200
Abstract Convenient and practical synthesis of N-Boc- and N-Cbz-α-amino stannanes from the corresponding α-amido sulfones was achieved. Yields of products are... 
practical synthetic procedures | tin | fluoride | imines | sulfones | stannylation | ACIDS | IMIDOYLSTANNANES | CHEMISTRY, ORGANIC | CONFIGURATIONAL STABILITY | BETA | AMINOORGANOSTANNANES | AMINOORGANOLITHIUMS | N-BOC | ENANTIOSELECTIVE SYNTHESES | PRIMARY AMINES | TIN-LITHIUM EXCHANGE
Journal Article
Organic letters, ISSN 1523-7060, 09/2019, Volume 21, Issue 18, pp. 7303 - 7306
Aryl–heteroatom bonds (C–Het) are almost ubiquitously present in chemical molecules. However, methods for diverse C–Het bond formations from a simple substrate... 
MILD | FUNCTIONALIZATION | PALLADIUM | COUPLING REACTIONS | STANNYLATION | CONSTRUCTION | ARYLATION | CHEMISTRY | CHEMISTRY, ORGANIC | CATALYZED SILYLATION | ARYLSULFONIUM SALTS
Journal Article