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Chemical Society reviews, ISSN 1460-4744, 2012, Volume 41, Issue 11, pp. 4165 - 4179
In addition to the well-established nucleophilic alkynylation, the use of electrophilic alkynes can expand tremendously the scope of acetylene transfer reactions... 
CATALYZED DIRECT ALKYNYLATION | MECHANISTIC ASPECTS | ORGANIC-SYNTHESIS | GACL3-CATALYZED ORTHO-ETHYNYLATION | CROSS-COUPLING REACTION | TERMINAL ALKYNES | ALK-1-YNYLLEAD TRIACETATES | ALKYNYLIODONIUM SALTS | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | CARBOXYLIC-ACID DERIVATIVES
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 02/2019, Volume 361, Issue 3, pp. 611 - 616
Two well known synthetic organic reactions Ramirez olefination and Corey‐fuchs reactions are integrated in one‐pot sequential manner for the synthesis of... 
Terminal alkyne | Ramirez olefination | Aldehyde | 1-Bromoarylacetylenes | DBU | Corey-Fuchs reaction | 1,1-DIBROMO-1-ALKENES | 1-HALOALKYNES | CHEMISTRY, ORGANIC | TERMINAL ALKYNES | CARBONYL-COMPOUNDS | ONE-POT PROCEDURE | INTERNAL ALKYNES | ALKYNYLATION | HETEROCYCLES | STEREOSELECTIVE-SYNTHESIS | CHEMISTRY, APPLIED | ENYNES | Aldehydes | Chemical synthesis | Aromatic compounds | Sodium hydroxide | Alkynes
Journal Article
Nature communications, ISSN 2041-1723, 2016, Volume 7, Issue 1, p. 11732
...: in the presence of a dichloro[(2,6,10-dodecatriene)-1,12-diyl] ruthenium catalyst, carboxylate salts of primary or secondary amines react with acetylene or ethoxyacetylene... 
PEPTIDE COUPLING REAGENTS | ENOL ESTERS | ROOM-TEMPERATURE | MULTIDISCIPLINARY SCIENCES | OXIDATIVE AMIDATION | LIGATION | BOND FORMATION | RUTHENIUM CATALYSTS | TERMINAL ALKYNES | ALDEHYDES | SELECTIVE ADDITION
Journal Article
Advanced synthesis & catalysis, ISSN 1615-4150, 2016, Volume 358, Issue 11, pp. 1778 - 1793
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 09/2012, Volume 134, Issue 37, pp. 15505 - 15511
A direct metal-free amination of arylalkynes has been developed, which proceeds by reaction of the terminal alkyne with the hypervalent iodine reagent... 
ORGANIC-SYNTHESIS | IODONIUM SALTS | COUPLING REACTIONS | POLYVALENT IODINE COMPOUNDS | OXIDATIVE AMIDATION | TERMINAL ALKYNES | N BOND FORMATION | ALKYNYLIODONIUM SALTS | PAUSON-KHAND REACTIONS | CHEMISTRY, MULTIDISCIPLINARY | GENERAL-METHOD | Chemical bonds | Iodine compounds | Chemical properties | Analysis | Acetylene
Journal Article
Catalysis Letters, ISSN 1011-372X, 3/2014, Volume 144, Issue 3, pp. 413 - 418
...Regio- and Stereoselective Homodimerization of Monosubstituted Acetylenes in the Presence of the Second Generation Grubbs Catalyst Beata Powa a • Cezary... 
Chemistry | Ruthenium | Physical Chemistry | Organometallic Chemistry | Homogeneous catalysis | Acetylenes | Catalysis | Alkylidene complexes | Industrial Chemistry/Chemical Engineering | Dimerization | COMPLEX | METAL VINYLIDENES | ACID | CHEMISTRY, PHYSICAL | TERMINAL ALKYNES | TAIL DIMERIZATION | TO-HEAD DIMERIZATION | COUPLING REACTIONS | 1-ALKYNES | ENYNES | Olefins | Stereoselectivity | Catalysts | Metathesis
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 2017, Volume 53, Issue 45, pp. 6136 - 6139
...; terminal acetylenes and acrolein can be coupled conjugate addition, followed by alkyne isomerisation... 
ALCOHOLS | RHODIUM | POLYENE NATURAL-PRODUCT | BUILDING-BLOCKS | ISOMERIZATION | 2,4-DIENALS | COMPLEXES | STEREOSELECTIVE-SYNTHESIS | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | DIENONES | Acroleins | Conjugates | Synthesis | Isomerization | Palladium | Terminals | Alkynes
Journal Article
Synlett, ISSN 0936-5214, 02/2014, Volume 25, Issue 3, pp. 407 - 410
Abstract A simple, rapid, one-pot synthesis of arylaminomethyl acetylenes is achieved under microwave-assisted conditions (power = 5 W... 
letter | CONVENIENT SYNTHESIS | propargyl halide | ARYLDIAZONIUM SILICA SULFATES | CLICK CHEMISTRY | ammonia | CHEMISTRY, ORGANIC | three-component | terminal alkynes | ONE-POT CONVERSION | COUPLING REACTIONS | microwave-assisted | PROPIOLIC ACID | 1,2,3-TRIAZOLES | REGIOSELECTIVE SYNTHESIS | ACTIVATED ALCOHOLS | EFFICIENT
Journal Article
Synthesis (Stuttgart), ISSN 1437-210X, 2005, Volume 2005, Issue 10, pp. 1706 - 1712
ABSTRACT Synthetic protocols using copper(I) catalysts for the formation of diaryl acetylenes, 1,3-enynes, benzofurans and indoles are described. 
special topic | Terminal acetylenes | Enynes | Indoles | Copper | Benzofurans | benzofurans | CHEMISTRY, ORGANIC | enynes | GENERAL-METHOD | IODOPHENOLS | IODIDES | indoles | terminal acetylenes | COPPER-CATALYZED SYNTHESIS | PROGRESS | copper | EFFICIENT | ULLMANN
Journal Article
Dyes and Pigments, ISSN 0143-7208, 09/2014, Volume 108, pp. 50 - 56
...-system between the N,N-dimethylamino group and terminal acetylene was systematically elongated which allowed elucidation of the fundamental structure... 
Emission | Absorption | Phenylene | Donor | π-System | Acetylene | ENGINEERING, CHEMICAL | FLUORESCENCE | MATERIALS SCIENCE, TEXTILES | pi-System | CHROMOPHORES | POLYMER | CHEMISTRY, APPLIED | Cytokinins | Analysis | Spectroscopy | Dyes | Scaffolding | Emission spectra | Elongated structure | Mathematical models | Terminals
Journal Article
Synlett, ISSN 0936-5214, 08/2019, Volume 30, Issue 13, pp. 1580 - 1584
Abstract A simple method is described for the synthesis of 1-arylprop-1-ynes directly from aromatic aldehyde p -tosylhydrazones by using calcium carbide as an acetylene source... 
letter | ONE-POT SYNTHESIS | CHEMISTRY, ORGANIC | CATALYZED ALLYLATION | TERMINAL ALKYNES | aralkynes | IONIC LIQUID | INTERNAL ALKYNES | FRIEDEL-CRAFTS ALKENYLATION | calcium carbide | N-TOSYLHYDRAZONES | tosylhydrazones | FACILE SYNTHESIS | arylpropynes | STEREOSELECTIVE-SYNTHESIS | DERIVATIVES
Journal Article
Catalysis letters, ISSN 1572-879X, 2018, Volume 148, Issue 11, pp. 3370 - 3377
Several S-containing organic compounds were used as ligands for Cu(I)-catalyzed acetylene hydration under mercury free condition... 
Cu(I) | Acetylene hydration | S-containing organic compounds | Acetaldehyde | OXIDATION | ACID | CHEMISTRY, PHYSICAL | TERMINAL ALKYNES | DIMERIZATION | CHEMICALS | EXCHANGE | NIEUWLAND CATALYST | WATER | Hydration | Ligands | Density functional theory | Selectivity | Copper | Acetylene | Organic compounds
Journal Article
Journal of molecular catalysis. A, Chemical, ISSN 1381-1169, 2016, Volume 414, pp. 37 - 46
[Display omitted] •2-PyPPh2 ligand based porous organic polymer (POL-2V-P,N) was successfully synthesized.•The Pd/POL-2V-P,N catalyst exhibits higher activity... 
Methoxycarbonylation of acetylene | Homogeneous reaction | Palladium | 2V-P,N polymer | Heterogenized catalyst | ALKOXYCARBONYLATION | COMPLEXES | CHEMISTRY, PHYSICAL | TERMINAL ALKYNES | EFFICIENT CATALYST | CARBONYLATION | CARBON-MONOXIDE | HOMOGENEOUS CATALYSIS | ACRYLIC-ACID | HYDROFORMYLATION | Palladium catalysts | Radiation | Polymer industry | Catalysis | Polymers | Acetylene
Journal Article
Applied catalysis. A, General, ISSN 0926-860X, 2019, Volume 571, pp. 170 - 179
[Display omitted] •The first example of selective nickel-catalyzed disulphide addition to acetylene is reported.•Synthesis of (Z)-1,2-bis(arylthio)ethenes and (Z,Z)-1,4-bis(arylthio... 
Calcium carbide | Diene | Sulfur derivatives | Nickel | Catalysis | Atom-economic addition | Acetylene | CARBON | PERFORMANCE | C-S | INTERMOLECULAR HYDROTHIOLATION | CHEMISTRY, PHYSICAL | TERMINAL ALKYNES | BOND FORMATION | SULFUR | INTERNAL ALKYNES | THIOLS | ENVIRONMENTAL SCIENCES | DIARYL DISULFIDES | Alkenes | Catalysts | Aromatic compounds | Switches | Disulfides | Ligands | Activation | Selectivity | Dienes
Journal Article
Synthesis, ISSN 0039-7881, 08/2011, Volume 2011, Issue 15, pp. 2466 - 2470
Abstract Cerium(IV) ammonium nitrate mediated oxidative addition of 1,3-dicarbonyl compounds to terminal acetylenes to yield multisubstituted furan derivatives is reported here... 
paper | multisubstituted furans | 1,3-dicarbonyl compounds | terminal acetylenes | cerium(IV) ammonium nitrate | oxidative addition | CYCLOADDITION | ALKENES | FACILE SYNTHESIS | FURANS | CHEMISTRY, ORGANIC | TRANSFORMATIONS | DIHYDROFURANS
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 04/2019, Volume 141, Issue 14, pp. 5772 - 5780
... attack of protonated acetylene, deprotonation of the vinyl cation, and catalyst regeneration, is the most... 
DENSITY FUNCTIONALS | H FUNCTIONALIZATION | AZIDE-ALKYNE CYCLOADDITION | ACTIVATION | AB-INITIO | COMPLEXES | CATALYZED REACTION | TERMINAL ALKYNES | DIAZO-COMPOUNDS | CHEMISTRY, MULTIDISCIPLINARY | N-TOSYLHYDRAZONES
Journal Article