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1. Full Text Catalytic hydrotrifluoromethylation of unactivated alkenes
by Mizuta, Satoshi and Verhoog, Stefan and Engle, Keary M and Khotavivattana, Tanatorn and O'Duill, Miriam and Wheelhouse, Katherine and Rassias, Gerasimos and Médebielle, Maurice and Gouverneur, Véronique
Journal of the American Chemical Society, ISSN 0002-7863, 02/2013, Volume 135, Issue 7, pp. 2505 - 2508
A visible-light-mediated hydrotrifluoromethylation of unactivated alkenes that uses the Umemoto reagent as the CF3 source and MeOH as the reductant is... 
MEDICINAL CHEMISTRY | ORGANIC-SYNTHESIS | ACIDS | LIGHT PHOTOREDOX CATALYSIS | BOND FORMATION | FLUORINE | RADICALS | EFFICIENT | CHEMISTRY, MULTIDISCIPLINARY | TERMINAL ALKENES | TRIFLUOROMETHYLATION | Alkenes - chemistry | Molecular Structure | Catalysis | Methylation | Fluorine - chemistry | Measurement | Thermal properties | Olefins | Analysis | Chemical properties | Activation energy
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2. Full Text Copper‐Catalyzed Intermolecular Trifluoromethylazidation of Alkenes: Convenient Access to CF3‐Containing Alkyl Azides
by Wang, Fei and Qi, Xiaoxu and Liang, Zhaoli and Chen, Pinhong and Liu, Guosheng
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2014, Volume 53, Issue 7, pp. 1881 - 1886
A novel copper‐catalyzed intermolecular trifluoromethylazidation of alkenes has been developed under mild reaction conditions. A variety of CF 3 ‐containing... 
copper | alkenes | azides | synthetic methods | fluorine | ROOM-TEMPERATURE | OLEFINIC TRIFLUOROMETHYLATION | BOND FORMATION | BETA-KETO-ESTERS | OXIDATIVE TRIFLUOROMETHYLATION | CHEMISTRY, MULTIDISCIPLINARY | UNACTIVATED ALKENES | ACTIVATED ALKENES | ALLYLIC ALCOHOLS | EFFICIENT | TERMINAL ALKENES | Alkenes - chemistry | Hydrocarbons, Fluorinated - chemical synthesis | Copper - chemistry | Stereoisomerism | Hydrocarbons, Fluorinated - chemistry | Molecular Structure | Catalysis | Azides - chemical synthesis | Azides - chemistry | Hydrocarbons, Cyclic - chemistry | Hydrocarbons, Cyclic - chemical synthesis | International cooperation | Fluorides | Copper | Olefins
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3. Full Text Copper‐Catalyzed Formal [2+2+1] Heteroannulation of Alkenes, Alkylnitriles, and Water: Method Development and Application to a Total Synthesis of (±)‐Sacidumlignan D
by Ha, Tu M and Chatalova‐Sazepin, Claire and Wang, Qian and Zhu, Jieping
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2016, Volume 55, Issue 32, pp. 9249 - 9252
A copper‐catalyzed three‐component reaction of alkenes, alkylnitriles, and water affords γ‐butyrolactones in good yields. The domino process involves an... 
multicomponent reactions | copper | total synthesis | alkenes | heterocycles | INTRAMOLECULAR CARBOAMINATION | ALKYL NITRILES | GAMMA-LACTONES | COPPER(I)-CATALYZED REACTION | CHEMISTRY, MULTIDISCIPLINARY | ACTIVATED ALKENES | COOPERATIVE CATALYSIS | ARYL DIAZONIUM SALTS | ALLYLIC ALCOHOLS | METAL-SALTS | TERMINAL ALKENES | Synthesis | Chemical properties | Copper | Olefins | Methods | Organic compounds
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4. Full Text Silver‐Catalyzed Hydrotrifluoromethylation of Unactivated Alkenes with CF3SiMe3
by Wu, Xinyue and Chu, Lingling and Qing, Feng‐Ling
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2013, Volume 52, Issue 8, pp. 2198 - 2202
A silver bullet : The title reaction results in selective formation of trifluoromethylated alkanes, and is in contrast to the previously reported... 
radical reactions | silver | homogeneous catalysis | synthetic methods | fluorine | ROOM-TEMPERATURE | COPPER-MEDIATED TRIFLUOROMETHYLATION | OXIDATIVE TRIFLUOROMETHYLATION | REDUCTIVE ELIMINATION | CHEMISTRY, MULTIDISCIPLINARY | ARYLBORONIC ACIDS | ARYL BORONIC ACIDS | PD(II)-CATALYZED ORTHO-TRIFLUOROMETHYLATION | ALLYLIC TRIFLUOROMETHYLATION | TERMINAL ALKENES | BOND-FORMATION | Alkenes - chemistry | Hydrocarbons, Fluorinated - chemistry | Molecular Structure | Catalysis | Trimethylsilyl Compounds - chemistry | Silver - chemistry | Olefins | Fluorides
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5. Full Text Terminal C(sp3)H alkylation of internal alkenes via Ni/H-catalyzed isomerization
by Wang, Zhen-Yu and Wang, Gao-Yin and Wang, Xi-Sheng and Wang, Rui and Wan, Jia-Hao and Jin, Ruo-Xing and Lan, Quan
Tetrahedron Letters, ISSN 0040-4039, 06/2018, Volume 59, Issue 23, pp. 2302 - 2305
An efficient nickel-catalyzed reductive relay cross-coupling of internal alkenes with alkyl (or aryl) halides has been developed. This method has demonstrated... 
Internal alkenes | Terminal-selectivity | Isomerization | Nickel-catalyzed | Alkylation | HALIDES | ORGANIC-SYNTHESIS | COBALT CATALYSTS | CHEMISTRY, ORGANIC | FORMAL HYDROAMINATION | CROSS-COUPLING REACTIONS | ARYL BORONIC ACIDS | REMOTE FUNCTIONALIZATION | OLEFINS | TERTIARY SILANES | CARBOXYLIC-ACIDS | Olefins
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6. Full Text Recent Progress in Direct Introduction of Fluorinated Groups on Alkenes and Alkynes by means of CH Bond Functionalization
by Besset, Tatiana and Poisson, Thomas and Pannecoucke, Xavier
Chemistry – A European Journal, ISSN 0947-6539, 12/2014, Volume 20, Issue 51, pp. 16830 - 16845
The direct introduction of fluorine and fluorinated building blocks has recently attracted a lot of attention and particularly the direct functionalization of... 
fluorination | radical reactions | trifluoromethylation | alkenes | alkynes | Alkenes | Radical reactions | Trifluoromethylation | Fluorination | Alkynes | OLEFINIC TRIFLUOROMETHYLATION | INITIATED RADICAL-ADDITION | MEDIATED TRIFLUOROMETHYLATION | TERMINAL ALKYNES | OXIDATIVE TRIFLUOROMETHYLATION | CHEMISTRY, MULTIDISCIPLINARY | COPPER-CATALYZED TRIFLUOROMETHYLATION | DIFLUOROMETHYL RADICALS | PD(II)-CATALYZED ORTHO-TRIFLUOROMETHYLATION | COUPLING REACTION | HYPERVALENT IODINE REAGENT | Fluorine | Transformations | Reaction mechanisms | Bonding | Radicals | Analytical chemistry | Medicinal Chemistry | or physical chemistry | Organic chemistry | Cheminformatics | Catalysis | Chemical Sciences | Theoretical and
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7. Full Text Aluminum-Catalyzed Hydroboration of Alkenes
by Bismuto, Alessandro and Cowley, Michael J and Thomas, Stephen P
ACS Catalysis, ISSN 2155-5435, 03/2018, Volume 8, Issue 3, pp. 2001 - 2005
The aluminum-catalyzed hydroboration of alkenes with HBpin is reported using simple commercially available aluminum hydride precatalysts [LiAlH4 or sodium... 
main group | catalysis | aluminum | hydroboration | alkene | REDUCTIVE DEHALOGENATION | COMPLEXES | CHEMISTRY, PHYSICAL | CARBONYL-COMPOUNDS | TERMINAL ALKYNES | ALDEHYDES | HYDROALUMINATION | HYDRIDE | SELECTIVE HYDROBORATION | KETONES | BORON REAGENTS
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8. Full Text Nickel-Catalyzed Reductive Dicarbofunctionalization of Alkenes
by García-Domínguez, Andrés and Li, Zhaodong and Nevado, Cristina
Journal of the American Chemical Society, ISSN 0002-7863, 05/2017, Volume 139, Issue 20, pp. 6835 - 6838
An intermolecular, three-component reductive dicarbofunctionalization of alkenes is presented here. The combination of Ni catalysis with TDAE as final... 
BORONIC ACIDS | HALIDES | COUPLING REACTIONS | ARYL IODIDES | RADICALS | REDOX-ACTIVE ESTERS | INTERMOLECULAR TRIFLUOROMETHYLARYLATION | ALKYL BROMIDES | ELECTROPHILES | CHEMISTRY, MULTIDISCIPLINARY | TERMINAL ALKENES | Metal catalysts | Olefins | Chemical bonds | Nickel | Chemical properties | Research | Electrophiles
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9. Full Text Enantioselective Palladium(II)‐Catalyzed Intramolecular Aminoarylation of Alkenes by Dual N−H and Aryl C−H Bond Cleavage
by Zhang, Wen and Chen, Pinhong and Liu, Guosheng
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2017, Volume 56, Issue 19, pp. 5336 - 5340
An asymmetric palladium‐catalyzed intramolecular oxidative aminoarylation of alkenes has been developed with quinoline–oxazoline chiral ligands and Ag 2 CO 3... 
aminoarylation | palladium | asymmetric catalysis | alkenes | heterocycles | OXIDATION | PALLADIUM-CATALYZED CARBOAMINATION | OXAZOLINE LIGANDS | CHEMISTRY, MULTIDISCIPLINARY | UNACTIVATED ALKENES | SOLE OXIDANT | AZA-WACKER REACTIONS | HYDROGEN-PEROXIDE | TERMINAL OLEFINS | CYCLIZATION | MOLECULAR-OXYGEN
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10. Full Text Direct Synthesis of 1,4‐Diols from Alkenes by Iron‐Catalyzed Aerobic Hydration and CH Hydroxylation
by Hashimoto, Takuma and Hirose, Daisuke and Taniguchi, Tsuyoshi
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2014, Volume 53, Issue 10, pp. 2730 - 2734
Various 1,4‐diols are easily accessible from alkenes through iron‐catalyzed aerobic hydration. The reaction system consists of a user‐friendly iron... 
radical reactions | CH oxygenation | iron catalysis | oxygen | synthetic methods | C-H oxygenation | CH oxygenation | OXIDATION | COMPLEXES | MULTIFUNCTIONALIZATION | CHEMISTRY, MULTIDISCIPLINARY | UNACTIVATED ALKENES | FUNCTIONALIZATION | ALCOHOLS | BONDS | TERMINAL OLEFINS | EFFICIENT | MOLECULAR-OXYGEN | Alcohols - chemistry | Alkenes - chemistry | Hydroxylation | Iron - chemistry | Alcohols - chemical synthesis | Molecular Structure | Catalysis | Synthesis | Hydration | Alkenes | Accessibility | Transformations | Iron | Radicals
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11. Full Text An Alternative Mechanism for the Cobalt‐Catalyzed Isomerization of Terminal Alkenes to (Z)‐2‐Alkenes
by Schmidt, Anastasia and Nödling, Alexander R and Hilt, Gerhard
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2015, Volume 54, Issue 3, pp. 801 - 804
The cobalt‐catalyzed selective isomerization of terminal alkenes to the thermodynamically less‐stable (Z)‐2‐alkenes at ambient temperatures takes place by a... 
cobalt | stereoselectivity | alkenes | isomerization | double‐bond migration | Stereoselectivity | Alkenes | Cobalt | Isomerization | Double-bond migration | COMPLEXES | OLEFINS | double-bond migration | CHEMISTRY, MULTIDISCIPLINARY | 1-ALKENES | Thermodynamics | Hydrogen | Olefins | Ambient temperature | Ligands | Formations | Materials selection | Hydrogen atoms | Terminals
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12. Full Text Diastereoselective [3+2] Annulation of Aromatic/Vinylic Amides with Bicyclic Alkenes through Cobalt‐Catalyzed C−H Activation and Intramolecular Nucleophilic Addition
by Gandeepan, Parthasarathy and Rajamalli, Pachaiyappan and Cheng, Chien‐Hong
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2016, Volume 55, Issue 13, pp. 4308 - 4311
A highly diastereoselective method for the synthesis of dihydroepoxybenzofluorenone derivatives from aromatic/vinylic amides and bicyclic alkenes is described.... 
amides | cobalt | annulation | C−H activation | alkenes | C-H activation | ORGANIC-SYNTHESIS | BOND FUNCTIONALIZATION | SELECTIVE ACCESS | TERMINAL ALKYNES | INTERNAL ALKYNES | TRANSITION-METALS | CHEMISTRY, MULTIDISCIPLINARY | DIRECTING GROUPS | MILD | N-CARBAMOYL INDOLINES | CYCLIZATION | Amides | Cobalt | Olefins | Organic chemistry | Transformation | Cycloaddition | Alkenes | Hydrogen bonds | Chemical reactions | Activation | Functional groups
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