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tmeda (104) 104
chemistry, inorganic & nuclear (55) 55
chemistry, organic (46) 46
chemistry, multidisciplinary (38) 38
complexes (37) 37
chemistry (27) 27
lithium (20) 20
crystal-structure (18) 18
crystal-structures (15) 15
ligands (15) 15
lithiation (12) 12
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spectroscopy (10) 10
tetramethylethylenediamine tmeda (10) 10
zinc (10) 10
iron (9) 9
molecular-structure (9) 9
ray crystal-structure (9) 9
analysis (8) 8
catalysis (8) 8
crystal structures (8) 8
cucl-tmeda (8) 8
deprotonation (8) 8
indium (8) 8
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index medicus (7) 7
ligand (7) 7
polymerization (7) 7
pyridine (7) 7
reactivity (7) 7
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activation (6) 6
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iodine (6) 6
molecular structure (6) 6
n,n,n',n'-tetramethylethylenediamine (6) 6
organic-synthesis (6) 6
organolithium compounds (6) 6
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amides (5) 5
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nitrogen (5) 5
organic chemistry (5) 5
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research (5) 5
tetramethylethylenediamine (5) 5
tmeda complexes (5) 5
acid (4) 4
acylation (4) 4
aldehydes (4) 4
alkyllithium compounds (4) 4
amine complexes (4) 4
aryl grignard-reagents (4) 4
bromide (4) 4
catalytic asymmetric acylation (4) 4
complex (4) 4
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copper (4) 4
cross coupling (4) 4
ethylendiamin (4) 4
gallium (4) 4
k dy chemistry (4) 4
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metal (4) 4
n-allyl-n-benzyl-2,2-dihaloamides (4) 4
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Bioorganic and Medicinal Chemistry Letters, ISSN 0960-894X, 01/2014, Volume 24, Issue 1, pp. 99 - 102
Bis-alkylated derivatives of N,N,N′,N′- tetramethylethylenediamine (TMEDA) represent a well-known class of versatile biscationic amphiphiles, owing to their... 
Asymmetric | Amphiphile | TMEDA | Antibacterial | Antiseptic
Journal Article
Inorganica Chimica Acta, ISSN 0020-1693, 01/2012, Volume 380, Issue 1, pp. 161 - 166
The preparation of the second generation iron(II) complex Fe(hfa) ·TMEDA (hfa = 1,1,1,5,5,5-hexafluoro-2,4-pentanedionate, TMEDA =... 
CVD | Precursors | TMEDA | Fe(hfa)
Journal Article
Carbohydrate Polymers, ISSN 0144-8617, 02/2020, Volume 229, p. 115572
[Display omitted] •A high yield of CNCs-COOH was achieved based on the modified APS method.•Activation of APS and ultrasonic assisted disintegration were... 
Activation of ammonium persulfate | Ultrasound | Carboxylated cellulose nanocrystals | N,N, N’,N’-tetramethylethylenediamine (TMEDA) | ACTIVATION | POLYMER SCIENCE | MECHANISM | STRATEGY | CHEMISTRY, ORGANIC | ACID HYDROLYSIS | N,N, N',N'-tetramethylethylenediamine (TMEDA) | WASTE | EXTRACTION | REMOVAL | SYSTEMS | CHEMISTRY, APPLIED | RESIDUES | WATER
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 06/2014, Volume 136, Issue 25, pp. 9132 - 9143
While iron-bisphosphines have emerged as effective catalysts for C-C cross-coupling, the nature of the in situ formed iron species, elucidation of the active... 
SQUARE-PLANAR | PHOSPHINE | COMPLEXES | ARYL-GRIGNARD-REAGENTS | TMEDA | LIGAND | CHEMISTRY, MULTIDISCIPLINARY | ALKYL-HALIDES | Density functionals | Usage | Catalysis | Electron configuration | Research | Analysis
Journal Article
Chemical Communications, ISSN 1359-7345, 01/2016, Volume 52, Issue 7, pp. 1466 - 1469
In comparison to iron(II) halides, iron(II) triflate exhibits a greater resistance towards reduction by p-tolylmagnesiumbromide. This knowledge has led to the... 
REACTIVITY | TMEDA | MAGNESIUM REAGENTS | CHEMISTRY, MULTIDISCIPLINARY | GRIGNARD-REAGENTS | ALKYL-HALIDES | COBALT
Journal Article
Dalton transactions (Cambridge, England : 2003), ISSN 1477-9226, 10/2016, Volume 45, Issue 40, pp. 15811 - 15817
The application of a variety of iron complexes with chelating amine ligands as pre-catalysts in the representative cross-coupling of 4-tolylmagnesium bromide... 
Journal Article
Organometallics, ISSN 0276-7333, 12/2018, Volume 37, Issue 23, pp. 4473 - 4480
Deprotonation of 1,3-dimethyl-2-methyleneimidazole (MeNHO) by nBuLi in hexane/benzene is fast and clean and gave a precipitate of the product in which the... 
CATALYSIS | LIGANDS | STABLE CARBENES | COMPLEXES | CHEMISTRY | CHEMISTRY, ORGANIC | COORDINATION | BOND ACTIVATION | POLYMERIZATION | TMEDA | ACCESS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Nature Communications, ISSN 2041-1723, 02/2016, Volume 7, Issue 1, p. 10614
In past decades, catalytic cross-coupling reactions between organic halides and organometallic reagents to construct carbon-carbon bond have achieved a... 
CHIRAL TETRAPHENYLENES | PALLADIUM | MULTIDISCIPLINARY SCIENCES | EFFICIENT SYNTHESIS | TMEDA | DERIVATIVES | GRIGNARD-REAGENTS | ARYL CHLORIDES | ALKYL-HALIDES
Journal Article
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, ISSN 1386-1425, 03/2020, Volume 229, p. 117938
A series of new three heteroleptic complexes of the general formula [Ln(Cn)(TMEDA)Cl(OH2)]·2Cl·xH2O, (where Ln = La(III), Er(III) and Yb(III), Cn = cocaine and... 
Antimetastatic effect | Cell oxidative stress | Cocaine | TMEDA | p21 and p27 tumor suppressor proteins | Heteroleptic complexes | TD-DFT | Apoptosis
Journal Article
by Yu, J and Baek, SW and Cho, SJ
ENERGIES, ISSN 1996-1073, 09/2019, Volume 12, Issue 17, p. 3208
N,N,N ' ,N ' -Tetramethylethylenediamine (TMEDA) is one of the candidate substances of hydrazine for hypergolic bipropellant applications. In this study, two... 
1 | 2 | 4-triazole | droplet | ENERGY & FUELS | ELEVATED PRESSURES | N '-Tetramethylethylenediamine (TMEDA) | decomposition | evaporation | N | Temperature | Toxicity | Rocket engines | Decomposition | Evaporation | Fuels | Pixels | Evaporation rate | Triazoles | Research methodology | Delay time | Propellant injection | Droplets | Combustion chambers | Propulsion systems | N,N,N′,N′-Tetramethylethylenediamine (TMEDA) | 1,2,4-triazole
Journal Article
Inorganica Chimica Acta, ISSN 0020-1693, 01/2012, Volume 380, pp. 161 - 166
A diamine adduct of Fe(II) hexafluoroacetylacetonate has been synthesized and characterized by an unprecedent joint theoretical and experimental approach. For... 
CVD | Fe(hfa)2·TMEDA | Precursors | Fe2O3 | CHEMICAL-VAPOR-DEPOSITION | PERFORMANCE | ELECTRODES | NANOSTRUCTURES | CHEMISTRY, INORGANIC & NUCLEAR | Fe(hfa)center dot TMEDA | ULTRASONIC SPRAY-PYROLYSIS | SPECTROSCOPY | GROWTH | OXIDE-FILMS | GAS-SENSING PROPERTIES | CATALYSTS
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 11/2014, Volume 53, Issue 21, pp. 11351 - 11353
Copper polyamine complexes are among the most utilized catalysts for controlled radical polymerization reactions. Copper(I) complexes may react reversibly with... 
CUCL-TMEDA | REARRANGEMENT | RATE COEFFICIENTS | ACTIVATION | EQUILIBRIUM-CONSTANTS | POLYMERIZATION | N-ALLYL-N-BENZYL-2,2-DIHALOAMIDES | ATRP | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Tetrahedron, ISSN 0040-4020, 08/2012, Volume 68, Issue 32, pp. 6463 - 6471
It is presented that a number of o-2-hydroxyalkylanisoles could be efficiently synthesized through the regioselective ring-opening reaction of epoxides with... 
Catalytic TMEDA | DoM | Ortho-lithiation | Epoxide opening | OEt
Journal Article
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 04/2017, Volume 53, Issue 33, pp. 4589 - 4592
A practical preparation of the reagent PMDTALi using a super base system under mild conditions has been developed. This PMDTALi base has been demonstrated to... 
ORGANIC-SYNTHESIS | ACTIVATION | REAGENTS | NMR-SPECTROSCOPY | ALKYLATION | COMPOUND | CRYSTAL-STRUCTURES | TMEDA | LITHIUM | ORGANOLITHIUM COMPOUNDS | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Chemical Communications, ISSN 1359-7345, 2017, Volume 53, Issue 2, pp. 324 - 327
After isolating an unusual binuclear, but monosolvated NaHMDS complex [{(R,R)-TMCDA}center dot(NaHMDS)(2)](infinity) which polymerises via intermolecular... 
ASYMMETRIC CATALYSIS | DONOR | BROMINE-LITHIUM EXCHANGE | COMPLEXES | CRYSTAL-STRUCTURES | N-BUTYLLITHIUM | TMEDA | LIGAND | HEXAMETHYLDISILAZIDES | CHEMISTRY, MULTIDISCIPLINARY | ZINC
Journal Article
Dalton Transactions, ISSN 1477-9226, 2016, Volume 45, Issue 40, pp. 15811 - 15817
The application of a variety of iron complexes with chelating amine ligands as pre-catalysts in the representative cross-coupling of 4-tolylmagnesium bromide... 
ARYL GRIGNARD-REAGENTS | BENZYL | ALKENYL HALIDES | COMPLEXES | TMEDA | DERIVATIVES | ALKYL-HALIDES | CHEMISTRY, INORGANIC & NUCLEAR | Chelating | Cross coupling | Amines | Bromides | Magnesium chloride | Ligands | Iron | Chelates
Journal Article
Chemical Communications: Chem Comm, ISSN 1359-7345, 01/2015, Volume 51, Issue 11, pp. 2111 - 2113
A protocol for the coupling of 3-iodoazetidines with Grignard reagents in the presence of an iron catalyst has been developed. A variety of aryl, heteroaryl,... 
Synthesis (chemistry) | Cross coupling | Catalysts | Aromatic compounds | Reagents | Pharmacology | Iron | Coupling
Journal Article
Tetrahedron, ISSN 0040-4020, 08/2012, Volume 68, Issue 32, pp. 6463 - 6471
It is presented that a number of o-2-hydroxyalkylanisoles could be efficiently synthesized through the regioselective ring-opening reaction of epoxides with... 
DoM | Catalytic TMEDA | BF3·OEt2 | Ortho-lithiation | Epoxide opening
Journal Article
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