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ORGANIC LETTERS, ISSN 1523-7060, 04/2019, Volume 21, Issue 8, pp. 2679 - 2683
A new robust methodology for gram-scale iron-catalyzed cross-coupling between alkyl Grignard reagents and alkenyl or aryl halides is developed. This method... 
CHLORIDES | CHEMISTRY, ORGANIC | REDUCTION | TOSYLATES
Journal Article
Organic Letters, ISSN 1523-7060, 02/2011, Volume 13, Issue 3, pp. 510 - 513
Aryl nonaflates are employed as electrophiles in the Pd-catalyzed cross-coupling with tosylhydrazones affording di-, tri-, and tetrasubstituted olefins. Fine... 
HALIDES | CHEMISTRY, ORGANIC | METAL | SERTRALINE | TOSYLATES
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 05/2009, Volume 2009, Issue 14, pp. 2251 - 2261
Catalytic activities of NHC-derived nickel-pincer complexes for the Suzuki-Miyaura coupling reactions of aryl/alkenyl to-sylates and mesylates are described.... 
Pincer complexes | Carbene ligands | Nickel | Cross-coupling | ROOM-TEMPERATURE | VINYL TOSYLATES | ARYL MESYLATES | TERMINAL ACETYLENES | CHEMISTRY, ORGANIC | ACTIVATED ALKENYL TOSYLATES | ARYLBORONIC ACIDS | ENOL TOSYLATES | ORGANOZINC REAGENTS | CROSS-COUPLINGS | 4-SUBSTITUTED 2(5H)-FURANONES
Journal Article
Organic Letters, ISSN 1523-7060, 2008, Volume 10, Issue 21, pp. 4971 - 4974
The combination of palladium acetate with XPhos shows high efficiency in the Hiyama cross-coupling reactions of aryl mesylates with arylsilanes. The reactions... 
HALIDES | ROOM-TEMPERATURE | EFFICIENT CATALYST | VINYL TOSYLATES | 4-SUBSTITUTED COUMARINS | TERMINAL ACETYLENES | CHEMISTRY, ORGANIC | ACTIVATED ALKENYL TOSYLATES | ARYLBORONIC ACIDS | SUZUKI-MIYAURA | ENOL TOSYLATES
Journal Article
Asian Journal of Chemistry, ISSN 0970-7077, 2018, Volume 30, Issue 3, pp. 505 - 507
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 10/2016, Volume 138, Issue 42, pp. 13862 - 13865
Alkyl oxalates, prepared from their corresponding alcohols, are engaged for the first time as carbon radical fragments in metallaphotoredox catalysis. In this... 
MERGING PHOTOREDOX | NICKEL CATALYSIS | VISIBLE-LIGHT PHOTOREDOX | DECARBOXYLATIVE ARYLATION | PHOTOCATALYSIS | BROMIDES | MERGER | CHEMISTRY, MULTIDISCIPLINARY | CARBOXYLIC-ACIDS | ALKYL-HALIDES | TOSYLATES
Journal Article
Organic Letters, ISSN 1523-7060, 09/2016, Volume 18, Issue 17, pp. 4284 - 4287
A robust copper-catalyzed or transition-metal-free cross-coupling of gem-difluoroalkenes with tertiary, secondary, and primary alkyl Grignard reagents has been... 
ALKENYL HALIDES | COMPLEXES | ARENES | CHEMISTRY, ORGANIC | COPPER | F BOND ACTIVATION | FLUORIDES | ACCESS | TOSYLATES
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 11/2008, Volume 130, Issue 44, pp. 14422 - 14423
The first cross-coupling of acylated phenol derivatives has been achieved. In the presence of an air-stable Ni(II) complex, readily accessible aryl pivalates... 
HALIDES | ARENESULFONATES | MESYLATES | COMPLEXES | BOND | CHEMISTRY, MULTIDISCIPLINARY | ARYLBORONIC ACIDS | TOSYLATES | Phenols | Nickel | Catalysis | Chemical properties | Analysis | Acylation
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 04/2011, Volume 133, Issue 15, pp. 6061 - 6071
A new technique for the ex situ generation of carbon monoxide (CO) and its efficient incorporation in palladium catalyzed carbonylation reactions was achieved... 
CROSS-COUPLING REACTIONS | ARYL BORONIC ACIDS | CARBONYLATION REACTIONS | CARBON-MONOXIDE | MICROWAVE-PROMOTED AMINOCARBONYLATION | CONVENIENT METHOD | PYRIDINE HALIDES | ELECTRON-RICH OLEFINS | CHEMISTRY, MULTIDISCIPLINARY | ATMOSPHERIC-PRESSURE | HETEROAROMATIC TOSYLATES
Journal Article
ACCOUNTS OF CHEMICAL RESEARCH, ISSN 0001-4842, 11/2008, Volume 41, Issue 11, pp. 1545 - 1554
Transition metal-catalyzed cross-coupling reactions of organic halides and pseudo-halides containing a C-X bond (X = 1, Br, Cl, OTf, OTs, etc.) with... 
ORGANOMETALLIC COMPOUNDS | PALLADIUM | NICKEL | CHLORIDES | BOND FORMATION | ELIMINATION | TRANSITION-METAL ALLYLS | COPPER | SUBSTITUTION-REACTIONS | CHEMISTRY, MULTIDISCIPLINARY | TOSYLATES
Journal Article
Organic Letters, ISSN 1523-7060, 04/2015, Volume 17, Issue 8, pp. 1942 - 1945
Aryl fluorosulfates were prepared by a simple method and employed as coupling partners in the Suzuki-Miyaura reaction. The cross-coupling reactions were... 
OXYGEN | CROSS-COUPLING REACTIONS | MIYAURA REACTIONS | ETHERS | MESYLATES | EFFICIENT SYNTHESIS | CHEMISTRY, ORGANIC | CARBON-CARBON BONDS | TOSYLATES | BIARYLS
Journal Article
Organic Process Research and Development, ISSN 1083-6160, 01/2013, Volume 17, Issue 1, pp. 29 - 39
This review describes our laboratory's efforts to develop transition metal-catalyzed cross-couplings of several unconventional phenol-based electrophiles.... 
BORONIC ACIDS | ARYL GRIGNARD-REAGENTS | O BOND ACTIVATION | AMINATION | DIRECTED ORTHO-METALATION | ONE CENTURY | CARBON-OXYGEN | CHEMISTRY, ORGANIC | SELECTIVE METHOD | CHEMISTRY, APPLIED | OXIDATIVE ADDITION | TOSYLATES
Journal Article
Journal of Physical Organic Chemistry, ISSN 0894-3230, 01/2017, Volume 30, Issue 1, pp. e3585 - n/a
A simple linear regression ( Q equation) is devised to position solvolyses within the established S N 2‐S N 1 spectrum of solvolysis mechanisms. Using... 
acid chlorides | solvolysis | kinetics | mechanistic spectrum | tosylates
Journal Article
Chemical Society Reviews, ISSN 0306-0012, 10/2011, Volume 40, Issue 10, pp. 4963 - 4972
Palladium-catalyzed cross-coupling reactions are state-of-the art methods for synthesis of many important compounds. The development of the use of the... 
HALIDES | SYSTEM | ROOM-TEMPERATURE | AMINATION | HETEROARYL TOSYLATES | ARENESULFONATES | CHLORIDES | METAL | CHEMISTRY, MULTIDISCIPLINARY | SUZUKI-MIYAURA | ARYLBORONIC ACIDS | Joining | Synthesis | Aromatic compounds | Halides | Hydroxyl groups | Organic compounds
Journal Article
Organic Letters, ISSN 1523-7060, 10/2016, Volume 18, Issue 19, pp. 4770 - 4773
We developed an efficient synthesis of alkenyl sulfonates via hydrogen bonding cluster-enabled addition of sulfonic acids to haloalkynes. The reactivity of... 
PALLADIUM-CATALYZED BROMOALKYNYLATION | CHEMISTRY, ORGANIC | TERMINAL ALKYNES | ARYL | EFFICIENT | TOSYLATES | ENYNES
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 09/2015, Volume 137, Issue 36, pp. 11562 - 11565
A mild Ni-catalyzed reductive arylation of tertiary alkyl halides with aryl bromides has been developed that delivers products bearing all-carbon quaternary... 
CONCISE TOTAL-SYNTHESIS | ALPHA-ARYLATION | KETONE FORMATION | ALLYLATION | UNACTIVATED PRIMARY | SECONDARY | ORGANIC HALIDES | CARBOXYLATION | CHEMISTRY, MULTIDISCIPLINARY | GRIGNARD-REAGENTS | TOSYLATES | Arylation | Usage | Chemical properties | Metal catalysts | Halides | Isomerization
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 02/2018, Volume 140, Issue 7, pp. 2446 - 2449
The synthesis of highly substituted 1,3-dienes from the coupling of vinyl bromides with vinyl triflates is reported for the first time. The coupling is... 
ACIDS | SELECTIVE SYNTHESIS | ARYL | VINYL HALIDES | BROMIDES | EFFICIENT | CHEMISTRY, MULTIDISCIPLINARY | TOSYLATES
Journal Article
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