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1. Full Text Gram-Scale, Cheap, and Eco-Friendly Iron-Catalyzed Cross-Coupling between Alkyl Grignard Reagents and Alkenyl or Aryl Halides
by Cahiez, G and Lefevre, G and Moyeux, A and Guerret, O and Gayon, E and Guillonneau, L and Lefevre, N and Gu, QZ and Zhou, E
ORGANIC LETTERS, ISSN 1523-7060, 04/2019, Volume 21, Issue 8, pp. 2679 - 2683
A new robust methodology for gram-scale iron-catalyzed cross-coupling between alkyl Grignard reagents and alkenyl or aryl halides is developed. This method... 
CHLORIDES | CHEMISTRY, ORGANIC | REDUCTION | TOSYLATES
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2. Full Text Room temperature nickel(II) complexes [(4-MeOC6H 4)Ni(PCy3)2OTs and Ni(PCy3) 2X2]-catalyzed cross-coupling reactions of aryl/alkenyl sulfonates with arylboronic acids
by Xing, Chun-Hui and Lee, Jeng-Ru and Tang, Zhen-Yu and Zheng, Jin Rong and Hu, Qiao-Sheng
Advanced Synthesis and Catalysis, ISSN 1615-4150, 08/2011, Volume 353, Issue 11-12, pp. 2051 - 2059
Room temperature nickel(II) complexes [(4-MeOC6H4)Ni(PCy3)(2)OTs and Ni(PCy3)(2)X-2 (X=Cl, Br)]-catalyzed cross-coupling reactions of aryl/alkenyl sulfonates... 
cross-coupling | nickel(II) complexes | aryl arenesulfonates | arylboronic acids | alkenyl tosylates | CHEMISTRY, ORGANIC | ACTIVATED ALKENYL TOSYLATES | ENOL TOSYLATES | PALLADIUM-CATALYZED AMINATION | GRAPHITE NI/C-G | ORGANOZINC REAGENTS | BORONIC ACIDS | ARYL TOSYLATES | EFFICIENT CATALYST | PHOSPHINE-LIGANDS | CHEMISTRY, APPLIED | 4-SUBSTITUTED 2(5H)-FURANONES | Availability | Synthesis | Catalysts | Aromatic compounds | Joining | Sulfonates | Catalysis | Constraining
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3. Full Text Synthesis of polysubstituted olefins by Pd-catalyzed cross-coupling reaction of tosylhydrazones and aryl nonaflates
by Barluenga, José and Florentino, Lucía and Aznar, Fernando and Valdés, Carlos
Organic Letters, ISSN 1523-7060, 02/2011, Volume 13, Issue 3, pp. 510 - 513
Aryl nonaflates are employed as electrophiles in the Pd-catalyzed cross-coupling with tosylhydrazones affording di-, tri-, and tetrasubstituted olefins. Fine... 
HALIDES | CHEMISTRY, ORGANIC | METAL | SERTRALINE | TOSYLATES
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4. Full Text N-heterocyclic carbene derived Nickel-Pincer complexes: Efficient and applicable catalysts for Suzuki-Miyaura coupling reactions of aryl/alkenyl tosylates and mesylates
by Kuroda, Jun-Ichi and Inamoto, Kiyofumi and Hiroya, Kou and Doi, Takayuki
European Journal of Organic Chemistry, ISSN 1434-193X, 05/2009, Volume 2009, Issue 14, pp. 2251 - 2261
Catalytic activities of NHC-derived nickel-pincer complexes for the Suzuki-Miyaura coupling reactions of aryl/alkenyl to-sylates and mesylates are described.... 
Pincer complexes | Carbene ligands | Nickel | Cross-coupling | ROOM-TEMPERATURE | VINYL TOSYLATES | ARYL MESYLATES | TERMINAL ACETYLENES | CHEMISTRY, ORGANIC | ACTIVATED ALKENYL TOSYLATES | ARYLBORONIC ACIDS | ENOL TOSYLATES | ORGANOZINC REAGENTS | CROSS-COUPLINGS | 4-SUBSTITUTED 2(5H)-FURANONES
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5. Full Text Palladium-catalyzed hiyama cross-coupling reactions of aryl mesylates
by Zhang, Liang and Qing, Jiang and Yang, Pengyuan and Wu, Jie
Organic Letters, ISSN 1523-7060, 2008, Volume 10, Issue 21, pp. 4971 - 4974
The combination of palladium acetate with XPhos shows high efficiency in the Hiyama cross-coupling reactions of aryl mesylates with arylsilanes. The reactions... 
HALIDES | ROOM-TEMPERATURE | EFFICIENT CATALYST | VINYL TOSYLATES | 4-SUBSTITUTED COUMARINS | TERMINAL ACETYLENES | CHEMISTRY, ORGANIC | ACTIVATED ALKENYL TOSYLATES | ARYLBORONIC ACIDS | SUZUKI-MIYAURA | ENOL TOSYLATES
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6. Full Text Heck coupling with nonactivated alkenyl tosylates and phosphates: Examples of effective 1,2-migrations of the alkenyl palladium(II) intermediates
by Hansen, Anders L and Ebran, Jean-Philippe and Ahlquist, Mårten and Norrby, Per-Ola and Skrydstrup, Troels and Teoretisk kemi och biologi and Skolan för bioteknologi (BIO) and KTH
Angewandte Chemie - International Edition, ISSN 1433-7851, 05/2006, Volume 45, Issue 20, pp. 3349 - 3353
Phosphates | Heck reaction | Tosylates | Alkenes | 1,2-migration | NITROGEN-CONTAINING HETEROCYCLES | CONVENIENT SYNTHESIS | ASYMMETRIC-SYNTHESIS | tosylates | alkenes | OXIDATIVE ADDITION | CHEMISTRY, MULTIDISCIPLINARY | ARYLBORONIC ACIDS | ENOL TOSYLATES | ARYL TOSYLATES | VINYL PHOSPHATES | phosphates | CATALYZED CROSS-COUPLINGS | HETEROARYL BORONIC ACIDS | Alkenes - chemistry | Vinyl Compounds - chemistry | Cations, Divalent | Models, Chemical | Phosphates - chemistry | Tosyl Compounds - chemistry | Catalysis | Isomerism | Palladium - chemistry | Index Medicus | Naturvetenskap | Natural Sciences | Organisk kemi | Kemi | Chemical Sciences | Organic Chemistry
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7. Full Text Palladium catalyzed Mizoroki–Heck reaction of pyrimidin-2-yl tosylates with aromatic and aliphatic olefins
by Gong, Hai-Peng and Quan, Zheng-Jun and Wang, Xi-Cun
Tetrahedron, ISSN 0040-4020, 04/2016, Volume 72, Issue 16, pp. 2018 - 2025
Pyrimidin-2-yl tosylates which are successfully applied as the electrophiles instead of halides coupled with olefins via Pd(PPh ) Cl catalyzed Mizoroki–Heck... 
Mizoroki–Heck coupling | Acrylates | Pyrimidin-2-yl tosylates | Styrenes | Palladium catalysis | Mizoroki-Heck coupling | ARYL GRIGNARD-REAGENTS | ROOM-TEMPERATURE | BIGINELLI DIHYDROPYRIMIDINE SYNTHESIS | EFFICIENT APPROACH | Pyrimidin-2-y1 tosylates | CHEMISTRY, ORGANIC | ARYLBORONIC ACIDS | CROSS-COUPLING REACTIONS | CARBON-OXYGEN BONDS | ELECTRON-RICH OLEFINS | C2-FUNCTIONALIZED PYRIMIDINES | HETEROAROMATIC TOSYLATES | Substitution reactions | Pyrimidines | Palladium | Acrylonitrile | Olefins | Tetrahedrons | Chemical reactions | Vinyl ethers | Derivatives | Aliphatic compounds
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8. Facile synthesis of polysubstituted cyclopropanes using α-tosyloxyketones
by Rana, Neena and Nain, Sonia and Kumar, Dinesh and Kumar, Ravi
Asian Journal of Chemistry, ISSN 0970-7077, 2018, Volume 30, Issue 3, pp. 505 - 507
Arylidenemalononitrile | α-Tosyloxyketones | Pyridinium tosylates
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9. Full Text Alcohols as Latent Coupling Fragments for Metallaphotoredox Catalysis: sp(3)-sp(2) Cross-Coupling of Oxalates with Aryl Halides
by Zhang, XH and MacMillan, DWC
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 10/2016, Volume 138, Issue 42, pp. 13862 - 13865
Alkyl oxalates, prepared from their corresponding alcohols, are engaged for the first time as carbon radical fragments in metallaphotoredox catalysis. In this... 
MERGING PHOTOREDOX | NICKEL CATALYSIS | VISIBLE-LIGHT PHOTOREDOX | DECARBOXYLATIVE ARYLATION | PHOTOCATALYSIS | BROMIDES | MERGER | CHEMISTRY, MULTIDISCIPLINARY | CARBOXYLIC-ACIDS | ALKYL-HALIDES | TOSYLATES
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10. Full Text Sterically Controlled Cu-Catalyzed or Transition-Metal-Free Cross-Coupling of gem-Difluoroalkenes with Tertiary, Secondary, and Primary Alkyl Grignard Reagents
by Dai, Wenpeng and Shi, Hongyan and Zhao, Xianghu and Cao, Song
Organic Letters, ISSN 1523-7060, 09/2016, Volume 18, Issue 17, pp. 4284 - 4287
A robust copper-catalyzed or transition-metal-free cross-coupling of gem-difluoroalkenes with tertiary, secondary, and primary alkyl Grignard reagents has been... 
ALKENYL HALIDES | COMPLEXES | ARENES | CHEMISTRY, ORGANIC | COPPER | F BOND ACTIVATION | FLUORIDES | ACCESS | TOSYLATES
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11. Full Text Cross-coupling reactions of aryl pivalates with boronic acids
by Quasdorf, Kyle W and Tian, Xia and Garg, Neil K
Journal of the American Chemical Society, ISSN 0002-7863, 11/2008, Volume 130, Issue 44, pp. 14422 - 14423
The first cross-coupling of acylated phenol derivatives has been achieved. In the presence of an air-stable Ni(II) complex, readily accessible aryl pivalates... 
HALIDES | ARENESULFONATES | MESYLATES | COMPLEXES | BOND | CHEMISTRY, MULTIDISCIPLINARY | ARYLBORONIC ACIDS | TOSYLATES | Phenols | Nickel | Catalysis | Chemical properties | Analysis | Acylation
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12. Full Text Ex Situ Generation of Stoichiometric and Substoichiometric (CO)-C-12 and (CO)-C-13 and Its Efficient Incorporation in Palladium Catalyzed Aminocarbonylations
by Hermange, P and Lindhardt, AT and Taaning, RH and Bjerglund, K and Lupp, D and Skrydstrup, T
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 04/2011, Volume 133, Issue 15, pp. 6061 - 6071
A new technique for the ex situ generation of carbon monoxide (CO) and its efficient incorporation in palladium catalyzed carbonylation reactions was achieved... 
CROSS-COUPLING REACTIONS | ARYL BORONIC ACIDS | CARBONYLATION REACTIONS | CARBON-MONOXIDE | MICROWAVE-PROMOTED AMINOCARBONYLATION | CONVENIENT METHOD | PYRIDINE HALIDES | ELECTRON-RICH OLEFINS | CHEMISTRY, MULTIDISCIPLINARY | ATMOSPHERIC-PRESSURE | HETEROAROMATIC TOSYLATES
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13. Full Text Cross-Coupling Reaction of Alkyl Halides with Grignard Reagents Catalyzed by Ni, Pd, or Cu Complexes with pi-Carbon Ligand(s)
by Terao, J and Kambe, N
ACCOUNTS OF CHEMICAL RESEARCH, ISSN 0001-4842, 11/2008, Volume 41, Issue 11, pp. 1545 - 1554
Transition metal-catalyzed cross-coupling reactions of organic halides and pseudo-halides containing a C-X bond (X = 1, Br, Cl, OTf, OTs, etc.) with... 
ORGANOMETALLIC COMPOUNDS | PALLADIUM | NICKEL | CHLORIDES | BOND FORMATION | ELIMINATION | TRANSITION-METAL ALLYLS | COPPER | SUBSTITUTION-REACTIONS | CHEMISTRY, MULTIDISCIPLINARY | TOSYLATES
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14. Full Text Palladium-catalyzed, ligand-free Suzuki reaction in water using aryl fluorosulfates
by Liang, Qiaobin and Xing, Ping and Huang, Zuogang and Dong, Jiajia and Sharpless, K. Barry and Li, Xiaoxian and Jiang, Biao
Organic Letters, ISSN 1523-7060, 04/2015, Volume 17, Issue 8, pp. 1942 - 1945
Aryl fluorosulfates were prepared by a simple method and employed as coupling partners in the Suzuki-Miyaura reaction. The cross-coupling reactions were... 
OXYGEN | CROSS-COUPLING REACTIONS | MIYAURA REACTIONS | ETHERS | MESYLATES | EFFICIENT SYNTHESIS | CHEMISTRY, ORGANIC | CARBON-CARBON BONDS | TOSYLATES | BIARYLS
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15. Full Text Ni- and Fe-catalyzed cross-coupling reactions of phenol derivatives
by Mesganaw, Tehetena and Garg, Neil K
Organic Process Research and Development, ISSN 1083-6160, 01/2013, Volume 17, Issue 1, pp. 29 - 39
This review describes our laboratory's efforts to develop transition metal-catalyzed cross-couplings of several unconventional phenol-based electrophiles.... 
BORONIC ACIDS | ARYL GRIGNARD-REAGENTS | O BOND ACTIVATION | AMINATION | DIRECTED ORTHO-METALATION | ONE CENTURY | CARBON-OXYGEN | CHEMISTRY, ORGANIC | SELECTIVE METHOD | CHEMISTRY, APPLIED | OXIDATIVE ADDITION | TOSYLATES
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16. Full Text Positioning solvolyses within the SN2‐SN1 and SN3‐SN2 spectrum of reaction mechanisms
by Bentley, T. W and Choi, Hojune and Koo, In Sun and Kevill, Dennis N
Journal of Physical Organic Chemistry, ISSN 0894-3230, 01/2017, Volume 30, Issue 1, pp. e3585 - n/a
A simple linear regression ( Q equation) is devised to position solvolyses within the established S N 2‐S N 1 spectrum of solvolysis mechanisms. Using... 
acid chlorides | solvolysis | kinetics | mechanistic spectrum | tosylates
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17. Full Text Palladium-catalyzed cross-coupling reactions of aryl mesylates
by So, Chau Ming and Kwong, Fuk Yee
Chemical Society Reviews, ISSN 0306-0012, 10/2011, Volume 40, Issue 10, pp. 4963 - 4972
Palladium-catalyzed cross-coupling reactions are state-of-the art methods for synthesis of many important compounds. The development of the use of the... 
HALIDES | SYSTEM | ROOM-TEMPERATURE | AMINATION | HETEROARYL TOSYLATES | ARENESULFONATES | CHLORIDES | METAL | CHEMISTRY, MULTIDISCIPLINARY | SUZUKI-MIYAURA | ARYLBORONIC ACIDS | Joining | Synthesis | Aromatic compounds | Halides | Hydroxyl groups | Organic compounds
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18. Full Text Hydrogen Bonding Cluster-Enabled Addition of Sulfonic Acids to Haloalkynes: Access to Both (E)- and (Z)-Alkenyl Sulfonates
by Zeng, Xiaojun and Liu, Shiwen and Shi, Zhenyu and Xu, Bo
Organic Letters, ISSN 1523-7060, 10/2016, Volume 18, Issue 19, pp. 4770 - 4773
We developed an efficient synthesis of alkenyl sulfonates via hydrogen bonding cluster-enabled addition of sulfonic acids to haloalkynes. The reactivity of... 
PALLADIUM-CATALYZED BROMOALKYNYLATION | CHEMISTRY, ORGANIC | TERMINAL ALKYNES | ARYL | EFFICIENT | TOSYLATES | ENYNES
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19. Full Text Nickel-Catalyzed Reductive Coupling of Aryl Bromides with Tertiary Alkyl Halides
by Wang, Xuan and Wang, Shulin and Xue, Weichao and Gong, Hegui
Journal of the American Chemical Society, ISSN 0002-7863, 09/2015, Volume 137, Issue 36, pp. 11562 - 11565
A mild Ni-catalyzed reductive arylation of tertiary alkyl halides with aryl bromides has been developed that delivers products bearing all-carbon quaternary... 
CONCISE TOTAL-SYNTHESIS | ALPHA-ARYLATION | KETONE FORMATION | ALLYLATION | UNACTIVATED PRIMARY | SECONDARY | ORGANIC HALIDES | CARBOXYLATION | CHEMISTRY, MULTIDISCIPLINARY | GRIGNARD-REAGENTS | TOSYLATES | Arylation | Usage | Chemical properties | Metal catalysts | Halides | Isomerization
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20. Full Text Multimetallic Ni- and Pd-Catalyzed Cross-Electrophile Coupling To Form Highly Substituted 1,3-Dienes
by Olivares, AM and Weix, DJ
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 02/2018, Volume 140, Issue 7, pp. 2446 - 2449
The synthesis of highly substituted 1,3-dienes from the coupling of vinyl bromides with vinyl triflates is reported for the first time. The coupling is... 
ACIDS | SELECTIVE SYNTHESIS | ARYL | VINYL HALIDES | BROMIDES | EFFICIENT | CHEMISTRY, MULTIDISCIPLINARY | TOSYLATES
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