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Angewandte Chemie International Edition, ISSN 1433-7851, 03/2007, Volume 46, Issue 12, pp. 1946 - 1948
...‐workers have obtained the first three‐coordinate boryl anion (see formula), which provides an unprecedented and synthetically highly useful source for a nucleophilic... 
organoboranes | boryl compounds | boron | Boron | Boryl compounds | Organoboranes | SUBSTITUTION | TRANSITION-METAL-COMPLEXES | HYDROBORATIONS | REACTIVITY | CHEMISTRY, MULTIDISCIPLINARY | ALUMINUM | CARBENE ANALOGS | CHEMISTRY | LIGAND | GALLIUM
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2016, Volume 55, Issue 46, pp. 14450 - 14454
.... In the current manuscript, we describe a series of complexes formally containing a phosphine‐stabilized borylene or boryl anion... 
iron | pincer ligands | reduction | boron | density functional theory | ACTIVATION | TRANSITION-METAL-COMPLEXES | CATALYTIC-HYDROGENATION | OXIDATIVE ADDITION | 1,3,2,5-DIAZADIBORININE | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | DIMETALLOBORYLENE COMPLEX | METALLABORATRANES | TRIMETHYLPHOSPHINE | Density functionals | Ligands | Boron
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 09/2013, Volume 19, Issue 40, pp. 13402 - 13407
The synthesis of base‐stabilized boryl and borylene complexes is reported. An N‐heterocyclic carbene (NHC)‐stabilized iron... 
carbenes | borylene complexes | iron | boryl complexes | boron | SUBSTITUTION | COORDINATION SPHERE | REACTIVITY | PLATINUM | STRUCTURAL-CHARACTERIZATION | REACTION CHEMISTRY | CHEMISTRY, MULTIDISCIPLINARY | BOND ACTIVATION | LIGAND | TRANSITION-METAL-BORYL | Methane | Iron | Anions | Synthesis | Cationic | Halides | Lewis base | Carbenes
Journal Article
Organometallics, ISSN 0276-7333, 11/2019, Volume 38, Issue 21, pp. 4183 - 4192
Reactions of complexes RhH­{κ3-P,O,P-[xant­(PiPr2)2]} (1) and Rh­(Bpin)­{κ3-P,O,P-[xant­(PiPr2)2]} (2; Bpin = pinacolboryl, xant­(PiPr2)2 =... 
RHODIUM | IRIDIUM COMPLEXES | POP-PINCER OSMIUM | TRANSITION-METAL | DEHYDROPOLYMERIZATION | CHEMISTRY, ORGANIC | RUTHENIUM | S-SUBSTITUTED ALDEHYDES | C-H BONDS | ACTIVATION REACTIONS | CONJUGATE ADDITION | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Catalysis Science and Technology, ISSN 2044-4753, 5/2014, Volume 4, Issue 6, pp. 1699 - 179
Journal Article
Catalysis Science and Technology, ISSN 2044-4753, 2018, Volume 8, Issue 13, pp. 3395 - 3405
... (DFT) studies. PBP(-H)CoH and DPB(-H)NiH complexes were chosen as representative models for the boryl type and the borane type LA-TM hydride, respectively... 
H-H | DEHYDROGENATION | MECHANISM | LIGANDS | CATALYTIC-HYDROGENATION | COMPLEXES | CHEMISTRY, PHYSICAL | STRUCTURAL-CHARACTERIZATION | BASIS-SETS | H-2 ACTIVATION | CLEAVAGE | Lewis acid | Organic chemistry | Metal hydrides | Electronic structure | Reactivity | Alkenes | Bridging | Chemical reactions | Density functional theory | Product design | Catalysis | Coordination compounds
Journal Article
Synlett, ISSN 0936-5214, 07/2017, Volume 28, Issue 11, pp. 1258 - 1267
Journal Article
Chemical science (Cambridge), ISSN 2041-6520, 01/2016, Volume 7, Issue 1, pp. 803 - 809
The reaction of a half-sandwich scandium boryl complex with CO (1 atm) afforded a novel boryl oxycarbene complex... 
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 04/2008, Volume 130, Issue 16, pp. 5586 - 5594
The detailed mechanism for the diboration of aldehydes catalyzed by (NHC)Cu(boryl) complexes (NHC = N-heterocyclic carbene... 
2-SUBSTITUTED INDOLES | HYDROBORATION | BORON | TRANSITION-METAL-COMPLEXES | IRIDIUM COMPLEXES | COUPLING REACTION | ARENES | REGIOSPECIFIC FUNCTIONALIZATION | BASIS-SET | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS
Journal Article
Chemical Communications, ISSN 1359-7345, 03/2014, Volume 50, Issue 21, pp. 2738 - 2740
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2010, Volume 49, Issue 23, pp. 3947 - 3951
Journal Article
Bulletin of the Chemical Society of Japan, ISSN 0009-2673, 10/2011, Volume 84, Issue 10, pp. 983 - 999
.... Detailed analyses of these boryl anions using NMR spectroscopy, X-ray crystallography, reactivity with electrophiles, and DFT calculations revealed that these compounds have anionic and nucleophilic... 
ASYMMETRIC-SYNTHESIS | TRANSITION-METAL-COMPLEXES | ALLYLIC CARBONATES | X-RAY-STRUCTURE | MOLECULAR-STRUCTURES | ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS | STRUCTURAL-CHARACTERIZATION | OXIDATIVE ADDITION | COPPER(I)-CATALYZED REACTION | CHEMISTRY, MULTIDISCIPLINARY | BETA-BORATION
Journal Article
Organometallics, ISSN 0276-7333, 05/2013, Volume 32, Issue 9, pp. 2744 - 2752
... = trifluoromethanesulfonate) reacts with pinacolborane (HBpin) and catecholborane (HBcat) to give the dihydride boryl osmium(IV) derivatives [OsH2(Bpin)(η6-p-cymene)(IPr)]OTf (2) and [OsH2(Bcat)(η6-p-cymene)(IPr)]OTf (3... 
HETEROCYCLIC CARBENE LIGAND | H BOND ACTIVATION | DICHLOROBORYL COMPLEX | TRANSITION-METAL-COMPLEXES | TRIOSMIUM CARBONYL CLUSTERS | TRIHYDRIDO-SILYL | CRYSTAL-STRUCTURE | METHYL-GROUP | CHEMISTRY, ORGANIC | OXIDATIVE ADDITION | ALKYL-HALIDES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Science China Chemistry, ISSN 1674-7291, 1/2019, Volume 62, Issue 1, pp. 62 - 66
An efficient, transition-metal free, and practical approach to cis-bis(boryl)alkenes from various alkynes was disclosed in the presence of a catalytic amount of K2CO3 under mild conditions... 
Chemistry | diborylation of alkynes | cis -1,2-bis(boryl)alkenes | base-catalyzed | Chemistry/Food Science, general | cis-1,2-bis(boryl)alkenes | NANOPARTICLES | ALKENES | ACTIVATION | cis-1 | FREE BORYLATION | 2-bis(boryl)alkenes | METAL-FREE DIBORATION | EFFICIENT | CHEMISTRY, MULTIDISCIPLINARY | DIBORON
Journal Article