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Journal of the American Chemical Society, ISSN 0002-7863, 07/2005, Volume 127, Issue 29, pp. 10166 - 10167
Deuterio-ethylene labeling studies on two homogeneous chromium ethylene oligomerization catalysts show that chain propagation proceeds via metallacyclic... 
ALPHA-OLEFINS | MECHANISM | TRIAZACYCLOHEXANE COMPLEXES | SELECTIVE TRIMERIZATION | ETHENE TRIMERIZATION | POLYMERIZATION | ETHYLENE TRIMERIZATION | OLIGOMERIZATION | ACTIVE CATALYSTS | CATIONIC GROUP-4 | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
ACS Catalysis, ISSN 2155-5435, 02/2018, Volume 8, Issue 2, pp. 1138 - 1142
Computational design of molecular homogeneous organometallic catalysts followed by experimental realization remains a significant challenge. Here, we report... 
transition-state design | ethylene trimerization | computational predictions | ethylene tetramerization | chromium catalysis | molecular catalysis | COMPLEXES | CHEMISTRY, PHYSICAL | DFT | PREDICT REACTIVITIES | SELECTIVE TRIMERIZATION | CHEMISTRY | ETHENE TRIMERIZATION | DENSITY-FUNCTIONAL THEORY | OLIGOMERIZATION | CHROMIUM CATALYSTS | LIGAND DESIGN
Journal Article
Coordination Chemistry Reviews, ISSN 0010-8545, 2011, Volume 255, Issue 7, pp. 861 - 880
Journal Article
Dalton Transactions, ISSN 1477-9226, 2010, Volume 39, Issue 2, pp. 560 - 567
A series of symmetric and unsymmetric N,N-bis(diarylphosphino)amine ('PNP') ligands (Ar2PN(R)PNAr'(2): R = Me, Ar-2 = o-anisyl, Ar'(2) = Ph, 1, R = Me, Ar-2 =... 
TETRAMERIZATION | COORDINATION CHEMISTRY | ISOPRENE | SELECTIVE TRIMERIZATION | ASSISTED TERPENOID SYNTHESIS | ETHENE TRIMERIZATION | FARNESENE | ETHYLENE TRIMERIZATION | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 02/2004, Volume 126, Issue 5, pp. 1304 - 1305
A system for catalytic trimerization of ethylene utilizing CrCl3(THF)3 and a diphosphine ligand PNPOMe [= (o-MeO-C6H4)2PN(Me)P(o-MeO-C6H4)2] has been... 
SYSTEM | ALPHA-OLEFINS | SELECTIVE TRIMERIZATION | COMPLEXES | ETHENE TRIMERIZATION | 1-HEXENE | LIGAND | CHEMISTRY, MULTIDISCIPLINARY | Chromium | Chemical reactions | Research | Chemical properties | Ethylene
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 06/2013, Volume 135, Issue 24, pp. 8830 - 8833
A heterobimetallic catalyst, {Ti--Cr}, consisting of a constrained-geometry titanium olefin polymerization center (CGCEtTi) covalently linked to a chromium... 
BINUCLEAR CATALYSTS | REACTION-KINETICS | COMPLEXES | COCATALYSTS | OLEFIN POLYMERIZATION | ETHENE TRIMERIZATION | ETHYLENE TRIMERIZATION | METAL OXIDATION-STATE | OLIGOMERIZATION | CHEMISTRY, MULTIDISCIPLINARY | ENCHAINMENT | Measurement | Molecular weights | Chemical reaction, Rate of | Analysis | Polymerization | Titanium | Chemical properties | Structure
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 08/2016, Volume 817, pp. 21 - 25
Journal Article
Chemical Communications, ISSN 1359-7345, 02/2005, Issue 5, pp. 622 - 624
Chromium-based catalyst systems with polar-substituted diphosphinoamine ligands are selective for either trimerisation or tetramerisation of ethylene,... 
MECHANISM | CHEMISTRY, MULTIDISCIPLINARY | SELECTIVE TRIMERIZATION | COMPLEXES
Journal Article
Organometallics, ISSN 0276-7333, 08/2009, Volume 28, Issue 15, pp. 4613 - 4616
Ligand backbone alkylation of the complex [Cr(CO)4(dppm)] (dppm = bis(diphenylphosphino)methane) with alkyl iodides yields the C-substituted dppm ligand... 
TETRAMERIZATION | CHEMISTRY, ORGANIC | ETHENE TRIMERIZATION | TRIMERIZATION CATALYSTS | COMPLEXES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Organometallics, ISSN 0276-7333, 06/2010, Volume 29, Issue 11, pp. 2394 - 2396
New Ti complexes bearing phenoxy−imine ligands with pendant aryl−OMe donors have been developed for ethylene trimerization to produce 1-hexene. These Ti... 
OLEFIN POLYMERIZATION CATALYSTS | FI CATALYSTS | MECHANISM | SELECTIVE TRIMERIZATION | ZIRCONIUM COMPLEXES | CHEMISTRY, ORGANIC | ETHENE TRIMERIZATION | METAL OXIDATION-STATE | OLIGOMERIZATION | COPOLYMERIZATION | CHROMIUM CATALYSTS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Organometallics, ISSN 0276-7333, 05/2015, Volume 34, Issue 9, pp. 1604 - 1607
Oxidative cyclization of tetrafluoroethylene (TFE) and ethylene with Ni(0) resulted in the formation of a five membered nickelacycle. In the presence of PPh3,... 
ACTIVATION | AZA-NICKELACYCLE | COUPLING REACTIONS | SELECTIVE TRIMERIZATION | CHEMISTRY, ORGANIC | 2+2+2 CYCLOADDITION | ETHYLENE TRIMERIZATION | ALKYNES | ETHENE | VALENT METAL-COMPLEXES | PLATINUM COMPLEXES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Organometallics, ISSN 0276-7333, 07/2011, Volume 30, Issue 13, pp. 3549 - 3558
To gain a deeper knowledge of the nature of the species formed in situ by reaction of a catalyst precursor complex and typical cocatalysts used for ethylene... 
OLEFIN POLYMERIZATION CATALYSTS | ALPHA-OLEFINS | TETRAMERIZATION CATALYST | SELECTIVE TRIMERIZATION | BIS(CARBENE)PYRIDINE COMPLEXES | CHEMISTRY, ORGANIC | ETHENE TRIMERIZATION | BRIDGED DIPHOSPHINE LIGAND | METAL OXIDATION-STATE | TRIMERIZATION CATALYSTS | ORGANOCHROMIUM CHEMISTRY | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
ACS Catalysis, ISSN 2155-5435, 12/2015, Volume 5, Issue 12, pp. 7095 - 7098
1-Phosphanyl methanimine ligands, R2P–C­(Ph)NR′, may be prepared via a modular, convergent synthesis in good overall yield. Coordination chemistry studies... 
chromium | oligomerization | α-olefins | P,N-ligands | tetramerization | trimerization | catalysis | ethylene | MECHANISTIC INVESTIGATIONS | COMPLEXES | TRI-/TETRAMERIZATION | CHEMISTRY, PHYSICAL | COORDINATION | SUBSTITUTED DIPHOSPHINOAMINE LIGANDS | ETHENE TRIMERIZATION | CATALYST SYSTEM | alpha-olefins
Journal Article
Journal of Catalysis, ISSN 0021-9517, 10/2019, Volume 378, pp. 312 - 319
Journal Article
Chemical Communications, ISSN 1359-7345, 02/2003, Volume 9, Issue 3, pp. 334 - 335
Cr(III) complexes of tridentate PNP ligands have been prepared and evaluated as catalysts for ethylene trimerisation, with several giving high activity and... 
SYSTEM | ETHENE | CHEMISTRY, MULTIDISCIPLINARY | TRIMERIZATION
Journal Article
Dalton transactions (Cambridge, England : 2003), ISSN 1477-9226, 07/2017, Volume 46, Issue 26, pp. 8399 - 8404
Cr(iii) catalysts supported by a series of diphosphinothiophene ligands have been developed, all of which, upon activation with MMAO-3A, are active for... 
Journal Article
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