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trimethylsilyl cyanide (667) 667
chemistry, organic (434) 434
aldehydes (261) 261
chemistry, multidisciplinary (204) 204
ketones (174) 174
catalysis (161) 161
carbonyl-compounds (140) 140
cyanosilylation (121) 121
cyanohydrins (90) 90
derivatives (88) 88
cyanation (86) 86
one-pot synthesis (83) 83
chemistry, inorganic & nuclear (81) 81
strecker reaction (78) 78
chemistry (74) 74
cyanides (72) 72
nitriles (71) 71
chemistry, physical (69) 69
index medicus (68) 68
asymmetric catalysis (63) 63
enantioselective cyanosilylation (61) 61
molecular structure (59) 59
catalysts (56) 56
lewis-acid (54) 54
efficient (51) 51
stereoisomerism (51) 51
cyanides - chemistry (50) 50
chemistry, applied (49) 49
complexes (49) 49
acid (48) 48
alpha-aminonitriles (48) 48
facile synthesis (48) 48
trimethylsilyl compounds - chemistry (48) 48
amines (44) 44
chemical properties (44) 44
cyanohydrin (42) 42
nitriles - chemistry (39) 39
asymmetric-synthesis (38) 38
organic-synthesis (38) 38
synthesis (38) 38
titanium (38) 38
alcohols (37) 37
organic chemistry (36) 36
stereoselective-synthesis (36) 36
3-component condensation (35) 35
complex (35) 35
α-aminonitriles (35) 35
asymmetric addition (34) 34
highly efficient (34) 34
palladium (34) 34
alpha-amino nitriles (33) 33
ligands (33) 33
tmscn (33) 33
catalyst (32) 32
research (32) 32
-camptothecin family (31) 31
asymmetric cyanohydrin synthesis (31) 31
solvent-free conditions (31) 31
asymmetric cyanosilylation (30) 30
cyanide (30) 30
cyanotrimethylsilane (30) 30
imines (30) 30
practical synthesis (30) 30
amino nitriles (29) 29
aminonitriles (29) 29
enantioselective synthesis (28) 28
n-oxide (28) 28
reagent (28) 28
activation (27) 27
carbonyl compounds (27) 27
trimethylsilyl azide (27) 27
nitriles - chemical synthesis (26) 26
analysis (25) 25
chiraltitanium complexes (25) 25
mild (25) 25
acids (24) 24
esters (24) 24
ketones - chemistry (23) 23
double-activation method (22) 22
highly enantioselective cyanosilylation (22) 22
potassium cyanide (22) 22
reagents (22) 22
silylcyanation (22) 22
solvent-free (22) 22
umpolung (22) 22
alkynes (21) 21
efficient synthesis (21) 21
lewis acid (21) 21
stereoselective synthesis (21) 21
synthetic applications (21) 21
trimethylsilyl cyanide addition (21) 21
aldehydes - chemistry (20) 20
enantiomers (20) 20
enantioselective addition (20) 20
hydrocyanation (20) 20
letter (20) 20
ligand (20) 20
paper (20) 20
organocatalysis (19) 19
water (19) 19
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Advanced Synthesis & Catalysis, ISSN 1615-4150, 02/2019, Volume 361, Issue 3, pp. 520 - 525
A regioselective cyanation of quinoline N‐oxides with trimethylsilyl cyanide was developed by using (Diacetoxyiodo) benzene (PIDA) as mediated hypervalent... 
Trimethylsilyl cyanide | Metal-free | PIDA | Cyanation | Quinoline N-oxides | ONE-POT SYNTHESIS | TERTIARY-AMINES | SULFONYLATION | CHEMISTRY, ORGANIC | MILD | C-H CYANATION | AMINATION | DOUBLE-BLIND | DIRECT OXIDATIVE CYANATION | CHEMISTRY, APPLIED | EFFICIENT | Nitrogen compounds | Nitriles | Oxides | Tuberculosis | Chemical tests and reagents | Regioselectivity | Benzene | Reagents | Quinoline | Cyanides | Substrates | Iodine
Journal Article
Tetrahedron, ISSN 0040-4020, 05/2013, Volume 69, Issue 21, pp. 4236 - 4240
A copper-mediated direct cyanation of indoles with benzyl cyanide as the cyanide anion surrogate has been achieved. The cascade reaction furnished... 
Benzyl cyanide | Cyanation | 3-Cyanoindoles | Copper catalysis | ACID | CHEMISTRY, ORGANIC | C-H BONDS | N,N-DIMETHYLFORMAMIDE | NITRILES | ARYL HALIDES | PALLADIUM-CATALYZED CYANATION | DERIVATIVES | TRANSFORMATIONS | SODIUM BIS(TRIMETHYLSILYL)AMIDE | Cyanides | Anions | Tetrahedrons | Tolerances | Indoles | Cascade chemical reactions | Functional groups
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 03/2015, Volume 80, Issue 5, pp. 2848 - 2854
Oxidation at the sulfur of the safe-to-handle potassium thiocyanate releases cyanide units that are trapped in the presence of co-oxidized tertiary amines to... 
ANODIC CYANATION | DEHYDROGENATIVE COUPLING REACTIONS | CHEMISTRY, ORGANIC | HYDROGEN-PEROXIDE | CATALYST | C-H FUNCTIONALIZATION | TRIMETHYLSILYL CYANIDE | AROMATIC-COMPOUNDS | HIGHLY EFFICIENT | ELECTROCHEMICAL OXIDATION | CYCLIC AMINES | Thiocyanates | Oxidation-reduction reaction | Amines | Research | Chemical properties | Catalysts
Journal Article
Bulletin of the Chemical Society of Japan, ISSN 0009-2673, 1/2014, Volume 87, Issue 1, pp. 59 - 68
The reaction of silyl cyanide (R3SiCN) with hydrosilane (R′3SiH) in the presence of a catalytic amount of [(η5-C5H5)Fe(CO)2Me] formed R′3SiCN and R3SiH. This... 
WAVE-FUNCTIONS | ACTIVATION | MOLECULAR CALCULATIONS | TRANSITION-METAL-COMPLEXES | ISOCYANIDE | ATOMS | LIGAND | TRIMETHYLSILYL CYANIDE | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | GAUSSIAN-BASIS SETS | Silicon carbonitride | Catalysts | Mathematical analysis | Exothermic reactions | Cleavage | Cyanides | Iron | Bonding
Journal Article
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 2010, Volume 8, Issue 6, pp. 1399 - 1405
Journal Article
ChemCatChem, ISSN 1867-3880, 08/2013, Volume 5, Issue 8, pp. 2405 - 2409
Structurally well‐defined bimetallic titanium(IV) (salen) and monometallic vanadium(V) (salen) complexes have been used as catalysts for the asymmetric... 
Michael addition | vanadium | asymmetric catalysis | titanium | N,O ligands | Titanium | Asymmetric catalysis | Vanadium | ANION | ORGANOCATALYST | CHEMISTRY, PHYSICAL | CYANOHYDRIN SYNTHESIS | ALDEHYDES | KETONES | (SALEN)TITANIUM COMPLEXES | NITROOLEFINS | TRIMETHYLSILYL CYANIDE | CONJUGATE ADDITION | Full Papers
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 2010, Volume 51, Issue 30, pp. 3922 - 3926
Journal Article
Journal of Chemical Research, ISSN 1747-5198, 06/2018, Volume 42, Issue 6, pp. 297 - 299
A number of 2-aryl-2H-chromene-4-carbonitriles were synthesised by cyanation of 2-aryl-3-nitro-2H-chromenes using trimethylsilyl cyanide (TMSCN) in the... 
Michael addition | Trimethylsilyl cyanide | Tetrabutylammonium fluoride | 3-nitro-chromene | trimethylsilyl cyanide | 3-NITROCHROMENES | tetrabutylammonium fluoride | CHROMENES | HALOGEN | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | Infrared spectroscopy | Cyanides | Nuclear magnetic resonance--NMR | Aromatic compounds | Crystallography
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 05/2011, Volume 52, Issue 18, pp. 2312 - 2315
Journal Article
Journal of Chemical Research, ISSN 1747-5198, 10/2017, Volume 41, Issue 10, pp. 614 - 616
2-Cyano-3-nitroporphyrin derivatives were synthesised by the reaction of 2-nitroporphyrin with trimethylsilyl cyanide in the presence of tetrabutylammonium... 
2-nitroporphyrin | Trimethylsilyl cyanide | Tetrabutylammonium fluoride | trimethylsilyl cyanide | NORCORROLE | tetrabutylammonium fluoride | CHEMISTRY, MULTIDISCIPLINARY | PORPHYRINS | Cyanides | Derivatives | X ray analysis | Chemical synthesis | Porphyrins
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 05/2018, Volume 83, Issue 10, pp. 5807 - 5815
A new approach for the synthesis of tetrasubstituted/functionalized NH-pyrroles from gem-diactivated acrylonitriles and TMSCN has been developed. The strategy... 
DOMINO REACTION | FACILE SYNTHESIS | 3-COMPONENT REACTION | BIOLOGICAL EVALUATION | EFFICIENT SYNTHESIS | CHEMISTRY, ORGANIC | CHEMOSELECTIVE SYNTHESIS | TRIMETHYLSILYL CYANIDE | DERIVATIVES | POLYSUBSTITUTED PYRROLES | STRUCTURE-BASED DESIGN
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 2005, Volume 46, Issue 27, pp. 4595 - 4597
[Display omitted] A straightforward and general method has been developed for the synthesis of α-aminonitriles by simply combining aldehydes or ketones,... 
Trimethylsilyl cyanide | Amines | Ketones | Aldehydes | α-Aminonitriles | Iodine | SYSTEM | ACIDS | amines | trimethylsilyl cyanide | CHEMISTRY, ORGANIC | CATALYST | ketones | CLEAVAGE | alpha-aminonitriles | STRECKER SYNTHESIS | TRIFLATE | aldehydes | ETHERS | NITRILES | iodine | DERIVATIVES
Journal Article
Tetrahedron, ISSN 0040-4020, 2006, Volume 62, Issue 1, pp. 49 - 53
Trimethylsilyl cyanide asymmetrically adds to various ketones by catalysis of 1 /triphenylphosphine oxide. This is a double activation where 1 acts as Lewis... 
Al(salen) | Trimethylsilyl cyanide | Asymmetric addition | Cyanohydrin | Ketone | ketone | CYANOHYDRINS | ACID | trimethylsilyl cyanide | CHEMISTRY, ORGANIC | cyanohydrin | ALDEHYDES | asymmetric addition | ENANTIOSELECTIVE CYANOSILYLATION
Journal Article
Tetrahedron, ISSN 0040-4020, 06/2019, Volume 75, Issue 25, pp. 3413 - 3420
Trimethylsilylcyanide was added to various imines derived from (2S)-ethyl lactate in the presence of Lewis acids to provide both syn- and anti-... 
Strecker reaction | Trimethylsilyl cyanide | Lactimine | AMINONITRILES | ROUTE | ASYMMETRIC-SYNTHESIS | ALDEHYDE | CHEMISTRY, ORGANIC | ALPHA-AMINO-ACIDS | CYANOSILYLATION | Stereoisomers | Schiff bases | Nitriles | Esters | Lactic acid
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 08/2009, Volume 131, Issue 31, pp. 10964 - 10973
Journal Article
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