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trimethylsilyl fluorosulfonyldifluoroacetate tfda (9) 9
difluoromethylation (6) 6
chemistry, multidisciplinary (5) 5
chemistry, organic (5) 5
chemistry, inorganic & nuclear (4) 4
difluorocarbene (3) 3
fluorine (3) 3
ketones (3) 3
reagent (3) 3
agent (2) 2
alpha-fluorinated ethers (2) 2
carbonyl-compounds (2) 2
catalysis (2) 2
chemistry (2) 2
chlorides (2) 2
complexes (2) 2
copper-catalyzed trifluoromethylation (2) 2
cycloaddition (2) 2
difluorocarbene reagent (2) 2
difluorocyclopropanes (2) 2
efficient synthesis (2) 2
gem-difluorocyclopropanes (2) 2
highly fluorinated epoxides (2) 2
nucleophiles (2) 2
o-difluoromethylation (2) 2
one-pot synthesis (2) 2
organocatalyst (2) 2
polyfluorosulfonic acids (2) 2
reagents (2) 2
route (2) 2
ruppert-prakash reagent (2) 2
salts (2) 2
sulfur compounds (2) 2
trifluoromethylation (2) 2
acetal (1) 1
acetals (1) 1
acid (1) 1
addition reactions (1) 1
adenine - chemistry (1) 1
aldehydes (1) 1
alkenes (1) 1
alkenes - chemistry (1) 1
alkynes (1) 1
alkynes - chemistry (1) 1
alpha,beta-unsaturated carboxylic-acids (1) 1
amides (1) 1
analysis (1) 1
aryl (1) 1
aryl boronic acids (1) 1
benzimidazoles - chemical synthesis (1) 1
biological evaluation (1) 1
c-h bonds (1) 1
carbon (1) 1
catalysts (1) 1
catalyzed reaction (1) 1
chemical properties (1) 1
chemical synthesis (1) 1
chlorides - chemistry (1) 1
convenient method (1) 1
copper-mediated difluoromethylation (1) 1
cyclopropane (1) 1
cyclopropanes - chemistry (1) 1
cytokinins (1) 1
derivatives (1) 1
difluoromethyl ethers (1) 1
difluoromethyl imidates (1) 1
difluoromethyl phenyl sulfone (1) 1
efficient difluoromethylation (1) 1
electric properties (1) 1
electron-transfer reaction (1) 1
electrophilic substitution (1) 1
enantioselective conjugate addition (1) 1
ethers (1) 1
fluor (1) 1
fluorinated sulfones (1) 1
gem -difluoroolefination (1) 1
gem-difluoroolefination (1) 1
generation (1) 1
halomethyl metal-compounds (1) 1
highly stereoselective-synthesis (1) 1
hydrocarbons, fluorinated - chemistry (1) 1
hypervalent iodine reagent (1) 1
imidazoles - chemistry (1) 1
index medicus (1) 1
indicators and reagents (1) 1
ions - chemistry (1) 1
ketene (1) 1
ketenes (1) 1
ketoesters (1) 1
kohlenstoff (1) 1
magnetic resonance spectroscopy (1) 1
mediated reductive trifluoromethylation (1) 1
mediated trifluoromethylation (1) 1
medicinal chemistry (1) 1
methyl 2,2-difluoro-2-acetate (1) 1
n-difluoromethylation (1) 1
n-heterocyclic carbene (1) 1
nhc (1) 1
nitrogen-heterocycles (1) 1
nucleophilic difluoromethylation (1) 1
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Journal of Fluorine Chemistry, ISSN 0022-1139, 2004, Volume 125, Issue 3, pp. 459 - 469
TFDA is readily prepared from the reaction of fluorosulfonyldifluoroacetic acid with trimethylsilyl chloride, and it is a very effective and efficient source... 
Trimethylsilyl fluorosulfonyldifluoroacetate | Addition reactions | Difluorocarbene reagent | CHEMISTRY, ORGANIC | GEM-DIFLUOROCYCLOPROPANES | difluorocarbene reagent | trimethylsilyl fluorosulfonyldifluoroacetate | addition reactions | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Chemical Communications, ISSN 1359-7345, 2009, Issue 48, pp. 7465 - 7478
The selective introduction of fluorine atom(s) and fluorinated moieties into organic molecules has become an important and fast-growing research field, since... 
PRACTICAL SYNTHESIS | TRIMETHYLSILYL FLUOROSULFONYLDIFLUOROACETATE TFDA | FLUORINATED SULFONES | PHENYL SULFONE | ENANTIOSELECTIVE CONJUGATE ADDITION | CARBONYL-COMPOUNDS | RADICAL TRIFLUOROMETHYLATION | NUCLEOPHILIC DIFLUOROMETHYLATION | STEREOSELECTIVE-SYNTHESIS | ORGANOFLUORINE COMPOUNDS | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Chemical Communications, ISSN 1359-7345, 02/2011, Volume 47, Issue 8, pp. 2411 - 2413
A chloride ion-catalyzed generation of difluorocarbene from a relatively non-toxic and inexpensive precursor, Me3SiCF2Cl (1), under mild and neutral conditions... 
REAGENT | AGENT | KETONES | DIFLUOROMETHYLATION | TRIMETHYLSILYL FLUOROSULFONYLDIFLUOROACETATE TFDA | COMPLEXES | DIFLUOROCYCLOPROPANES | SALTS | CHEMISTRY, MULTIDISCIPLINARY | Index Medicus
Journal Article
Synthesis, ISSN 0039-7881, 04/2014, Volume 46, Issue 7, pp. 842 - 863
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 02/2011, Volume 47, Issue 8, pp. 2411 - 2413
A chloride ion-catalyzed generation of difluorocarbene from a relatively non-toxic and inexpensive precursor, Me(3)SiCF(2)Cl (1), under mild and neutral... 
Cyclopropanes - chemistry | Alkenes - chemistry | Thermodynamics | Ions - chemistry | Hydrocarbons, Fluorinated - chemistry | Alkynes - chemistry | Silicates - chemistry | Catalysis | Chlorides - chemistry | Cycloaddition | Alkenes | Cyclopropane | Precursors | Chlorides | Alkynes
Journal Article
Journal of Fluorine Chemistry, ISSN 0022-1139, 03/2015, Volume 171, pp. 133 - 138
Upon treatment with trimethylsilyl 2,2-difluoro-2-fluorosulfonylacetate (TFDA) and a catalytic amount of , , ′, ′-tetramethyl-1,8-diaminonaphthalene, secondary... 
Thioamide | Sulfur | Thiocarbamate | Organocatalyst | Difluoromethylation | Difluorocarbene | ROUTE | REAGENTS | COPPER-MEDIATED DIFLUOROMETHYLATION | CHEMISTRY, ORGANIC | CHEMISTRY, INORGANIC & NUCLEAR | TRIMETHYLSILYL FLUOROSULFONYLDIFLUOROACETATE TFDA | ORGANIC-COMPOUNDS | CHEMISTRY | ALPHA-FLUORINATED ETHERS | ARYL | GENERATION | THIOETHERS | Cytokinins | Sulfur compounds
Journal Article
Chinese Journal of Chemistry, ISSN 1001-604X, 11/2018, Volume 36, Issue 11, pp. 1069 - 1074
Journal Article
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