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1. Full Text Copper‐Catalyzed Aerobic Oxidative CC Bond Cleavage for CN Bond Formation: From Ketones to Amides
by Tang, Conghui and Jiao, Ning
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2014, Volume 53, Issue 25, pp. 6528 - 6532
A novel copper‐catalyzed aerobic oxidative C(CO)C(alkyl) bond cleavage reaction of aryl alkyl ketones for CN bond formation is described. A series of... 
copper | amides | ketones | oxygen | cleavage reactions | ALPHA-CLEAVAGE | ACTIVATION | ORGANIC-CHEMICALS | CARBON TRIPLE BOND | CHEMISTRY, MULTIDISCIPLINARY | PHENYLACETIC ACIDS | ELECTRON-TRANSFER | DIRECT TRANSFORMATION | ARYL AZIDES | METAL-FREE | MOLECULAR-OXYGEN | Copper - chemistry | Acetophenones - chemistry | Nitrogen - chemistry | Oxidation-Reduction | Ketones - chemistry | Amides - chemistry | Molecular Structure | Catalysis | Carbon - chemistry | Ketones | Aromatic compounds | Acetophenone | Amides | Cleavage | Derivatives | Bonding | Pharmaceuticals
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2. Full Text Single, Double, Triple Bonds and Chains: The Formation of Electron‐Precise BB Bonds
by Braunschweig, Holger and Dewhurst, Rian D
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2013, Volume 52, Issue 13, pp. 3574 - 3583
The construction of boron–boron bonds, despite the intense synthetic interest in diboranes and the high BB bond enthalpy, is still difficult, uncontrollable,... 
boron‐centered ligands | boron–boron bonds | boron | multiple bonding | transition metals | boron-boron bonds | boron-centered ligands | Construction | Diborane | Boron | Formations | Synthesis | Enthalpy
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3. Full Text Synthesis of a Dimeric Base‐Stabilized Cobaltosilylene Complex for Catalytic C−H Bond Functionalization and C−C Bond Formation
by Khoo, Sabrina and Cao, Jiajia and Yang, Ming‐Chung and Shan, Yu‐Liang and Su, Ming‐Der and So, Cheuk‐Wai
Chemistry – A European Journal, ISSN 0947-6539, 09/2018, Volume 24, Issue 54, pp. 14329 - 14334
The synthesis of a dimeric base‐stabilized cobaltosilylene complex and its catalytic reactions are described. Treatment of the amidinato silicon(I) dimer... 
carbene homologue | cobalt | silicon | C−H activation | C−C bond functionalization | METALLOGERMYLENES | ACTIVATION | TRIPLE BONDS | BIS(SILYLENE) | C-C bond functionalization | N-HETEROCYCLIC SILYLENE | CHEMISTRY, MULTIDISCIPLINARY | C-H activation | LIGANDS | NICKEL | CHLORIDE | Dichloropropane | Chemical properties | Cobalt | Toluene | Chlorides | Phosphine | Magnetic moments | Chemical reactions | Crystallography | Intermediates | Coupling (molecular) | Electronic structure | Hydrogen bonds | Aromatic compounds | Reagents | Dimers | Catalysis | Chemical synthesis | Alkynes | Crystal structure
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4. Full Text Real‐Space In Situ Bond Energies: Toward A Consistent Energetic Definition of Bond Strength
by Menéndez‐Crespo, Daniel and Costales, Aurora and Francisco, Evelio and Martín Pendás, Ángel
Chemistry – A European Journal, ISSN 0947-6539, 06/2018, Volume 24, Issue 36, pp. 9101 - 9112
A rigorous definition of intrinsic bond strength based on the partitioning of a molecule into real‐space fragments is presented. Using the domains provided by... 
computational chemistry | bond energy | quantum theory of atoms in molecules | bond theory | interacting quantum atoms | GROUND-STATE | DECOMPOSITION SCHEME | C-2 | FORCE-CONSTANTS | CHEMISTRY, MULTIDISCIPLINARY | CHEMICAL-BOND | 3 VIEWS | BORON TRIPLE BOND | ONE MOLECULE | ELECTRONIC-STRUCTURE | Bonds | Quantum theory | Appellate procedure | Organic chemistry | Deformation | Bond strength | Fragments | Chemical bonds | Bonding strength | Bond energy | Atomizing | Molecular chains | Fragmentation
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5. Full Text Direct Syn Addition of Two Silicon Atoms to a C≡C Triple Bond by Si−Si Bond Activation: Access to Reactive Disilylated Olefins
by Ahmad, Maha and Gaumont, Annie‐Claude and Durandetti, Muriel and Maddaluno, Jacques
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2017, Volume 56, Issue 9, pp. 2464 - 2468
A catalytic intramolecular silapalladation of alkynes affords, in good yields and stereoselectively, syn‐disilylated heterocycles of different chemical... 
vinylsilane | palladium | disilane | heterocycles | cyclization | ORGANIC-SYNTHESIS | CATALYZED CIS-SILABORATION | DRUG DISCOVERY | TERMINAL ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | UNACTIVATED C(SP)-H BONDS | DEHYDROGENATIVE SILYLATION | CHEMISTRY | HECK REACTION | DERIVATIVES | INTRAMOLECULAR BIS-SILYLATION
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6. Full Text Ag-catalyzed C-H/C-C bond functionalization
by Zheng, Qing-Zhong and Jiao, Ning
Chemical Society Reviews, ISSN 0306-0012, 08/2016, Volume 45, Issue 16, pp. 4590 - 4627
Silver, known and utilized since ancient times, is a coinage metal, which has been widely used for various organic transformations in the past few decades.... 
H FUNCTIONALIZATION | CARBON-CARBON BOND | DECARBOXYLATIVE FLUORINATION | ONE-POT | RADICAL CYCLIZATION | TERMINAL ALKYNES | TRIPLE BOND | ALIPHATIC CARBOXYLIC-ACIDS | PHOSPHINE OXIDES | ALPHA-KETO ACIDS | CHEMISTRY, MULTIDISCIPLINARY
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7. Full Text Chemoselective Oxidative C(CO)C(methyl) Bond Cleavage of Methyl Ketones to Aldehydes Catalyzed by CuI with Molecular Oxygen
by Zhang, Lin and Bi, Xihe and Guan, Xiaoxue and Li, Xingqi and Liu, Qun and Barry, Badru‐Deen and Liao, Peiqiu
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2013, Volume 52, Issue 43, pp. 11303 - 11307
Aldehyde Termination: A novel copper‐catalyzed transformation from methyl ketones into aldehydes has been accomplished. This method is applicable to a wide... 
copper | aldehydes | ketones | oxygen | cleavage reactions | C-C-BOND | ACTIVATION | DIOXYGEN | LEWIS-ACID | TRIPLE BOND | CARBON-CARBON BONDS | CHEMISTRY, MULTIDISCIPLINARY | CYANO BONDS | REDUCTIVE CLEAVAGE | HOMOGENEOUS CATALYSIS | METAL-FREE | Ketones | Carbon dioxide | Byproducts | Cleavage | Transformations | Aldehydes | Aliphatic compounds
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8. Full Text The First Boron–Tellurium Double Bond: Direct Insertion of Heavy Chalcogens into a Mn=B Double Bond
by Liu, Siyuan and Légaré, Marc‐André and Auerhammer, Dominic and Hofmann, Alexander and Braunschweig, Holger
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2017, Volume 56, Issue 49, pp. 15760 - 15763
The base‐stabilized borylene [Cp(OC)2Mn=BtBu(IMe)] readily reacts with elemental chalcogens in an insertion reaction that yields borachalcone complexes... 
tellurium | subvalent compounds | multiple bonds | boron | manganese | CARBON DOUBLE-BOND | SINGLE | SILABORENE | TRIPLE BONDS | COORDINATION | CHEMISTRY, MULTIDISCIPLINARY | TERMINAL BORYLENE | BASIS-SETS | METATHESIS | BORYLENE COMPLEXES | Bonds | Chemical properties | Insertion | Boron | Tellurium
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9. Full Text Unstrained CarbonCarbon Bond Cleavage
by Liu, Hui and Feng, Minghao and Jiang, Xuefeng
Chemistry – An Asian Journal, ISSN 1861-4728, 12/2014, Volume 9, Issue 12, pp. 3360 - 3389
This Focus Review presents recent developments in the cleavage of CC bonds in organic molecules. Significant progress in CC activation, including the... 
metal‐free synthesis | unstrained CC bonds | CC activation | synthesis design | transition metals | Transition metals | Synthesis design | Unstrained C-C bonds | Metal-free synthesis | C-C activation | unstrained CC bonds | C-C-BOND | AEROBIC OXIDATIVE CLEAVAGE | TRIPLE BOND | INTRAMOLECULAR ARYLCYANATION | CHEMISTRY, MULTIDISCIPLINARY | H ACTIVATION | metal-free synthesis | LIGHT PHOTOREDOX CATALYSIS | MECHANISTIC INSIGHT | METATHESIS REACTION | METAL-FREE | CC activation | MOLECULAR-OXYGEN
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