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twisted amides (124) 124
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Chemistry – A European Journal, ISSN 0947-6539, 10/2016, Volume 22, Issue 41, pp. 14494 - 14498
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 05/2017, Volume 23, Issue 30, pp. 7157 - 7173
Journal Article
Organic Letters, ISSN 1523-7060, 09/2017, Volume 19, Issue 17, pp. 4656 - 4659
Despite recent progress in catalytic cross-coupling technologies, the direct activation of N-alkyl-N-aryl amides has been a challenging transformation. Here,... 
CROSS-COUPLING REACTIONS | KETONE SYNTHESIS | NICKEL CATALYSIS | HETEROCYCLIC CARBENE COMPLEXES | TWISTED AMIDES | ESTERS | NHC | CHEMISTRY, ORGANIC | C BOND ACTIVATION | SUZUKI-MIYAURA | GENERAL-METHOD
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2016, Volume 55, Issue 16, pp. 5062 - 5066
Herein, we describe the first structural characterization of N‐alkylated twisted amides prepared directly by N‐alkylation of the corresponding non‐planar... 
N−C activation | N−C cleavage | amide bonds | twisted amides | N-coordination | N-C activation | N-C cleavage | MECHANISM | BICYCLIC LACTAMS | COMPLEXES | HYDROLYSIS | ION | FRAGMENTATION | CHEMISTRY, MULTIDISCIPLINARY | PROTONATION | 3,4-DIHYDRO-2-OXO-1,4-ETHANOQUINOLINE | NITROGEN | PEPTIDE-BOND | Bonds | Chemical properties
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 07/2017, Volume 23, Issue 42, pp. 10043 - 10047
The first cobalt‐catalyzed amide activation of N‐Boc‐amides, and their conversion into esters, is reported here. This new methodology presents a very practical... 
cross-coupling | amides | cobalt | esterification | homogeneous catalysis | NICKEL CATALYSIS | TWISTED AMIDES | TERTIARY AMIDE | CHEMOSELECTIVE KETONE SYNTHESIS | CARBON-HYDROGEN BONDS | CHEMISTRY, MULTIDISCIPLINARY | H BOND ACTIVATION | CROSS-COUPLING REACTIONS | MILD CONDITIONS | N-C CLEAVAGE | HETEROCYCLIC CARBENE COMPLEXES | Amides | Esters | Catalysis | Cobalt | Catalysts | Atmosphere | Esterification | Chemical Sciences | Other
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 11/2018, Volume 16, Issue 43, pp. 7998 - 81
Cross-coupling reactions are among the most powerful C-C and C-X bond forming tools in organic chemistry. Traditionally, cross-coupling methods rely on the use... 
ACYCLIC AMIDES | ELECTRONICALLY-ACTIVATED AMIDES | SECONDARY AMIDES | N-C CLEAVAGE | CATALYZED CARBONYLATION REACTIONS | TWISTED AMIDES | CHEMISTRY, ORGANIC | BOND FORMATION | CHEMOSELECTIVE KETONE SYNTHESIS | ACYL-TRANSFER REAGENTS | GENERAL-METHOD
Journal Article
Organic & Biomolecular Chemistry, ISSN 1477-0520, 01/2018, Volume 16, Issue 43, pp. 7998 - 8010
Cross-coupling reactions are among the most powerful C–C and C–X bond forming tools in organic chemistry. Traditionally, cross-coupling methods rely on the use... 
Cross coupling | Amides | Chemical reactions | Activation | Carbon | Couplings | Organic chemistry | Halides | Aromatic compounds | Construction methods | Extrusion | Functional groups | Coupling methods
Journal Article
ACS Catalysis, ISSN 2155-5435, 03/2017, Volume 7, Issue 3, pp. 1960 - 1965
The direct Suzuki–Miyaura cross-coupling of amides catalyzed by Pd-NHC complexes is reported. Using a single protocol, commercially available, air- and... 
N-C activation | palladium | amides | N-heterocyclic carbenes (NHCs) | Suzuki-Miyaura cross-coupling | CATALYZED ACTIVATION | C CLEAVAGE | REAGENTS | TWISTED AMIDES | CHEMISTRY, PHYSICAL | Suzuki Miyaura cross-coupling | BOND-CLEAVAGE | KETONE SYNTHESIS | LIGANDS | BUCHWALD-HARTWIG | NITROGEN | ARYL CHLORIDES
Journal Article
Organic Letters, ISSN 1523-7060, 07/2017, Volume 19, Issue 13, pp. 3596 - 3599
The formation of C–C bonds from amides by catalytic activation of the amide bond has been thus far possible by steric distortion. Herein, we report the first... 
ALIPHATIC AMIDES | KETONE SYNTHESIS | NICKEL CATALYSIS | SECONDARY AMIDES | NITROGEN BOND-CLEAVAGE | HETEROCYCLIC CARBENE COMPLEXES | TWISTED AMIDES | CHEMISTRY, ORGANIC | TRANSAMIDATION | SALTS | GENERAL-METHOD
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2015, Volume 54, Issue 48, pp. 14518 - 14522
Metal‐catalyzed reactions of amides proceeding via metal insertion into the NCO bond are severely underdeveloped due to resonance stabilization of the amide... 
Heck reaction | base‐free Heck reaction | amide bonds | twisted amides | NC activation | N-C activation | base-free Heck reaction | HALIDES | SUBSTITUTION | ROTATIONAL PATHWAY | ARYLATION | CLEAVAGE | MIZOROKI-HECK | CHEMISTRY, MULTIDISCIPLINARY | ARYL BROMIDES | COUPLING REACTIONS | AROYL CHLORIDES | free Heck reaction | base
Journal Article
Synlett, ISSN 0936-5214, 11/2016, Volume 27, Issue 18, pp. 2530 - 2540
Abstract In recent years, significant conceptual advances have taken place in the field of amide bond cross-coupling. Mild and selective functionalization of... 
account | Suzuki coupling | decarbonylative coupling | nickel | amides | C-H activation | cross-coupling | palladium | N-C bond activation | ORGANIC-SYNTHESIS | ROTATIONAL PATHWAY | NICKEL CATALYSIS | TWISTED AMIDES | CHEMISTRY, ORGANIC | CHEMOSELECTIVE KETONE SYNTHESIS | CLEAVAGE | ORGANOMETALLIC REAGENTS | RESONANCE | NITROGEN | METAL
Journal Article