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Organic Letters, ISSN 1523-7060, 05/2016, Volume 18, Issue 10, pp. 2351 - 2354
A new method was demonstrated to overcome the selectivity issue of radical–radical cross-coupling toward the synthesis of asymmetric diaryl thioethers. The... 
MECHANISM | STRATEGY | CHEMISTRY | REACTIVITY | CHEMISTRY, ORGANIC | THIYL RADICALS | OLEFINS
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 05/2018, Volume 54, Issue 44, pp. 5574 - 5577
A new protocol for C-S bond formation was developed by selective cross-coupling between a thiyl radical and an isobutyronitrile radical. Using this strategy, a... 
Journal Article
Chemical Communications, ISSN 1359-7345, 2018, Volume 54, Issue 44, pp. 5574 - 5577
A new protocol for C-S bond formation was developed by selective cross-coupling between a thiyl radical and an isobutyronitrile radical. Using this strategy, a... 
KETONES | ELECTRON-TRANSFER | NITRILES | EPR | REACTIVITY | CHEMISTRY | THIYL RADICALS | CYANATION | ALDEHYDES | AIBN | CHEMISTRY, MULTIDISCIPLINARY | Cross coupling | Coupling | Copper | Bonding
Journal Article
ACS Catalysis, ISSN 2155-5435, 12/2018, Volume 8, Issue 12, pp. 11134 - 11139
Despite the prevalence of alcohols and carboxylic acids as functional groups in organic molecules and the potential to serve as radical precursors, C–O bonds... 
β-scission | C-O Bond activation | phosphoranyl radical | photoredox catalysis | carboxylic acid | radical cyclization | ACYL RADICALS | CHEMISTRY, PHYSICAL | ALPHA | SINGLE-ELECTRON TRANSMETALATION | ALKOXY | beta-scission | DEOXYGENATION | CHEMISTRY | THIYL RADICALS | DERIVATIVES | CARBOXYLIC-ACIDS
Journal Article
Archives of Biochemistry and Biophysics, ISSN 0003-9861, 04/2016, Volume 595, pp. 33 - 39
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 11/2014, Volume 50, Issue 92, pp. 14349 - 14351
Carbon-centered radicals of alcohols commonly used as hydroxyl radical scavengers (MeOH, EtOH, i-PrOH and t-BuOH) add reversibly to histidine with equilibrium... 
Alcohols - chemistry | Oxidation-Reduction | Histidine - chemistry | Free Radicals - chemistry | Carbon - chemistry
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 02/2018, Volume 24, Issue 7, pp. 1505 - 1508
Two hitherto unreported sulfur‐centered radicals CF3SO. and CF3OS. were generated in the gas phase through high‐vacuum flash pyrolyses of sulfoxide CF3S(O)X... 
sulfur | ab initio computations | radicals | isomerization | IR spectroscopy | PEROXYL RADICALS | HSO | STABILITY | DECOMPOSITION | CHEMISTRY, MULTIDISCIPLINARY | CH3(O)S-CENTER-DOT | GAS-PHASE | CENTER-DOT | ISOMERS | CHEMISTRY | THIYL RADICALS | Sulfur compounds | Analysis | Isomerization | Infrared spectroscopy | Ultraviolet radiation | Vacuum | Light irradiation | Quantum chemistry | U.V. radiation | Irradiation | Sulfur | Rare gases | Radicals
Journal Article
Free Radical Research, ISSN 1071-5762, 02/2016, Volume 50, Issue 2, pp. 143 - 149
Journal Article
Chemical Communications, ISSN 1359-7345, 11/2014, Volume 50, Issue 92, pp. 14349 - 14351
Carbon-centered radicals of alcohols commonly used as hydroxyl radical scavengers (MeOH, EtOH, i-PrOH and t-BuOH) add reversibly to histidine with equilibrium... 
PROTEIN RADICALS | TRYPTOPHAN | REDOX POTENTIALS | AQUEOUS-SOLUTIONS | PEPTIDES | REDUCTION | PULSE-RADIOLYSIS | TYROSINE | CYSTEINE THIYL RADICALS | FLASH-PHOTOLYSIS | CHEMISTRY, MULTIDISCIPLINARY | Chemical equilibrium | Scavengers | Histidine | Rate constants | Hydroxyl radicals | Electrode potentials | Radicals | Alcohols
Journal Article
Chempluschem, ISSN 2192-6506, 2013, Volume 78, Issue 9, pp. 970 - 978
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2015, Volume 54, Issue 32, pp. 9249 - 9252
Etching of gold with an excess of thiol ligand is used in both synthesis and analysis of gold particles. Mechanistically, the process of etching gold with... 
nanoparticles | etching | gold nanoclusters | thiolates | ELECTRONIC-PROPERTIES | OPTICAL-PROPERTIES | CHEMISTRY, MULTIDISCIPLINARY | SCALE SYNTHESIS | RAY CRYSTAL-STRUCTURE | NANOCLUSTERS | NANOMOLECULES | THIYL RADICALS | CORE SIZE CONVERSION | MOLECULAR-OXYGEN | Atoms & subatomic particles | Gold | Etching | Thiols | Synthesis | Initiators | Attenuation | Ligands | Radicals | nanoparticle | nanocluster | mechanism | thiolate
Journal Article
Physical Chemistry Chemical Physics, ISSN 1463-9076, 2016, Volume 18, Issue 37, pp. 26161 - 26265
Journal Article
Physical chemistry chemical physics : PCCP, ISSN 1463-9076, 09/2016, Volume 18, Issue 37, pp. 26161 - 26165
The phenylthiyl radical (1) was prepared in the gas phase by vacuum flash pyrolysis of allylphenyl sulfide or diphenyl sulfide and isolated in an argon matrix.... 
Journal Article
The Journal of Physical Chemistry A, ISSN 1089-5639, 09/2016, Volume 120, Issue 37, pp. 7398 - 7403
High-level ab initio calculations have been used to calculate the standard and inherent radical stabilities (RSEs) of a test set of 41 sulfur-centered... 
CARBON | DOUBLE-BONDS | THERMOCHEMISTRY | PHYSICS, ATOMIC, MOLECULAR & CHEMICAL | REACTIVITY | CHEMISTRY | CHEMISTRY, PHYSICAL | THIYL RADICALS | POLYMERIZATION | AIR | DISULFIDE | Chemical bonds | Sulfur compounds | Chemical properties | Research | Atmospheric chemistry | Analysis
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 08/2018, Volume 140, Issue 31, pp. 9972 - 9978
Arylsulfinyl radicals are key intermediates in sulfoxide chemistry. The parent molecule, phenylsulfinyl radical PhSO•, has been generated for the first time in... 
DIMETHYL SULFIDE | SOLID ARGON | PEROXYL RADICALS | SULFUR-COMPOUNDS | PHOTOSENSITIZED OXIDATION | THIYL RADICALS | S BOND-CLEAVAGE | CYSTEINE SULFINYL RADICALS | MATRIX-ISOLATION | CHEMISTRY, MULTIDISCIPLINARY | MOLECULAR-OXYGEN
Journal Article