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trifluoroethylation (48) 48
chemistry, organic (40) 40
fluorine (17) 17
chemistry, multidisciplinary (16) 16
cross-coupling reactions (15) 15
trifluoromethylation (14) 14
aryl iodides (12) 12
derivatives (12) 12
medicinal chemistry (12) 12
2,2,2-trifluoroethylation (11) 11
arylboronic acids (10) 10
catalysis (10) 10
c-h trifluoroethylation (9) 9
activation (8) 8
alkylation (8) 8
aryl (8) 8
index medicus (8) 8
photoredox catalysis (8) 8
reagents (8) 8
alkenes (7) 7
alkynes (7) 7
amino-acids (7) 7
chemistry, inorganic & nuclear (7) 7
functionalization (7) 7
indoles (7) 7
palladium (7) 7
aromatic compounds (6) 6
functional groups (6) 6
n-arylacrylamides (6) 6
organic-synthesis (6) 6
synthesis (6) 6
terminal alkynes (6) 6
acids (5) 5
bond (5) 5
boronic acids (5) 5
chemistry (5) 5
copper-catalyzed trifluoromethylation (5) 5
fluorination (5) 5
visible-light (5) 5
alkylierung (4) 4
amines (4) 4
arylation (4) 4
c-h activation (4) 4
functional-group (4) 4
funktionelle gruppe (4) 4
molecular structure (4) 4
organoboronic acids (4) 4
propargylic halides (4) 4
salts (4) 4
terminal alkenes (4) 4
acid (3) 3
asymmetric-synthesis (3) 3
copper (3) 3
cross-coupling (3) 3
diaryliodonium salts (3) 3
drug discovery (3) 3
esters (3) 3
fluorides (3) 3
fluorinated 3,3-disubstituted 2-oxindoles (3) 3
fluoroalkyl analogs (3) 3
halides (3) 3
iodonium salts (3) 3
light-mediated trifluoroethylation (3) 3
mediated trifluoroethylation (3) 3
n-trifluoroethylation (3) 3
nickel (3) 3
nickel-catalysts (3) 3
nickelkatalysator (3) 3
organic-compounds (3) 3
organische synthese (3) 3
photocatalysis (3) 3
photoredox (3) 3
reactivity (3) 3
substrates (3) 3
trifluoroethyl iodide synthesis (3) 3
usage (3) 3
1,1,1-trifluoro-2-iodoethane (2) 2
2-biaryl isothiocyanates (2) 2
activated alkenes (2) 2
additive (2) 2
agonists (2) 2
alkyl-halides (2) 2
alkylations (2) 2
alkyne (2) 2
allylation (2) 2
anilides (2) 2
anilines (2) 2
antagonists (2) 2
bond activation (2) 2
bond formation (2) 2
bonding (2) 2
bromides (2) 2
c-h bonds (2) 2
carbonyl-compounds (2) 2
catalysts (2) 2
complexes (2) 2
conformational study (2) 2
cross‐coupling (2) 2
cupric acetate (2) 2
cyclization (2) 2
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Tetrahedron Letters, ISSN 0040-4039, 01/2018, Volume 59, Issue 5, pp. 462 - 468
[Display omitted] •The additive CF3COOH can convert the substrate to a new active species.•The two-step migration of CF3CH2– group is the dominant path.•This... 
Trifluoroethylation | Additive | DFT
Journal Article
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 11/2019, Volume 55, Issue 87, pp. 13132 - 13135
A novel and direct strategy has been developed for the synthesis of 2-(2,2,2-trifluoroethyl)benzoxazoles by reaction of o-aminophenols and... 
MILD | 2,2,2-TRIFLUOROETHYLATION | C-H TRIFLUOROETHYLATION | BENZOXAZOLES | ARYL IODIDES | ALKYLATIONS | ALKYNES | CATALYZED DECARBOXYLATIVE TRIFLUOROETHYLATION | CHEMISTRY, MULTIDISCIPLINARY | ARYLBORONIC ACIDS
Journal Article
Journal of Fluorine Chemistry, ISSN 0022-1139, 12/2017, Volume 204, pp. 23 - 30
[Display omitted] •A catalyst-free structure-dependent regioselective trifluoroethylation is described.•Cyclic 1,3-diketones exclusively afforded the... 
Structure-dependent | 1,3-Dicarbonyls | (2,2,2-Trifluoroethyl)iodonium | Trifluoroethylation | 2,2,2-TRIFLUOROETHYLATION | ACTIVATION | ASYMMETRIC-SYNTHESIS | DRUG DISCOVERY | CHEMISTRY, ORGANIC | H TRIFLUOROETHYLATION | N-TRIFLUOROETHYLATION | ARYLBORONIC ACIDS | CHEMISTRY, INORGANIC & NUCLEAR | FUNCTIONALIZATION | AMINO-ACIDS | ARYL IODIDES
Journal Article
Chinese Journal of Chemistry, ISSN 1001-604X, 05/2016, Volume 34, Issue 5, pp. 459 - 464
Journal Article
Organic Letters, ISSN 1523-7060, 10/2018, Volume 20, Issue 20, pp. 6480 - 6484
An efficient and transition-metal-free method for the synthesis of the structurally diversified trifluoroethylthiol phenanthridines and... 
TANDEM REACTIONS | C-H TRIFLUOROETHYLATION | ASYMMETRIC-SYNTHESIS | 2-BIARYL ISOTHIOCYANATES | ISOQUINOLINE ALKALOIDS | EFFICIENT SYNTHESIS | CHEMISTRY, ORGANIC | DIARYLIODONIUM SALTS | IODONIUM TRIFLATE | N-TRIFLUOROETHYLATION | ARYLBORONIC ACIDS
Journal Article
CHINESE JOURNAL OF ORGANIC CHEMISTRY, ISSN 0253-2786, 01/2019, Volume 39, Issue 1, pp. 84 - 94
Transition metal-free and metal-catalyzed reactions using aryl(trifluoroethyl) iodonium salts as the trifluoroethylation reagents are summarized in this... 
transition metal-catalyzed | 2,2,2-TRIFLUOROETHYLATION | C-H TRIFLUOROETHYLATION | trifluoroethylation | FLUOROALKYL ANALOGS | CHEMISTRY, ORGANIC | electrophilic | N-TRIFLUOROETHYLATION | ARYLBORONIC ACIDS | INDOLES | PEPTIDES | AMINO-ACIDS | CONSTRUCTION | FLUORINE | transition metal-free | aryl(trifluoroethyl)iodonium salts
Journal Article
Chemical Communications, ISSN 1359-7345, 2017, Volume 53, Issue 94, pp. 12650 - 12653
A novel and highly efficient method for N-fluoroalkylation of amines using 2,4,6-tris(fluoroalkoxy)-1,3,5-triazines was developed. This simple approach allowed... 
TRIFLUOROETHYLATION | ACID | RECEPTOR | ANTAGONISTS | DERIVATIVES | AGONISTS | CHEMISTRY, MULTIDISCIPLINARY | DISCOVERY
Journal Article
Bioorganic & Medicinal Chemistry, ISSN 0968-0896, 2011, Volume 19, Issue 7, pp. 2287 - 2297
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 04/2017, Volume 53, Issue 28, pp. 3945 - 3948
An exclusive catalytic C4-selective fluoroalkylation of indoles with highly active (1H, 1H-perfluoroalkyl)mesityliodonium triflate has been described. The key... 
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 11/2012, Volume 53, Issue 48, pp. 6565 - 6568
A palladium-catalyzed allylation reaction of PhSO2CH2CF3 (2) with a variety of allyl carbonates has been successfully developed for selective... 
Fluorine | Palladium catalysis | Trifluoroethylation | Trifluoroethyl sulfone | Allylation
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 12/2018, Volume 140, Issue 48, pp. 16464 - 16468
Sulfuryl fluoride, SO2F2, has been known and used as a fumigant for over 50 years but it has only recently gained widespread interest as a reagent for organic... 
NUCLEOPHILES | TRIFLUOROETHYLATION | ATOMS | OPTIMIZATION | CHEMISTRY, MULTIDISCIPLINARY | SUFEX
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2014, Volume 53, Issue 9, pp. 2477 - 2480
Journal Article
Chemical Communications, ISSN 1359-7345, 2017, Volume 53, Issue 28, pp. 3945 - 3948
An exclusive catalytic C4-selective fluoroalkylation of indoles with highly active (1H, 1H-perfluoroalkyl) mesityliodonium triflate has been described. The key... 
MEDICINAL CHEMISTRY | DIRECTING GROUP | FUNCTIONALIZATION | TRIFLUOROETHYLATION | SODIUM PERSULFATE | FLUORINE | BOND ACTIVATION | ORTHO-ARYLATION | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | SIMPLE ARENES | Strategy | Palladium | Indoles | Catalysis | Catalysts | Accessibility
Journal Article
Organic Letters, ISSN 1523-7060, 10/2015, Volume 17, Issue 19, pp. 4714 - 4717
The visible-light-induced photoredox difunctionalization reactions of styrenes with 1,1,1-trifluoro-2-iodoethane under an oxygen atmosphere in the presence of... 
ORGANOBORONIC ACIDS | CF3-CONTAINING OXINDOLES | ELECTROPHILIC TRIFLUOROMETHYLATING REAGENTS | TRIFLUOROETHYL IODIDE SYNTHESIS | CHEMISTRY, ORGANIC | PROPARGYLIC HALIDES | TRANSFER RADICAL-ADDITION | MEDIATED TRIFLUOROETHYLATION | TERMINAL ALKENES | FLUOROALKYLSULFONYL CHLORIDES | UNACTIVATED ALKENES
Journal Article
Chemical Communications, ISSN 1359-7345, 03/2015, Volume 51, Issue 21, pp. 4488 - 4491
A novel highly C3 selective metal free trifluoroethylation of indoles using 2,2,2-trifuoroethyl(mesityl)-iodonium triflate was developed. The methodology... 
TRIFLUOROETHYLATION | ALKENES | CROSS-COUPLING REACTIONS | REAGENTS | DIARYLIODONIUM SALTS | ARYL | ALDEHYDES | COPPER-CATALYZED TRIFLUOROMETHYLTHIOLATION | ALKYNES | DIRECT ALKYNYLATION | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Chemical Communications : Chem Comm, ISSN 1359-7345, 01/2017, Volume 53, Issue 94, pp. 12650 - 12653
A novel and highly efficient method for N-fluoroalkylation of amines using 2,4,6-tris(fluoroalkoxy)-1,3,5-triazines was developed. This simple approach allowed... 
Amines
Journal Article
Asian Journal of Organic Chemistry, ISSN 2193-5807, 05/2019, Volume 8, Issue 5, pp. 665 - 670
Reactions of a dimeric [(bzq)Pd(OAc)]2 complex (1 a′) and mesityl(2,2,2‐trifluoroethyl)iodonium triflate (2 a) with or without additives at room temperature... 
density functional calculations | palladium | benzo[h]quinolines | C−H trifluoroethylation | iodonium | 2,2,2-TRIFLUOROETHYLATION | REAGENTS | FLUOROALKYLATION | CHEMISTRY, ORGANIC | ALKYLATIONS | ARYLBORONIC ACIDS | INDOLES | PROGRESS | C-H trifluoroethylation | ARYL | TRIFLUOROMETHYLATION
Journal Article
ACS Catalysis, ISSN 2155-5435, 03/2018, Volume 8, Issue 3, pp. 2173 - 2180
A selective palladium-catalyzed trifluoroethylation reaction of indoles has been developed. The C-H bond activation process, using CF3CH2I as the fluoroalkyl... 
trifluoroethylation | indoles | C-H activation | palladacycle | Catellani reaction | HALIDE-IONS | ACTIVATION | ALKYLATION | CHEMISTRY, PHYSICAL | CASCADE | OXIDATIVE ADDITION | FUNCTIONALIZATION | CROSS-COUPLING REACTIONS | NORBORNENE | ARYL IODIDES | TRIFLUOROMETHYLATION
Journal Article
by Liu, XC and Mao, GJ and Qiao, JY and Xu, CZ and Liu, H and Ma, JJ and Sun, ZZ and Chu, WY
ORGANIC CHEMISTRY FRONTIERS, ISSN 2052-4129, 04/2019, Volume 6, Issue 8, pp. 1189 - 1193
A Ni(TFA)(2)-catalyzed ortho-trifluoromethylation of 8-aminoquinoline derivatives was developed by acyl-directed C-H functionalization. A series of... 
TRIFLUOROETHYLATION | ACTIVATION | HETEROARENES | PHARMACEUTICALS | ARENES | CHEMISTRY, ORGANIC | FLUORINE
Journal Article
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