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chemistry, inorganic & nuclear (84) 84
chemistry, organic (52) 52
chelating triphosphines (41) 41
reactivity (31) 31
triphosphine (24) 24
molecular-structure (23) 23
palladium (23) 23
ruthenium hydride complexes (22) 22
crystal-structure (20) 20
hydride complexes (17) 17
ligands (17) 17
complexes (16) 16
triphosphine ligand (16) 16
platinum (15) 15
chemistry (14) 14
ray crystal-structure (14) 14
ruthenium (13) 13
triphosphines (13) 13
hydrogenation (12) 12
triphosphine complexes (11) 11
chemistry, multidisciplinary (10) 10
x-ray structures (10) 10
cyttp = c6h5p2 (9) 9
crystal structure (8) 8
metal-complexes (8) 8
platinum complexes (8) 8
trinuclear complexes (8) 8
crystal-structures (7) 7
cyclopentadienyl-osmium chemistry (7) 7
derivatives (7) 7
insertion reactions (7) 7
ruthenium complexes (7) 7
chemistry, physical (6) 6
coordination chemistry (6) 6
crystal structures (6) 6
k ec chemistry, inorganic & nuclear (6) 6
palladium complexes (6) 6
phosphine (6) 6
phosphines (6) 6
rhodium (6) 6
terminal alkynes (6) 6
transition-metal complexes (6) 6
transition-metal-complexes (6) 6
x-ray structure (6) 6
5
catalytic dimerization (5) 5
coordination (5) 5
crystallography (5) 5
diyne coordination chemistry (5) 5
gold complexes (5) 5
mechanism (5) 5
molecular-structures (5) 5
organometallic chemistry (5) 5
reaction-mechanism (5) 5
reduction (5) 5
structural-characterization (5) 5
tert-butylacetylene (5) 5
transition-metal (5) 5
tridentate phosphine ligand (5) 5
acetylenes (4) 4
acetylide complexes (4) 4
catalysis (4) 4
cluster (4) 4
electrochemical preparation (4) 4
ligand substitution (4) 4
nmr (4) 4
phosphanes (4) 4
phosphorus (4) 4
rhodium complexes (4) 4
stereoselective dimerization (4) 4
syn-anti isomerism (4) 4
synthesis (4) 4
vinylidene (4) 4
vinylidene complexes (4) 4
1-alkynes (3) 3
alkynes (3) 3
bimetallic and trimetallic triphosphine complexes (3) 3
bisphenylphosphine (3) 3
carbon bond formation (3) 3
carbon-monoxide (3) 3
carbonyl-complexes (3) 3
carboxylato complexes (3) 3
catalysts (3) 3
catalyzed dimerization (3) 3
chemical sciences (3) 3
clusters (3) 3
crystal (3) 3
dihydrogen complexes (3) 3
dimerization (3) 3
dinuclear (3) 3
diphosphines (3) 3
hydride (3) 3
hydroformylation (3) 3
ligand (3) 3
metal strings m (3) 3
nmr spectroscopy (3) 3
nmr-spectroscopy (3) 3
olefins (3) 3
p-31 nmr (3) 3
platinum metals (3) 3
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Angewandte Chemie (International ed.), ISSN 1433-7851, 2015, Volume 54, Issue 3, pp. 1016 - 1021
Journal Article
Dalton transactions : an international journal of inorganic chemistry, ISSN 1477-9226, 2009, Issue 46, pp. 10231 - 10243
Linearly ordered tetraphosphine, meso-bis[(diphenylphosphinomethyl)phenylphosphino]methane(dpmppm), readily reacted with 4 equiv. of CuX in dichloromethane to... 
CU-I | MOLECULAR-STRUCTURE | TRIPHOSPHINE LIGAND | PHOSPHINE-LIGANDS | CU4I4 CORE | TRIRHODIUM CHAIN | CRYSTAL-STRUCTURE DETERMINATION | M4X4 CORE | TRINUCLEAR COMPLEXES | AG-I | CHEMISTRY, INORGANIC & NUCLEAR | Bromides | Dimethyl Sulfoxide | Ligands | Copper - chemistry | Phosphines - chemistry | Chlorides
Journal Article
Organometallics, ISSN 0276-7333, 09/2016, Volume 35, Issue 17, pp. 2793 - 2805
Electrophilic attack with methyl trifluoro­methane­sulfonate or tetrafluoro­boric acid, to new alkynyl rhodium complexes containing alkenylphosphanes, leads to... 
METAL VINYLIDENES | CHELATING TRIPHOSPHINES | CARBON BOND ACTIVATION | ALPHA-ALKENYLPHOSPHINE | REACTIVITY | CHEMISTRY, ORGANIC | RUTHENIUM HYDRIDE COMPLEXES | TERMINAL ALKYNES | DIMERIZATION | 2+2 CYCLOADDITION | SPONTANEOUS RESOLUTION | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Organometallics, ISSN 0276-7333, 05/2011, Volume 30, Issue 9, pp. 2571 - 2580
In our efforts to probe the reaction mechanism of the endo cycloisomerization of alkynols catalyzed by the complex [Ru(N3P)(OAc)](BPh4) (1; NP3 =... 
EQUIVALENT-TO-C | ANTI-MARKOVNIKOV HYDRATION | CHELATING TRIPHOSPHINES | CHEMISTRY, ORGANIC | TERMINAL ALKYNES | ALLENYLIDENE COMPLEXES | VINYLIDENE COMPLEXES | BOND-CLEAVAGE | CATALYZED RECONSTITUTIVE CONDENSATION | HYDRIDE COMPLEXES | CARBOXYLIC-ACIDS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
CHEMISTRY-A EUROPEAN JOURNAL, ISSN 0947-6539, 01/2017, Volume 23, Issue 3, pp. 524 - 528
By using a chiral tetraphosphine, rac-bis[(diphenylphosphinomethyl)phenylphosphino]methane (rac-dpmppm), linear octapalladium chains were synthesized as... 
chiral self-recognition | metal atom chains | METAL STRINGS M | COMPLEXES | PT-6 | palladium | ATOMS | TRIPHOSPHINE LIGANDS | octanuclear complexes | CHEMISTRY, MULTIDISCIPLINARY | tetraphosphines
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 12/2014, Volume 53, Issue 24, pp. 12720 - 12731
In this study, a new family of tetranuclear gold(I) triphosphine derivatives bearing alkynyl and thiolate groups have been efficiently synthesized by treating... 
GOLD(I) COMPLEXES | EXCITED-STATE | PHOSPHINE | DENSITY-FUNCTIONAL METHODS | STRUCTURAL-CHARACTERIZATION | COORDINATION | BASIS-SETS | TRIPHOSPHINE | THEORETICAL CHEMISTRY | ALKYNYL CLUSTERS | CHEMISTRY, INORGANIC & NUCLEAR | Gold compounds | Chemical properties | Analysis | Luminescence
Journal Article
Journal of organometallic chemistry, ISSN 0022-328X, 2020, Volume 917, p. 121291
Novel complexes of ruthenium with tridentate phosphine ligands: tris(diphenylphosphinomethyl)ethane and bis(2-diphenylphosphinoethyl)phenylphosphine were... 
Cyclic voltammetry | Ruthenium | Triphosphines | Metallacarboranes | ATRP | DESIGN | TRIPHOS | REACTIVITY | CHEMISTRY, ORGANIC | CHEMISTRY, INORGANIC & NUCLEAR | ALCOHOLS | CLOSO-RUTHENACARBORANES | REDUCTION
Journal Article
Organometallics, ISSN 1520-6041, 2020, Volume 39, Issue 3, pp. 433 - 442
A series of ruthenaindene complexes containing electron-donating and -withdrawing groups were synthesized and characterized. The ruthenaindenes were... 
CATALYSIS | CHELATING TRIPHOSPHINES | REACTION-MECHANISM | TERT-BUTYLACETYLENE | MOLECULAR-STRUCTURES | REACTIVITY | CHEMISTRY | CHEMISTRY, ORGANIC | RUTHENIUM HYDRIDE COMPLEXES | STRUCTURAL-CHARACTERIZATION | DIMERIZATION | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Journal of organometallic chemistry, ISSN 0022-328X, 2016, Volume 814, pp. 35 - 41
From a reaction of [Pt3(μ-dpmp)2(XylNC)2](PF6)2 (1a) with NaBH4 and [Pt(dba)2] in N,N-dimethyl formamide (DMF), a trihydride hexaplatinum complex,... 
Triphosphine | Hydride | Hexanuclear complex | Platinum | Crystal structure | PT-6 | CHEMISTRY, ORGANIC | CHEMISTRY, INORGANIC & NUCLEAR | FRAGMENTS | METAL STRINGS M | TETRAPHOSPHINE LIGANDS | CHAINS | BOND
Journal Article
ACS Catalysis, ISSN 2155-5435, 09/2018, Volume 8, Issue 9, pp. 7973 - 7982
Journal Article
Journal of molecular structure, ISSN 0022-2860, 2020, Volume 1200, p. 127129
The triphosphines-containing ruthenium-acetato complexes [RuCl(κ2-OAc)(triphos)] (2) and the new analogue synthesized in our research group [RuCl(κ2-OAc)(etp)]... 
Cyclic voltammetry | Ruthenium | DFT | Acetate | Triphosphines | Formic acid decomposition | METHYLATION | MOLDEN | AMMONIA | REACTIVITY | CHEMISTRY, PHYSICAL | HYDROGEN-STORAGE | UTILIZING CARBON-DIOXIDE | AMINATION | LIGANDS | CHEMISTRY | DERIVATIVES
Journal Article
Bulletin of the Chemical Society of Japan, ISSN 0009-2673, 7/2002, Volume 75, Issue 7, pp. 1407 - 1422
This paper reviews the recent development of linearly ordered multinuclear transition-metal complexes, which have been of increasing interest as potential... 
6-DIPHENYLPHOSPHINO-2-PYRIDONATE LIGANDS | ELECTROCHEMICAL PREPARATION | CLUSTER COMPLEXES | TRIPHOSPHINE LIGAND | TRIDENTATE PHOSPHINE LIGAND | TRINUCLEAR COMPLEXES | BINUCLEAR PALLADIUM(I) COMPLEXES | DI(2-PYRIDYL)AMIDE DPA LIGANDS | ALIGNED TETRAMETAL SYSTEM | CHEMISTRY, MULTIDISCIPLINARY | RAY CRYSTAL-STRUCTURE
Journal Article
HETEROCYCLES, ISSN 0385-5414, 01/2005, Volume 65, Issue 1, pp. 181 - 185
Phosphorus compound prepared by reaction of triphenylphosphine with trichloroisocyanuric acid was found to be applied to chlorination of nitrogen-containing... 
CHEMISTRY, ORGANIC | SUBSTITUTION | DERIVATIVES | RING | OXIDATIVE MAGNESIATION
Journal Article
DALTON TRANSACTIONS, ISSN 1477-9226, 2015, Volume 44, Issue 48, pp. 21016 - 21024
Reactions of cis-RuCl2(dppm)(2) with various terminal alkynes, of the type HC CC6H4-4-R (1 equiv.), in the presence of TlBF4 have resulted in the formation of... 
SIGMA-ACETYLIDE COMPLEXES | CHELATING TRIPHOSPHINES | ACTIVE MOLECULAR WIRES | ORGANOMETALLIC COMPLEXES | CHARGE-TRANSPORT | RUTHENIUM HYDRIDE COMPLEXES | TRIRUTHENIUM COMPLEXES | NONLINEAR OPTICS | METAL-COMPLEXES | RAY CRYSTAL-STRUCTURE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2010, Volume 49, Issue 1, pp. 188 - 192
One at a time: Stepwise opening and final removal of the η1‐bound Cp* substituents in the bridged pentelidene complexes [Cp*E{W(CO)5}2] (E=P, As) occurs by the... 
pentamethylcyclopentadiene | pentelidene complexes | arsenic | triphosphines | phosphorus | Phosphorus | Pentelidene complexes | Arsenic | Triphosphines | Pentamethylcyclopentadiene | GROUP-15 | REACTIVITY | CLEAVAGE | MAIN-GROUP ELEMENTS | CHEMISTRY, MULTIDISCIPLINARY | PHOSPHINIDENE COMPLEXES | CHEMISTRY | LIGAND | WHITE PHOSPHORUS | DIPHOSPHENE | PHOSPHORUS TRIPLE BOND
Journal Article
Journal of organometallic chemistry, ISSN 0022-328X, 2010, Volume 695, Issue 8, pp. 1138 - 1145
The new triphosphine ligand, N(CH 2PCy 2) 3, preferentially forms bidentate group 6 metal tetracarbonyl complexes owing to its steric bulk at the metal centre.... 
Tetracarbonyl | Triphosphine | Phosphine | Multimetallic | COORDINATION CHEMISTRY | HYDROGENATION | TRANSITION-METAL-COMPLEXES | MEC(CH2PPH2) | MOLYBDENUM | POLYPHOSPHINE LIGANDS | REACTIVITY | SECONDARY | CHEMISTRY, ORGANIC | CRYSTAL-STRUCTURES | CHEMISTRY, INORGANIC & NUCLEAR | PRECURSORS
Journal Article
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