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Angewandte Chemie International Edition, ISSN 1433-7851, 09/2017, Volume 56, Issue 40, pp. 12245 - 12249
Palladium‐catalyzed activation of remote meta‐C−H bonds in arenes containing tethered alcohols was achieved with high regioselectivity by using a nitrile... 
density-functional calculations | regioselectivity | palladium | C−H activation | arenes | DIRECTING GROUP | ARYLATION | CHEMISTRY, MULTIDISCIPLINARY | FUNCTIONALIZATION | ACID-DERIVATIVES | C-H activation | U-SHAPED TEMPLATE | OLEFINATION | ANILINES | LIGAND | SELECTIVITY | BORYLATION | Palladium | Regioselectivity | Aromatic compounds | Computer applications | Alcohol | Activation | Alcohols
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2017, Volume 56, Issue 12, pp. 3182 - 3186
To expand the scope of meta‐functionalization, a pyrimidine‐based template effective for the formation of β‐aryl aldehydes and ketones, using allyl alcohols,... 
alkenylation | alkylation | palladium | C−H activation | arenes | DIRECTING GROUP | ACTIVATION | DIRECT ARYLATION | CHEMISTRY, MULTIDISCIPLINARY | REDOX-RELAY STRATEGY | FUNCTIONALIZATION | CROSS-COUPLING REACTIONS | C-H activation | U-SHAPED TEMPLATE | OLEFINATION | ALLYLIC ALCOHOLS | HECK ARYLATIONS | Esters | Pyrimidines | Palladium | Aldehydes
Journal Article
Chemical Communications, ISSN 1359-7345, 2017, Volume 53, Issue 99, pp. 13209 - 13212
A traceless organosilicon template-directed meta-selective-C-H alkenylation of phenols was realized with good yields and high selectivities. The template was... 
DIRECTING GROUP | FUNCTIONALIZATION | ACTIVATION | U-SHAPED TEMPLATE | OLEFINATION | ACIDS | COUPLING REACTION | ARYLATION | BOND FORMATION | LIGAND | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Chemical Communications : Chem Comm, ISSN 1359-7345, 01/2017, Volume 53, Issue 99, pp. 13209 - 13212
A traceless organosilicon template-directed meta-selective-C–H alkenylation of phenols was realized with good yields and high selectivities. The template was... 
Phenols | Aromatic compounds
Journal Article
Organic Letters, ISSN 1523-7060, 01/2018, Volume 20, Issue 2, pp. 425 - 428
An effective pyridine based U-shaped template has been developed to enable a diverse range of meta-C–H functionalizations of phenylacetic acid scaffolds. This... 
DIRECTING GROUP | ACTIVATION | U-SHAPED TEMPLATE | OLEFINATION | ALKYLATION | ARYLATION | ARENES | BONDS | CHEMISTRY, ORGANIC | LIGAND | BORYLATION
Journal Article
ACS Catalysis, ISSN 2155-5435, 05/2017, Volume 7, Issue 5, pp. 3162 - 3168
Strong σ-coordination by a heteroatom containing directing group (DG) is one of the effective strategies for performing site-selective C–H functionalization.... 
palladium | DFT | meta-C-H activation | acetoxylation | olefination | DIRECTING GROUP | ACTIVATION | ARYLATION | AMINO-ACID LIGANDS | CHEMISTRY, PHYSICAL | CARBON-HYDROGEN BONDS | AB-INITIO PSEUDOPOTENTIALS | ALKYL-HALIDES | BIDENTATE-CHELATION ASSISTANCE | TRANSITION-ELEMENTS | U-SHAPED TEMPLATE
Journal Article
Green Chemistry, ISSN 1463-9262, 2017, Volume 19, Issue 18, pp. 4272 - 4277
Oximes have been identified as reusable templates for the synthesis of ureas and carbamates by an in situ generation of carbamoyl oximes under metal-free... 
GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY | U-SHAPED TEMPLATE | CURTIUS REARRANGEMENT | BOC-PROTECTED AMINES | ONE-POT SYNTHESIS | CATALYZED SYNTHESIS | ISOCYANIDE INSERTION | C-H FUNCTIONALIZATION | UNSYMMETRICALLY SUBSTITUTED UREAS | CHEMISTRY, MULTIDISCIPLINARY | TRANSIENT DIRECTING GROUP | CARBOXYLIC-ACIDS
Journal Article
Chinese Journal of Catalysis, ISSN 1872-2067, 01/2016, Volume 37, Issue 1, pp. 98 - 101
The -selective C–H activation of toluene-type substrates has been achieved using a strained biphenyl-type template, and a highly selective -C–H borylation of... 
DIRECTING GROUP | ALKYLATION | ARYLATION | AMINO-ACID LIGANDS | CHEMISTRY, PHYSICAL | ELECTRON-DEFICIENT ARENES | FUNCTIONALIZATION | ENGINEERING, CHEMICAL | U-SHAPED TEMPLATE | OLEFINATION | BONDS | CHEMISTRY, APPLIED | BORYLATION
Journal Article
ACS Central Science, ISSN 2374-7943, 10/2015, Volume 1, Issue 7, pp. 394 - 399
The pyridyl group has been extensively employed to direct transition-metal-catalyzed C–H activation reactions in the past half-century. The typical cyclic... 
DIRECTING GROUP | FUNCTIONALIZATION | U-SHAPED TEMPLATE | OLEFINATION | ACIDS | ALKYLATION | ARENES | 2-PHENYLPYRIDINES | BOND FORMATION | CHEMISTRY, MULTIDISCIPLINARY | CATALYZED ARYLATION
Journal Article
Journal Article
Organic & biomolecular chemistry, ISSN 1477-0520, 06/2016, Volume 14, Issue 24, pp. 5440 - 5453
The directing group assisted site selective C-H functionalization approach is having a continuous impact in the field of natural product synthesis, drug... 
Journal Article
by Fan, ZL and Ni, JB and Zhang, A
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 07/2016, Volume 138, Issue 27, pp. 8470 - 8475
The first example of transition metal-catalyzed meta-selective C-Ar-H nitration of arenes is described. With the use of Ru-3(CO)(12) as the catalyst and... 
TRACELESS DIRECTING GROUPS | NITROARENES | ACTIVATION | U-SHAPED TEMPLATE | DIRECT ARYLATION | OLEFINATION | NATURAL-PRODUCTS | BOND FUNCTIONALIZATION | PD CATALYSTS | CHEMISTRY, MULTIDISCIPLINARY | CARBOXYLIC-ACIDS
Journal Article
Chemical Society Reviews, ISSN 0306-0012, 7/2017, Volume 46, Issue 14, pp. 4299 - 4328
Recent advances in transition metal-catalyzed C-H bond functionalization have profoundly impacted synthetic strategy. Since organic substrates typically... 
TRACELESS DIRECTING GROUP | ROOM-TEMPERATURE | U-SHAPED TEMPLATE | PARA-SELECTIVE ALKYLATION | ARYL BORONIC ACIDS | REGIOSELECTIVE SYNTHESIS | NICKEL/LEWIS ACID CATALYSIS | CARBON-HYDROGEN BONDS | COOPERATIVE NICKEL/ALUMINUM CATALYSIS | DIRECT C-2 ARYLATION | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 6/2016, Volume 14, Issue 24, pp. 544 - 5453
The directing group assisted site selective C-H functionalization approach is having a continuous impact in the field of natural product synthesis, drug... 
TRACELESS DIRECTING GROUP | CROSS-COUPLING REACTIONS | U-SHAPED TEMPLATE | OLEFINATION | CONJUGATED POLYMERS | ARYLATION | ARENES | CHEMISTRY, ORGANIC | BOND ACTIVATION | LIGAND | DERIVATIVES
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 03/2015, Volume 137, Issue 11, pp. 3775 - 3778
We report the first example of ipso-borylation for the modular 1,2-bisfunctionalization of aryl iodides via C–H functionalization. The carbon–boron bond is... 
HALIDES | PALLADIUM(II) COMPLEX | ACTIVATION | U-SHAPED TEMPLATE | NORBORNENE | OLEFINATION | HETEROCYCLES | VINYLARENES | TOSYLHYDRAZONE INSERTION REACTION | CHEMISTRY, MULTIDISCIPLINARY | Chemical bonds | Chemical properties | Research | Chemical synthesis | Aromatic compounds
Journal Article
Chemical Society Reviews, ISSN 0306-0012, 1/2018, Volume 47, Issue 1, pp. 149 - 171
The elaboration of simple arenes in order to access more complex substitution patterns is a crucial endeavor for synthetic chemists, given the central role... 
DIRECTING GROUP | REMOVABLE AUXILIARIES | U-SHAPED TEMPLATE | AMINO-ACID LIGANDS | SELECTIVE ARYLATION | RUTHENIUM CATALYSTS | SITE-SELECTIVITY | NONCOVALENT INTERACTIONS | CHEMISTRY, MULTIDISCIPLINARY | PHENOL DERIVATIVES | ARYLSULFONYL CHLORIDES
Journal Article
Nature, ISSN 0028-0836, 03/2015, Volume 519, Issue 7543, pp. 334 - 338
Journal Article