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Organic Chemistry Frontiers, ISSN 2052-4110, 07/2017, Volume 4, Issue 7, pp. 1435 - 1467
The transition metal-catalyzed transformation of otherwise inert C-H bonds into substituted alkenes offers a versatile tool for the synthesis of value added... 
CROSS-COUPLING REACTIONS | OXIDIZING DIRECTING GROUP | FUJIWARA-MORITANI REACTIONS | PALLADIUM(II)-CATALYZED ORTHO-OLEFINATION | NATURAL-PRODUCT SYNTHESIS | U-SHAPED TEMPLATE | CHEMISTRY, ORGANIC | ELECTRON-DEFICIENT ARENES | CARBON-HYDROGEN BONDS | DEHYDROGENATIVE HECK REACTION | CATALYZED DIRECT ARYLATION
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 02/2015, Volume 137, Issue 4, pp. 1593 - 1600
The rhodium-catalyzed reaction of aryl 2-pyridyl ethers with a diboron reagent results in the formation of arylboronic acid derivatives via activation of the... 
CYANO BONDS | CROSS-COUPLING REACTIONS | U-SHAPED TEMPLATE | R-CN | TRANSITION-METAL-COMPLEXES | H/D EXCHANGE | CATIONIC RH(III) | DIRECT ORTHO ARYLATION | C-H ACTIVATION | CHEMISTRY, MULTIDISCIPLINARY | IRON-COMPLEX | Hydrogen | Carbon compounds | Chemical properties
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2016, Volume 55, Issue 27, pp. 7751 - 7755
Various practical methods for the selective C−H functionalization of the ortho and recently also of the meta position of an arene have already been developed.... 
palladium | silicon | C−H activation | synthetic methods | olefination | META | ACTIVATION | CARBON-HYDROGEN BONDS | CHEMISTRY, MULTIDISCIPLINARY | ALKYL-HALIDES | C-H activation | U-SHAPED TEMPLATE | SELECTIVE ARYLATION | ORTHO-ARYLATION | MULTISUBSTITUTED ARENES | DERIVATIVES | Phenols | Palladium
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 09/2015, Volume 137, Issue 38, pp. 12231 - 12240
By developing a new Ir­(III)-catalyzed C–C cross-coupling, a versatile method for direct arylation of sp2 and sp3 C–H bonds in ketoximes, nitrogen-containing... 
C(SP)-H BONDS | CROSS-COUPLING REACTIONS | CHELATION-ASSISTANCE | U-SHAPED TEMPLATE | MILD CONDITIONS | LATE-STAGE DIVERSIFICATION | ARYL HALIDES | CARBON-HYDROGEN BONDS | CHEMISTRY, MULTIDISCIPLINARY | INTERMOLECULAR ARYLATION | CATALYZED DIRECT ARYLATION | Arylation | Aromatic compounds | Chemical bonds | Catalysis | Research | Iridium | Chemical properties
Journal Article
Nature Chemistry, ISSN 1755-4330, 04/2017, Volume 9, Issue 4, pp. 361 - 368
The direct and selective functionalization of C-H bonds of arenes is one of the most challenging yet valuable aims in organic synthesis. Despite notable recent... 
DIRECTING GROUP | DOMINO REACTION | FUNCTIONALIZATION | ACTIVATION | U-SHAPED TEMPLATE | ARYLATION | ARENES | EFFICIENT SYNTHESIS | C(SP)-H | CHEMISTRY, MULTIDISCIPLINARY | Aromatic compounds | Indole | Benzofuran | Computer applications | Cleavage | Palladium | Alkylation
Journal Article
ACS Catalysis, ISSN 2155-5435, 11/2015, Volume 5, Issue 11, pp. 7008 - 7014
A one-pot two-step method for para-selective C–H amination of carbocyclic arenes comprises the in situ formation of unsymmetrical diaryl-λ3-iodanes followed by... 
hypervalent iodine | regioselectivity | diaryliodonium salts | copper | amination | ACTIVATION | INTERMOLECULAR AMINATION | CHEMISTRY, PHYSICAL | AMBIENT-TEMPERATURE | FUNCTIONALIZATION | MILD | DIRECTED AMINATION | U-SHAPED TEMPLATE | N BOND FORMATION | IMIDATION
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 03/2017, Volume 23, Issue 14, pp. 3285 - 3290
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 2017, Volume 15, Issue 28, pp. 5993 - 6000
A catalytic meta selective C-H alkylation of arenes is described using a wide range of alpha-halo carbonyls as coupling partners. Previously unreported primary... 
DIRECTING GROUP | U-SHAPED TEMPLATE | NATURAL-PRODUCTS | ARENES | ARYLATION | CHEMISTRY, ORGANIC | ORTHO-METALATION STRATEGY | BOND ACTIVATION | LIGAND | CARBOXYLIC-ACIDS | ALKYL-HALIDES
Journal Article
Chemistry – An Asian Journal, ISSN 1861-4728, 03/2016, Volume 11, Issue 6, pp. 882 - 892
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 02/2016, Volume 81, Issue 3, pp. 1006 - 1020
DFT calculations have been carried out to investigate the reaction mechanism for PdII-mediated enantioselective C–H iodination. Iodination of the aryl ortho... 
DENSITY FUNCTIONALS | U-SHAPED TEMPLATE | ASYMMETRIC-SYNTHESIS | OLEFINATION | KINETIC RESOLUTION | ARYLATION | CHEMISTRY, ORGANIC | BOND ACTIVATION | LIGAND | DIRECTING-GROUP | ACTIVATION REACTIONS
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2018, Volume 57, Issue 26, pp. 7659 - 7663
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2017, Volume 56, Issue 19, pp. 5272 - 5276
Rhodium‐catalyzed ortho‐C−H functionalization is well known in the literature. Described herein is the Xphos‐supported rhodium catalysis of meta‐C−H... 
regioselectivity | reaction mechanisms | reaction kinetics | C−H activation | rhodium | DIRECTING GROUP | ARYLATION | AMINO-ACID LIGANDS | INTERNAL ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | C-H activation | U-SHAPED TEMPLATE | OLEFINATION | PHENOLS | BOND ACTIVATION | DERIVATIVES | BORYLATION
Journal Article
by Fan, ZL and Ni, JB and Zhang, A
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 07/2016, Volume 138, Issue 27, pp. 8470 - 8475
The first example of transition metal-catalyzed meta-selective C-Ar-H nitration of arenes is described. With the use of Ru-3(CO)(12) as the catalyst and... 
TRACELESS DIRECTING GROUPS | NITROARENES | ACTIVATION | U-SHAPED TEMPLATE | DIRECT ARYLATION | OLEFINATION | NATURAL-PRODUCTS | BOND FUNCTIONALIZATION | PD CATALYSTS | CHEMISTRY, MULTIDISCIPLINARY | CARBOXYLIC-ACIDS
Journal Article
Organic Letters, ISSN 1523-7060, 12/2015, Volume 17, Issue 24, pp. 5966 - 5969
The Pd­(II)-catalyzed arylation of unactivated β-C­(sp3)–H bonds in α-hydroxy aliphatic acid with a variety of aryl iodides was developed utilizing an amino... 
FUNCTIONALIZATION | C(SP)-H BONDS | ACTIVATION | U-SHAPED TEMPLATE | OLEFINATION | ALKYLATION | CHEMISTRY, ORGANIC | IODINATION | AUXILIARY | C-H BONDS | PALLADIUM ACETATE | Magnetic Resonance Spectroscopy | Amino Acids - chemistry | Molecular Structure | Catalysis | Hydrocarbons, Iodinated - chemistry | Hydroxy Acids - chemistry | Palladium - chemistry
Journal Article
Organic & Biomolecular Chemistry, ISSN 1477-0520, 06/2017, Volume 15, Issue 24, pp. 5112 - 5116
With the assistance of the same bidentate directing group, the first example of sequential, controllable C-H functionalization of beta -arylethylamines at... 
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 2017, Volume 15, Issue 24, pp. 5112 - 5116
With the assistance of the same bidentate directing group, the first example of sequential, controllable C-H functionalization of beta-arylethylamines at... 
DIRECTING GROUP | AROMATIC FUNCTIONALIZATION | C(SP)-H BONDS | CROSS-COUPLING REACTIONS | U-SHAPED TEMPLATE | CHEMISTRY, ORGANIC | DIRECT (HETERO)ARYLATION | CARBON-HYDROGEN BONDS | OXALYL AMIDE | PHENOL DERIVATIVES | EPSILON-POSITIONS
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2018, Volume 57, Issue 9, pp. 2497 - 2501
Journal Article