ChemPhysChem, ISSN 1439-4235, 06/2015, Volume 16, Issue 8, pp. 1582 - 1592
On‐surface synthesis constitutes a rapidly growing field of research due to its promising application for creating stable molecular structures on surfaces....
two‐dimensional confinement | ultrahigh vacuum | molecular electronics | scanning probe microscopy | molecular structure formation | Molecular structure formation | Molecular electronics | Scanning probe microscopy | Two-dimensional confinement | Ultrahigh vacuum | two-dimensional confinement | AZIDE-ALKYNE CYCLOADDITION | CATALYZED CYCLODEHYDROGENATION | AROMATIC PRECURSORS | MOLECULAR BUILDING-BLOCKS | PHYSICS, ATOMIC, MOLECULAR & CHEMICAL | CHEMISTRY, PHYSICAL | ULLMANN POLYMERIZATION | COVALENT ORGANIC FRAMEWORKS | BULK INSULATOR | SCANNING-TUNNELING-MICROSCOPY | METAL-SURFACES | ULTRAHIGH-VACUUM
two‐dimensional confinement | ultrahigh vacuum | molecular electronics | scanning probe microscopy | molecular structure formation | Molecular structure formation | Molecular electronics | Scanning probe microscopy | Two-dimensional confinement | Ultrahigh vacuum | two-dimensional confinement | AZIDE-ALKYNE CYCLOADDITION | CATALYZED CYCLODEHYDROGENATION | AROMATIC PRECURSORS | MOLECULAR BUILDING-BLOCKS | PHYSICS, ATOMIC, MOLECULAR & CHEMICAL | CHEMISTRY, PHYSICAL | ULLMANN POLYMERIZATION | COVALENT ORGANIC FRAMEWORKS | BULK INSULATOR | SCANNING-TUNNELING-MICROSCOPY | METAL-SURFACES | ULTRAHIGH-VACUUM
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 07/2014, Volume 79, Issue 14, pp. 6395 - 6402
A mild and versatile method for the construction of C–N bonds by the reaction of (2,2-difluorovinyl)arenes with various N–H-containing heterocycles in the...
NITROGEN-CONTAINING HETEROCYCLES | ARYL BROMIDES | CATALYZED N-ARYLATION | INTRAMOLECULAR CYCLIZATION | DIPEPTIDYL-PEPTIDASE-IV | CROSS-COUPLING REACTION | NUCLEOPHILIC 5-ENDO-TRIG CYCLIZATION | C-N | CHEMISTRY, ORGANIC | ULLMANN-TYPE REACTION | VINYL BROMIDES | Azoles - chemistry | Hydrocarbons, Fluorinated - chemical synthesis | Heterocyclic Compounds - chemical synthesis | Hydrocarbons, Fluorinated - chemistry | Molecular Structure | Heterocyclic Compounds - chemistry | Azoles (Class of compounds) | Chemical properties | Research | Structure | Chemical synthesis | Olefins
NITROGEN-CONTAINING HETEROCYCLES | ARYL BROMIDES | CATALYZED N-ARYLATION | INTRAMOLECULAR CYCLIZATION | DIPEPTIDYL-PEPTIDASE-IV | CROSS-COUPLING REACTION | NUCLEOPHILIC 5-ENDO-TRIG CYCLIZATION | C-N | CHEMISTRY, ORGANIC | ULLMANN-TYPE REACTION | VINYL BROMIDES | Azoles - chemistry | Hydrocarbons, Fluorinated - chemical synthesis | Heterocyclic Compounds - chemical synthesis | Hydrocarbons, Fluorinated - chemistry | Molecular Structure | Heterocyclic Compounds - chemistry | Azoles (Class of compounds) | Chemical properties | Research | Structure | Chemical synthesis | Olefins
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 01/2013, Volume 355, Issue 1, pp. 53 - 58
Herein, an efficient method for the Ullmann CO coupling reaction between various kinds of phenols and aryl halides, including amino, ketone, cyano, methyl,...
catalyst recycling | copper ferrite (CuFe2O4) | Ullmann reaction | magnetic particles | CO cross‐coupling | C-O cross-coupling | copper ferrite (CuFe | POTASSIUM TERT-BUTOXIDE | CHEMISTRY, ORGANIC | C?O cross-coupling | BOND FORMATION | EFFICIENT CATALYST | MILD CONDITIONS | PHENOLS | VERSATILE | DIARYL ETHER FORMATION | ARYL HALIDES | CHEMISTRY, APPLIED | N-ARYLATION | NITROGEN LIGANDS | Nanoparticles | PARTICLES | FERRITE | Derivatives | Recycled | Copper | JOINING | CATALYSTS | CU
catalyst recycling | copper ferrite (CuFe2O4) | Ullmann reaction | magnetic particles | CO cross‐coupling | C-O cross-coupling | copper ferrite (CuFe | POTASSIUM TERT-BUTOXIDE | CHEMISTRY, ORGANIC | C?O cross-coupling | BOND FORMATION | EFFICIENT CATALYST | MILD CONDITIONS | PHENOLS | VERSATILE | DIARYL ETHER FORMATION | ARYL HALIDES | CHEMISTRY, APPLIED | N-ARYLATION | NITROGEN LIGANDS | Nanoparticles | PARTICLES | FERRITE | Derivatives | Recycled | Copper | JOINING | CATALYSTS | CU
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 09/2015, Volume 137, Issue 37, pp. 11942 - 11945
A class of oxalic diamides are found to be effective ligands for promoting CuI-catalyzed aryl amination with less reactive (hetero)aryl chlorides. The...
ROOM-TEMPERATURE | AMINATION | C-N | ARYL HALIDES | EFFICIENT COPPER CATALYST | BOND FORMATION | ULLMANN REACTION | LIGAND | N-ARYLATION | CONTAINING HETEROCYCLES | CHEMISTRY, MULTIDISCIPLINARY | Amines - chemistry | Copper - chemistry | Oxalic Acid - chemistry | Chlorine - chemistry | Diamide - chemistry | Iodides - chemistry | Catalysis | Ligands | Aromatic amines | Research
ROOM-TEMPERATURE | AMINATION | C-N | ARYL HALIDES | EFFICIENT COPPER CATALYST | BOND FORMATION | ULLMANN REACTION | LIGAND | N-ARYLATION | CONTAINING HETEROCYCLES | CHEMISTRY, MULTIDISCIPLINARY | Amines - chemistry | Copper - chemistry | Oxalic Acid - chemistry | Chlorine - chemistry | Diamide - chemistry | Iodides - chemistry | Catalysis | Ligands | Aromatic amines | Research
Journal Article
Coordination Chemistry Reviews, ISSN 0010-8545, 12/2004, Volume 248, Issue 21-24, pp. 2337 - 2364
In the last decade, a number of methods using various copper complexes and salts to carry out cross-coupling reactions leading to the formation of Cheteroatom...
Cross-coupling | Catalysis | Copper | Ullmann reaction | CATALYZED N-ARYLATION | IODIDE-PROMOTED ALLYLATION | SALICYLIC-ACID DERIVATIVES | catalysis | AROMATIC NUCLEOPHILIC-SUBSTITUTION | CHEMISTRY, INORGANIC & NUCLEAR | DIARYL ETHER SYNTHESIS | ORTHO C-CL | cross-coupling | 2-CARBOXY SUBSTITUTED DIPHENYLETHERS | copper | UNACTIVATED ARYL HALIDES | GRIGNARD-REAGENTS | MIZOROKI-HECK TYPE
Cross-coupling | Catalysis | Copper | Ullmann reaction | CATALYZED N-ARYLATION | IODIDE-PROMOTED ALLYLATION | SALICYLIC-ACID DERIVATIVES | catalysis | AROMATIC NUCLEOPHILIC-SUBSTITUTION | CHEMISTRY, INORGANIC & NUCLEAR | DIARYL ETHER SYNTHESIS | ORTHO C-CL | cross-coupling | 2-CARBOXY SUBSTITUTED DIPHENYLETHERS | copper | UNACTIVATED ARYL HALIDES | GRIGNARD-REAGENTS | MIZOROKI-HECK TYPE
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 12/2010, Volume 16, Issue 46, pp. 13613 - 13616
Unique ligand acceleration: A kinetic investigation of the copper‐catalyzed CN cross‐coupling in the sub‐mol % range reveals an exceptional ligand dependence....
copper | ligand acceleration | cross‐coupling | kinetics | sub‐mol % catalysis | cross-coupling | sub-mol % catalysis | HALIDES | sub-mol% catalysis | ARYLATION | COMPLEXES | AMIDATION | IMIDAZOLES | CHEMISTRY, MULTIDISCIPLINARY | DIAMINE LIGANDS | NUCLEOPHILES | ARYL IODIDES | EFFICIENT | ULLMANN | Pyrazoles - chemistry | Copper - chemistry | Cross-Linking Reagents - chemistry | Ligands | Molecular Structure | Catalysis | Kinetics | Cross coupling | Low concentrations | Catalysts | Reaction kinetics | Chemical reactions | Copper | Acceleration | Kemi | Chemical Sciences
copper | ligand acceleration | cross‐coupling | kinetics | sub‐mol % catalysis | cross-coupling | sub-mol % catalysis | HALIDES | sub-mol% catalysis | ARYLATION | COMPLEXES | AMIDATION | IMIDAZOLES | CHEMISTRY, MULTIDISCIPLINARY | DIAMINE LIGANDS | NUCLEOPHILES | ARYL IODIDES | EFFICIENT | ULLMANN | Pyrazoles - chemistry | Copper - chemistry | Cross-Linking Reagents - chemistry | Ligands | Molecular Structure | Catalysis | Kinetics | Cross coupling | Low concentrations | Catalysts | Reaction kinetics | Chemical reactions | Copper | Acceleration | Kemi | Chemical Sciences
Journal Article
Chemical Science, ISSN 2041-6520, 6/2010, Volume 1, Issue 1, pp. 13 - 31
The utility of copper-mediated cross-coupling reactions has been significantly increased by the development of mild reaction conditions and the ability to...
NITROGEN-CONTAINING HETEROCYCLES | CROSS-COUPLING REACTIONS | ULLMANN-TYPE SYNTHESIS | AMINO-ACID | SULFINIC ACID SALTS | DIPEPTIDYL-PEPTIDASE-IV | C-N | ARYL HALIDES | N BOND FORMATION | HIGHLY EFFICIENT SYNTHESIS | CHEMISTRY, MULTIDISCIPLINARY
NITROGEN-CONTAINING HETEROCYCLES | CROSS-COUPLING REACTIONS | ULLMANN-TYPE SYNTHESIS | AMINO-ACID | SULFINIC ACID SALTS | DIPEPTIDYL-PEPTIDASE-IV | C-N | ARYL HALIDES | N BOND FORMATION | HIGHLY EFFICIENT SYNTHESIS | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Chemistry of Heterocyclic Compounds, ISSN 0009-3122, 1/2014, Volume 49, Issue 10, pp. 1400 - 1425
Our review concerns the classical heterocyclic name reactions of pyrrole derivatives that were discovered in late 19th and early 20th centuries, and...
Brunner reaction | indole | Madelung reaction | Bischler–Möhlau reaction | carboline | pyrrole | Knorr reaction | Nenitzescu reaction | Chemistry | Pharmacy | Graebe–Ullmann reaction | carbazole | Hantzsch reaction | Organic Chemistry | Piloty–Robinson reaction | Piloty-Robinson reaction | Graebe-Ullmann reaction | Bischler-Möhlau reaction | MODIFIED MADELUNG REACTION | SOLID-PHASE SYNTHESIS | SUBSTITUTED PYRROLES | ALPHA-CARBOLINE | GAMMA-CARBOLINES | CHEMISTRY, ORGANIC | REAKTSII PROIZVODNYKH GIDRAZINA | SYNTHETIC UTILITY | INDOLE SYNTHESIS | Bischler-Mohlau reaction | Heterocyclic compounds | Thiophene
Brunner reaction | indole | Madelung reaction | Bischler–Möhlau reaction | carboline | pyrrole | Knorr reaction | Nenitzescu reaction | Chemistry | Pharmacy | Graebe–Ullmann reaction | carbazole | Hantzsch reaction | Organic Chemistry | Piloty–Robinson reaction | Piloty-Robinson reaction | Graebe-Ullmann reaction | Bischler-Möhlau reaction | MODIFIED MADELUNG REACTION | SOLID-PHASE SYNTHESIS | SUBSTITUTED PYRROLES | ALPHA-CARBOLINE | GAMMA-CARBOLINES | CHEMISTRY, ORGANIC | REAKTSII PROIZVODNYKH GIDRAZINA | SYNTHETIC UTILITY | INDOLE SYNTHESIS | Bischler-Mohlau reaction | Heterocyclic compounds | Thiophene
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 04/2009, Volume 131, Issue 12, pp. 4541 - 4550
Heterogeneous palladium catalysts, which are supported on ordered mesoporous silica−carbon nanocomposites, have been applied in water-mediated coupling...
NANOCOMPOSITE MATERIALS | SILICA COMPOSITE | ORGANIC-INORGANIC HYBRID | MEDIUM ULLMANN REACTION | TEMPLATING SYNTHESIS | TRANSFER HYDROGENATION | PD CATALYSTS | MOLECULAR-SIEVES | HECK REACTION | CHEMISTRY, MULTIDISCIPLINARY | PALLADIUM CATALYSTS | Chlorobenzene | Palladium catalysts | Analysis | Chemical properties | Phase transformations (Statistical physics) | Structure | Silica | Naturvetenskap | Natural Sciences
NANOCOMPOSITE MATERIALS | SILICA COMPOSITE | ORGANIC-INORGANIC HYBRID | MEDIUM ULLMANN REACTION | TEMPLATING SYNTHESIS | TRANSFER HYDROGENATION | PD CATALYSTS | MOLECULAR-SIEVES | HECK REACTION | CHEMISTRY, MULTIDISCIPLINARY | PALLADIUM CATALYSTS | Chlorobenzene | Palladium catalysts | Analysis | Chemical properties | Phase transformations (Statistical physics) | Structure | Silica | Naturvetenskap | Natural Sciences
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2017, Volume 56, Issue 42, pp. 12852 - 12856
Ullmann coupling of 4‐bromobiphenyl thermally catalyzed on Ag(111), Cu(111), and Cu(100) surfaces was scrutinized by scanning tunneling microscopy as well as...
self-assembly strategies | surface reaction dynamics | Ullmann coupling | scanning tunneling microscopy | GRAPHENE NANORIBBONS | MACROCYCLES | POLYMERIZATION | MECHANISMS | BOTTOM | INSIGHT | CHEMISTRY, MULTIDISCIPLINARY | MONOLAYERS | RADICALS | EFFICIENCY | Scanning tunneling microscopy | Self assembly | Silver | Self-assembly | Metal surfaces | Microscopy | Coupling | Copper | Dispersion | Intermediates
self-assembly strategies | surface reaction dynamics | Ullmann coupling | scanning tunneling microscopy | GRAPHENE NANORIBBONS | MACROCYCLES | POLYMERIZATION | MECHANISMS | BOTTOM | INSIGHT | CHEMISTRY, MULTIDISCIPLINARY | MONOLAYERS | RADICALS | EFFICIENCY | Scanning tunneling microscopy | Self assembly | Silver | Self-assembly | Metal surfaces | Microscopy | Coupling | Copper | Dispersion | Intermediates
Journal Article
Chemical Reviews, ISSN 0009-2665, 02/2009, Volume 109, Issue 2, pp. 711 - 724
SUPPORTED AQUEOUS-PHASE | ASYMMETRIC TRANSFER HYDROGENATION | LEWIS-ACID CATALYSTS | PERIODIC MESOPOROUS ORGANOSILICAS | MEDIUM ULLMANN REACTION | DIELS-ALDER REACTIONS | SILYL ENOL ETHERS | IONIC LIQUID | ALLYLIC SUBSTITUTION | CHEMISTRY, MULTIDISCIPLINARY | HOMOALLYLIC ALCOHOL ISOMERIZATION | Organic Chemicals - chemical synthesis | Fluorides - chemistry | Metals - chemistry | Silicon Dioxide - chemistry | Surface Properties | Organic Chemicals - chemistry | Water - chemistry | Catalysis | Ionic Liquids - chemistry | Palladium - chemistry | Phase Transition | Hydrophobic effect | Immobilized enzymes | Chemical properties | Silica | Analysis
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 03/2005, Volume 127, Issue 12, pp. 4120 - 4121
The mechanistic details of the Cu-catalyzed amidation of aryl iodides are presented. The kinetic data suggest that the diamine ligand prevents multiple...
ULLMANN CONDENSATION | HALIDES | ORGANIC REACTIONS | SUBSTITUTION | CRYSTAL-STRUCTURE | COMPLEXES | TRIARYLAMINES | N-ARYLATION | METAL-IONS | CHEMISTRY, MULTIDISCIPLINARY | Copper - chemistry | Amides - chemical synthesis | Iodobenzenes - chemistry | Chelating Agents - chemistry | Diamines - chemistry | Ligands | Catalysis | Kinetics | Copper compounds | Aromatic compounds | Chemical properties
ULLMANN CONDENSATION | HALIDES | ORGANIC REACTIONS | SUBSTITUTION | CRYSTAL-STRUCTURE | COMPLEXES | TRIARYLAMINES | N-ARYLATION | METAL-IONS | CHEMISTRY, MULTIDISCIPLINARY | Copper - chemistry | Amides - chemical synthesis | Iodobenzenes - chemistry | Chelating Agents - chemistry | Diamines - chemistry | Ligands | Catalysis | Kinetics | Copper compounds | Aromatic compounds | Chemical properties
Journal Article
Asian Journal of Organic Chemistry, ISSN 2193-5807, 10/2017, Volume 6, Issue 10, pp. 1492 - 1497
A nickel‐catalyzed cross‐coupling reaction between (functionalized) aryl chlorides and alcohols that results in C(sp2)−O bond formation is described. This...
cross-coupling | nickel | C−O bond formation | micelles | water | ROOM-TEMPERATURE | PALLADIUM | C-N | METATHESIS REACTIONS | CHEMISTRY, ORGANIC | C-O bond formation | COPPER | DIETHYL PHOSPHITE | PHENOLS | ARYL HALIDES | DIARYL ETHERS | ULLMANN
cross-coupling | nickel | C−O bond formation | micelles | water | ROOM-TEMPERATURE | PALLADIUM | C-N | METATHESIS REACTIONS | CHEMISTRY, ORGANIC | C-O bond formation | COPPER | DIETHYL PHOSPHITE | PHENOLS | ARYL HALIDES | DIARYL ETHERS | ULLMANN
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 01/2018, Volume 24, Issue 1, pp. 56 - 61
On‐surface reactions based on metal‐catalysed Ullmann coupling have been successfully employed to synthesise a wide variety of covalently coupled structures....
scanning probe microscopy | surface chemistry | heterogeneous catalysis | supramolecular chemistry | templated reactions | BUILDING-BLOCKS | NETWORKS | NANOSTRUCTURES | INSIGHT | CHEMISTRY, MULTIDISCIPLINARY | ULLMANN POLYMERIZATION | ORGANIZATION | CHEMISTRY | INTERMEDIATE | CHAINS | Heterogeneous catalysis | Coupling (molecular) | Vacuum | Scanning probe microscopy | Microscopy | Surface reactions | Topology | High vacuum | Substrates
scanning probe microscopy | surface chemistry | heterogeneous catalysis | supramolecular chemistry | templated reactions | BUILDING-BLOCKS | NETWORKS | NANOSTRUCTURES | INSIGHT | CHEMISTRY, MULTIDISCIPLINARY | ULLMANN POLYMERIZATION | ORGANIZATION | CHEMISTRY | INTERMEDIATE | CHAINS | Heterogeneous catalysis | Coupling (molecular) | Vacuum | Scanning probe microscopy | Microscopy | Surface reactions | Topology | High vacuum | Substrates
Journal Article