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chemistry, multidisciplinary (9) 9
chemistry, organic (9) 9
unactivated alkenes (7) 7
cross-coupling reactions (4) 4
nickel (4) 4
terminal alkenes (4) 4
activation (3) 3
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alkene (2) 2
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carbon (2) 2
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synthesis (2) 2
visible-light (2) 2
1,2-alkylarylation (1) 1
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absolute rate constants (1) 1
acetonitrile (1) 1
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Journal of the American Chemical Society, ISSN 0002-7863, 08/2018, Volume 140, Issue 31, pp. 9801 - 9805
We report a Ni-catalyzed regioselective alkylarylation of vinylarenes with alkyl halides and arylzinc reagents to generate 1,1-diarylalkanes. The reaction... 
ALKENYL CARBONYL-COMPOUNDS | ARYL GRIGNARD-REAGENTS | CROSS-COUPLING REACTIONS | TRANSIENT METALLACYCLES | ASYMMETRIC-SYNTHESIS | HECK REACTIONS | UNACTIVATED OLEFINS | CHEMISTRY, MULTIDISCIPLINARY | TERMINAL ALKENES | ALKYL-HALIDES | INTERMOLECULAR CYANOTRIFLUOROMETHYLATION
Journal Article
Journal of organometallic chemistry, ISSN 0022-328X, 11/2015, Volume 797, pp. 13 - 20
Reactions of KPPh2 with dimeric C,N, C,P and C,S cyclopalladated complexes (CPCs) 1a−g containing an (sp3)C–Pd bond were investigated... 
Phosphination | KPPh2 | N,P, S,P, P,P ligands | Cyclopalladated complex | (sp3)C–Pd bond | PALLADATION | PALLADIUM COMPLEXES | MOLECULAR-STRUCTURE | PLATINUM | CHEMISTRY, ORGANIC | CRYSTAL | UNACTIVATED METHYL-GROUPS | PHOSPHIDO COMPLEXES | CHEMISTRY, INORGANIC & NUCLEAR | P-31 NMR-SPECTROSCOPY | LIGANDS | (sp)C-Pd bond
Journal Article
ORGANIC LETTERS, ISSN 1523-7060, 01/2020, Volume 22, Issue 2, pp. 556 - 559
.... Reactions that increase the sp(3) character of molecules enable the pursuit of more selective and well-tolerated pharmaceuticals... 
HIGH-THROUGHPUT EXPERIMENTATION | ACTIVATION | METALLAPHOTOREDOX CATALYSIS | TAE226 | CHEMISTRY, ORGANIC | ARYL | FOCAL ADHESION KINASE | INHIBITOR | BROMIDES | UNACTIVATED ALKYL-HALIDES
Journal Article
Green chemistry : an international journal and green chemistry resource : GC, ISSN 1463-9270, 2019, Volume 21, Issue 2, pp. 269 - 274
...–radical coupling to construct C(sp 3 )–C(sp 3 ) and C(sp 3 )–O bonds. A convenient Fe-catalyzed decarbonylative alkylation... 
DIFUNCTIONALIZATION | KETONES | GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY | HYDROPEROXYARYLATION | DIOXYGEN | HECK-TYPE REACTION | ESTERS | CARBONYLATION-PEROXIDATION | CHEMISTRY, MULTIDISCIPLINARY | STYRENE DERIVATIVES | UNACTIVATED ALKENES | CONJUGATE ADDITION
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 05/2014, Volume 136, Issue 20, pp. 7253 - 7256
A novel Ni-catalyzed reductive amidation of C­(sp2)–O and C­(sp3)–O electrophiles with isocyanates is described... 
UNACTIVATED ALKYL BROMIDES | CROSS-COUPLING REACTIONS | ARYL HALIDES | OXIDATIVE AMIDATION | REACTIVITY | DIRECT CARBOXYLATION | ISOCYANATES | ALDEHYDES | ELECTROPHILES | CHEMISTRY, MULTIDISCIPLINARY | BENZYL HALIDES
Journal Article
ACS catalysis, ISSN 2155-5435, 07/2017, Volume 7, Issue 7, pp. 4697 - 4706
Transition metal-catalyzed cross-coupling reactions have created an epoch in modern synthetic organic chemistry, offering a variety of insights into... 
alkyl electrophiles | cross-coupling | catalysis | single-electron transfer | radicals | UNACTIVATED SECONDARY | NUCLEOPHILIC-SUBSTITUTION | SILICON | C-S | CHEMISTRY, PHYSICAL | PHOTOSENSITIZED DECARBOXYLATION | COPPER | CARBON BOND FORMATION | AMINATION | ORGANIC HALIDES | REDOX-ACTIVE ESTERS
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 09/2019, Volume 141, Issue 35, pp. 13812 - 13821
.... Simultaneous formation of one C­(sp3)–C­(sp3) and one C­(sp3)–C­(sp2) bond across a variety of unbiased π... 
HALIDES | DIFUNCTIONALIZATION | STYRENES | 1,2-ALKYLARYLATION | NICKEL | CARBONYL ALKYL BROMIDES | COUPLING REACTIONS | HYDROXYPHTHALIMIDE ESTERS | UNACTIVATED OLEFINS | CHEMISTRY, MULTIDISCIPLINARY | TERMINAL ALKENES
Journal Article
ORGANIC & BIOMOLECULAR CHEMISTRY, ISSN 1477-0520, 2014, Volume 12, Issue 28, pp. 5082 - 5088
An operationally simple and environmentally benign formal hydrogenation protocol has been developed using highly abundant iron (III) salts and an inexpensive,... 
AROMATIC NITRO-COMPOUNDS | NITROBENZENE | SODIUM-BOROHYDRIDE | NITROARENES | CHEMOSELECTIVE REDUCTION | LITHIUM ALUMINUM-HYDRIDE | CHEMISTRY, ORGANIC | SELECTIVE REDUCTION | ALKYNES | RADICAL-ANION | UNACTIVATED ALKENES
Journal Article
Chemical communications (Cambridge, England), ISSN 1364-548X, 2019, Volume 55, Issue 80, pp. 12080 - 12083
...! Abundant aliphatic aldehydes were readily decarbonylated into alkyl radicals for the cascade construction of C(sp 3 )–C(sp 3 ), C(sp 3 )–C(sp 3 ) and C(sp 3... 
KETONES | HYDROPEROXYARYLATION | CARBON | ESTERS | CATALYZED CARBONYLATION-PEROXIDATION | HYDROPEROXIDES | CHEMISTRY, MULTIDISCIPLINARY | STYRENE DERIVATIVES | UNACTIVATED ALKENES
Journal Article
Science (American Association for the Advancement of Science), ISSN 1095-9203, 2020, Volume 367, Issue 6481, pp. 1021 - 1026
Journal Article
Chemical communications (Cambridge, England), ISSN 1364-548X, 2016, Volume 52, Issue 74, pp. 11100 - 11103
...], bathophenanthroline, K 3 PO 4 , BnOH and ( BuO) 2 afforded 1,3-dihydroisobenzofurans (phthalanes) formation of one C(sp 3 )–C(sp 3 ) and one C(sp 3 )–O bonds. A concise synthesis... 
ACTIVATED ALKENES | HETEROCYCLES | ALLYLIC ALCOHOLS | NOREPINEPHRINE TRANSPORTER | CARBOETHERIFICATION | BOND FUNCTIONALIZATION | ALKYL NITRILES | ACETONITRILE | CYANOMETHYLATION | CHEMISTRY, MULTIDISCIPLINARY | UNACTIVATED ALKENES | Synthesis | Alkenes | Catalysts | Heating | Formations | Transformations | Catalysis | Hydrates
Journal Article
Synlett, ISSN 0936-5214, 08/2019, Volume 30, Issue 13, pp. 1496 - 1507
.... Herein, we highlight some recent strategies for activating challenging organic halides under light irradiation, with special emphasis in C(sp 3 )–halide bonds... 
synpacts | NICKEL(I) OCTAETHYLISOBACTERIOCHLORIN ANION | PART I | nonactivated alkyl chlorides | CHEMISTRY, ORGANIC | BOND FORMATION | visible-light | SINGLE-ELECTRON TRANSMETALATION | RADICAL GENERATION | cyclizations | UNACTIVATED ALKYL | ONE-STEP | vitamin B-12 | ARYL HALIDES | cobaloximes | photoredox catalysis | METAL-COMPLEXES
Journal Article
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, ISSN 1381-1169, 11/2012, Volume 363, pp. 322 - 327
...)-2,6-pyridinedicarboxamido, was examined for sp(3)-sp(3) coupling of Grignard reagents with polychlorinated solvents. The nickel(II... 
SITE | UNACTIVATED ARYL CHLORIDES | ACTIVATION | CHEMISTRY, PHYSICAL | Nickel(II) complex | Catalytic cross-coupling | Multiple C-C bond formation | NONACTIVATED ALKYL-HALIDES | Pincer ligand | LIGAND | CARBON-DIOXIDE | CATALYSTS | Polychlorinated solvents | CH2CL2
Journal Article
Tetrahedron letters, ISSN 0040-4039, 2019, Volume 60, Issue 16, pp. 1130 - 1134
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2020, Volume 142, Issue 1, pp. 214 - 221
Substantial advances in enantioconvergent C­(sp3)–C­(sp3) bond formation reactions have been made in recent years through the use of transition-metal-catalyzed... 
PALLADIUM | CROSS-COUPLING REACTIONS | PHOSPHONATES | REAGENTS | LIGANDS | AMINO-ACIDS | ARYLATION | HYDROCARBOFUNCTIONALIZATION | CHEMISTRY, MULTIDISCIPLINARY | UNACTIVATED ALKENES
Journal Article
Journal of fluorine chemistry, ISSN 0022-1139, 11/2014, Volume 167, pp. 30 - 36
....•Umemoto's and Togni's reagents.•C(sp3)CF3 bond formation. For the past few years, transition-metal-catalyzed trifluoromethylation of olefins has been rapidly developing... 
Transition metal catalyst | Trifluoromethylation | Electrophilic CF3 reagent | Step economy | Alkene difunctionlalization | Photocatalysis | reagent | Electrophilic CF | ASYMMETRIC FLUORINATION | PHOTOREDOX | CHEMISTRY, ORGANIC | BOND FORMATION | COPPER | UNACTIVATED ALKENES | CHEMISTRY, INORGANIC & NUCLEAR | 3-COMPONENT OXYTRIFLUOROMETHYLATION | HYDROTRIFLUOROMETHYLATION | CONSTRUCTION | EFFICIENT | TERMINAL ALKENES
Journal Article
Organic letters, ISSN 1523-7060, 01/2016, Volume 18, Issue 1, pp. 52 - 55
.... A chemoselective reaction at C­(sp3)–I in the presence of a C­(sp2)–X (X = Br or I) bond was attained, which allowed for the stepwise functionalization of two types of C... 
HALIDES | UNACTIVATED ALKYL | VISIBLE-LIGHT | CARBONYLATION | COUPLING REACTION | RADICAL CONJUGATE ADDITIONS | CHEMISTRY, ORGANIC | ELECTRON-DEFICIENT ALKENES | HECK REACTION | DERIVATIVES | ARYLBORONIC ACIDS
Journal Article
Tetrahedron, ISSN 0040-4020, 2019, Volume 75, Issue 33, pp. 4486 - 4496
...) complexes along with some feedstock is achieved in good yield under the mild conditions. This practically useful method of C(sp3)−C(sp3... 
Nickel | Synthesis | Neopentyl bromide | Reductive coupling | Radical | EPOXYNITRILE CYCLIZATION | ENANTIOSPECIFIC SYNTHESIS | NUCLEOPHILIC-SUBSTITUTION | KETONE FORMATION | CHEMISTRY, ORGANIC | BOND FORMATION | DISPLACEMENT-REACTIONS | UNACTIVATED ALKYL-HALIDES | ELECTRON-TRANSFER | ORGANIC HALIDES | CONJUGATE ADDITION | Aldehydes | Sesquiterpenes | Olefins
Journal Article
JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, ISSN 0037-9980, 12/2004, Volume 62, Issue 12, pp. 1192 - 1204
Cross-coupling reaction of organic halides with main group organometallic reagents has now become one of the most practical and reliable methods for constructing C-C bonds in organic synthesis... 
PALLADIUM | cross-coupling reaction | transition metal catalysts | CHEMISTRY, ORGANIC | Grignard reagents | organometallic reagents | BROMIDES | UNACTIVATED NEOPENTYL IODIDES | NEGISHI REACTIONS | BORONIC ACIDS | C-C bond formation | NICKEL | alkyl halides | SUZUKI REACTIONS | EFFICIENT | ELECTROPHILES | GRIGNARD-REAGENTS
Journal Article
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