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vinylarenes (274) 274
chemistry, organic (133) 133
alkenes (112) 112
chemistry, multidisciplinary (110) 110
complexes (74) 74
alkynes (68) 68
olefins (67) 67
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amination (49) 49
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efficient (17) 17
styrene (17) 17
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vinylarene (15) 15
anilines (14) 14
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pinacolborane (13) 13
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activation (12) 12
chemistry (12) 12
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boron (10) 10
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Chemical Communications, ISSN 1359-7345, 2006, Issue 28, pp. 2974 - 2976
The concept of immobilising organometallic complexes in a thin film of supported ionic liquids was utilised to synthesise novel bi-functional catalysts... 
CHEMISTRY, MULTIDISCIPLINARY | VINYLARENES
Journal Article
Organic Letters, ISSN 1523-7060, 06/2013, Volume 15, Issue 11, pp. 2680 - 2683
Bis(imino)pyridine iron dinitrogen complexes have been shown to promote the anti-Markovnikov catalytic hydroboration of terminal, internal, and geminal alkenes... 
1,1-DISUBSTITUTED ALKENES | RHODIUM | HYDROGENATION | LIGANDS | VINYLARENES | DEHYDROGENATIVE BORYLATION | COMPLEXES | HYDROSILYLATION | CHEMISTRY, ORGANIC | PINACOLBORANE | ASYMMETRIC HYDROBORATION
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 11/2014, Volume 136, Issue 44, pp. 15501 - 15504
We report the synthesis of cobalt complexes of novel iminopyridine–oxazoline (IPO) ligands and their application to the asymmetric hydroboration of... 
ORGANIC-SYNTHESIS | STYRENES | DIHYDROXYLATION | HYDROGENATION | SUBSTITUTED VINYLARENES | OLEFINS | PINACOLBORANE | RHODIUM COMPLEXES | ASYMMETRIC HYDROBORATION | CHEMISTRY, MULTIDISCIPLINARY | TERMINAL SELECTIVITY | Hydroboration | Chemical properties | Research | Metal catalysts | Olefins
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 03/2015, Volume 137, Issue 11, pp. 3775 - 3778
We report the first example of ipso-borylation for the modular 1,2-bisfunctionalization of aryl iodides via C–H functionalization. The carbon–boron bond is... 
HALIDES | PALLADIUM(II) COMPLEX | ACTIVATION | U-SHAPED TEMPLATE | NORBORNENE | OLEFINATION | HETEROCYCLES | VINYLARENES | TOSYLHYDRAZONE INSERTION REACTION | CHEMISTRY, MULTIDISCIPLINARY | Chemical bonds | Chemical properties | Research | Chemical synthesis | Aromatic compounds
Journal Article
Organic Letters, ISSN 1523-7060, 10/2016, Volume 18, Issue 20, pp. 5268 - 5271
A copper-mediated, three-component reaction between two different N-Ts hydrazones and elemental sulfur was developed, leading to a series of unsymmetric... 
ANTIDEPRESSANT | VINYLARENES | CHEMISTRY | CHEMISTRY, ORGANIC | CASCADE | TOSYLHYDRAZONE INSERTION REACTION | AGENTS | 1,3,4-OXADIAZOLES | THIADIAZOLES | DERIVATIVES | EFFICIENT
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2012, Volume 134, Issue 1, pp. 111 - 114
A general method for regioselective C3-benzylation of indoles has been developed. Various 3-substituted indoles and benzyl methyl carbonates with different... 
FUNCTIONALIZATION | SUBSTITUTION | ALKYLATION | VINYLARENES | ALLYLATION | BENZYLATION | OXINDOLES | HYDROAMINATION | 2,3-DISUBSTITUTED INDOLES | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
by Yu, RR and Fang, XJ
ORGANIC LETTERS, ISSN 1523-7060, 01/2020, Volume 22, Issue 2, pp. 594 - 597
A vast range of novel TADDOL-based diphosphite ligands were first synthesized and applied in the nickel-catalyzed asymmetric hydrocyanation of disubstituted... 
ALKENES | ASYMMETRIC HYDROCYANATION | VINYLARENES | COMPLEXES | CHEMISTRY, ORGANIC | 1,4-ADDITION | PHOSPHINE-PHOSPHITE LIGANDS | GRIGNARD-REAGENTS
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 05/2016, Volume 52, Issue 35, pp. 5916 - 5919
A new method has been developed for the Markovnikov hydroboration of alkyl-substituted terminal alkenes. Notably, the use of a bulky bisphosphine-copper(i)... 
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 02/2006, Volume 128, Issue 6, pp. 1798 - 1799
Ph3PAuOTf catalyzes efficient intra- and intermolecular hydroamination of unactivated olefins with sulfonamides. 
PALLADIUM | ALKENES | VINYLARENES | GOLD-CATALYZED CYCLOISOMERIZATION | COMPLEXES | HOMOGENEOUS CATALYSIS | ALKYNES | OXIDATIVE AMINATION | EFFICIENT | CHEMISTRY, MULTIDISCIPLINARY | ENYNES
Journal Article
Organic Letters, ISSN 1523-7060, 01/2018, Volume 20, Issue 1, pp. 248 - 251
The CuH-catalyzed asymmetric intramolecular reductive coupling of allenes to enones is successfully realized, providing cis-hydrobenzofurans with promising... 
FORMAL HYDROAMINATION | NUCLEOPHILES | ALKENES | HYDROSILANES | IMINES | VINYLARENES | ALLYLATION | CHEMISTRY, ORGANIC | TERMINAL ALKYNES | HYDROALLYLATION | HYDROALKYLATION
Journal Article
Accounts of Chemical Research, ISSN 0001-4842, 09/2016, Volume 49, Issue 9, pp. 1997 - 2006
Journal Article
Chemical Communications, ISSN 1359-7345, 2018, Volume 54, Issue 57, pp. 7979 - 7982
Hydroaminomethylation of olefins with H2O as the hydrogen source was accomplished over an Ir-catalyst with the involvement of an ionic diphosphine (L6). The... 
Journal Article
Organic Letters, ISSN 1523-7060, 06/2019, Volume 21, Issue 12, pp. 4480 - 4485
A visible-light-promoted metal-free alkylheteroarylation of unactivated olefins was developed by using readily available ketones/esters as the alkyl radical... 
FUNCTIONALIZATION | MIGRATION | ALKENES | KETONES | DIRECT ARYLATION | VINYLARENES | ALKYLATION | CHEMISTRY, ORGANIC | RADICALS | C-H BONDS | PHOTOREDOX CATALYSIS
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 10/2013, Volume 135, Issue 42, pp. 15746 - 15749
Journal Article
ACS Catalysis, ISSN 2155-5435, 01/2017, Volume 7, Issue 1, pp. 855 - 863
We report a regiodivergent hydrosilylation of alkenes catalyzed by catalysts generated in situ from bench-stable Co­(acac)2 and phosphine- or nitrogen-based... 
hydrosilylation | regiodivergent | cobalt | vinylarenes | homogeneous catalysis | aliphatic alkenes | SILICON BOND | MECHANISM | CHEMISTRY, PHYSICAL | OLEFIN HYDROSILYLATION | IRON CATALYSTS | HYDROSILATION REACTION | MARKOVNIKOV | PLATINUM-CARBENE COMPLEXES | DEHYDROGENATIVE SILYLATION | EFFICIENT | TERTIARY SILANES
Journal Article
ORGANIC LETTERS, ISSN 1523-7060, 01/2020, Volume 22, Issue 2, pp. 376 - 380
The first catalytic enantioselective hydrocyanation of allenes catalyzed by a (R,R)-Ph-BPE-Ni(0) complex catalyst has been accomplished. Numerous optically... 
ALKENES | AXIAL CHIRALITY | VINYLARENES | STEREOSELECTIVE HYDROCYANATION | CHEMISTRY, ORGANIC | HYDROGEN-CYANIDE | OLEFINS | CYANATION | INHIBITOR | PHOSPHINE-PHOSPHITE LIGANDS | MARKOVNIKOV
Journal Article
Organic Letters, ISSN 1523-7060, 09/2006, Volume 8, Issue 19, pp. 4179 - 4182
Intermolecular additions of the O−H bonds of phenols and alcohols and the N−H bonds of sulfonamides and benzamide to olefins catalyzed by 1 mol % of triflic... 
1,3-DIENES | INTERMOLECULAR HYDROAMINATION | VINYLARENES | ANILINES | ADDITION-REACTIONS | INTRAMOLECULAR HYDROAMINATION | CHEMISTRY, ORGANIC | ANTI-MARKOVNIKOV HYDROAMINATION | OLEFINS | ALKYLAMINES | CARBOXYLIC-ACIDS | Catalysis | Mesylates - chemistry | Amination | Metals - chemistry | Alkanes - chemistry
Journal Article
Organic Letters, ISSN 1523-7060, 09/2006, Volume 8, Issue 19, pp. 4175 - 4178
Intermolecular addition of phenols, carboxylic acids, and protected amines to inert olefins can be catalyzed by low concentrations (1−5%) of triflic acid.... 
OXYGEN | ALKENES | AMINATION | INTERMOLECULAR HYDROAMINATION | VINYLARENES | INTRAMOLECULAR HYDROAMINATION | NITROGEN | CHEMISTRY, ORGANIC | ANTI-MARKOVNIKOV HYDROAMINATION | ELECTRON-RICH ARENES | CYCLIZATION
Journal Article
Chemical Communications, ISSN 1359-7345, 05/2016, Volume 52, Issue 35, pp. 5916 - 5919
A new method has been developed for the Markovnikov hydroboration of alkyl-substituted terminal alkenes. Notably, the use of a bulky bisphosphine-copper(I)... 
TERTIARY BORONIC ESTERS | REGIOSELECTIVE HYDROBORATION | VINYL ARENES | VINYLARENES | SECONDARY | REGIO | FLUORINATION | RHODIUM COMPLEXES | MONOBORYLATION | ASYMMETRIC HYDROBORATION | CHEMISTRY, MULTIDISCIPLINARY | Hydroboration | Terminals | Alkenes | Catalysts | Compatibility | Functional groups
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2014, Volume 53, Issue 10, pp. 2696 - 2700
An extremely efficient cobalt catalyst for the hydroboration of both vinylarenes and aliphatic α‐olefins with pinacolborane is described, providing the... 
cobalt | hydroboration | alkenes | cross‐coupling | synthetic methods | cross-coupling | REGIOSELECTIVE HYDROBORATION | HYDROGENATION | H BOND | VINYL ARENES | VINYLARENES | CATECHOLBORANE | RHODIUM COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY | ALKYL-HALIDES | FUNCTIONALIZATION | CROSS-COUPLING REACTIONS | Cobalt | Olefins | Hydroboration | Catalysts | Chlorides | Displays | Tolerances | Aliphatic compounds
Journal Article
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