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Advanced Synthesis & Catalysis, ISSN 1615-4150, 05/2014, Volume 356, Issue 7, pp. 1461 - 1479
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2017, Volume 139, Issue 2, pp. 888 - 896
Pd-catalyzed C–H functionalizations promoted by transient directing groups remain largely limited to C–H arylation only. Herein, we report a diverse set of... 
DECARBONYLATION | CATALYSIS | AMINATION | C-H AMIDATION | ARYL HALIDES | BOND ACTIVATION | ALDEHYDES | HALOGENATION | WEAK COORDINATION | CHEMISTRY, MULTIDISCIPLINARY | HYDROACYLATION | Chemical reactions | Usage | Chemical properties | Organic compounds
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 01/2017, Volume 82, Issue 2, pp. 1114 - 1126
A palladium-catalyzed, ortho-selective C–H halogenation methodology is reported herein. The highlight of the work is the highly selective C­(sp2)–H... 
FUNCTIONALIZATION | ACTIVATION | ORTHO-BROMINATION | VERSATILE | REGIOSELECTIVE HALOGENATION | ARYLATION | CHEMISTRY, ORGANIC | BOND FORMATION | IODINATION | WEAK COORDINATION | CHLORINATION | Usage | Palladium | Chemical properties | Chemical synthesis | Halogenation
Journal Article
Organic Letters, ISSN 1523-7060, 10/2016, Volume 18, Issue 20, pp. 5432 - 5435
Ruthenium ligated to tricyclohexylphosphine or di-tert-butylbipyridine catalyzes the arylation of carboxylic acids with diverse aryl halides (iodide, bromide,... 
FUNCTIONALIZATION | TRACELESS DIRECTING GROUPS | AROMATIC KETONES | NATURAL-PRODUCTS | STRATEGY | CHEMISTRY, ORGANIC | BOND ACTIVATION | LIGAND | WEAK COORDINATION | BENZOIC-ACIDS | BIARYLS | Molecular Structure | Catalysis | Ruthenium - chemistry | Carboxylic Acids - chemical synthesis | Hydrocarbons, Halogenated - chemistry | Pyridines - chemical synthesis | Letter
Journal Article
Chemical science (Cambridge), ISSN 2041-6539, 2017, Volume 8, Issue 4, pp. 3204 - 3210
The ruthenium( )-catalyzed oxidative cross-coupling of C(sp 2 )–H bonds with organosilanes has been accomplished for the first time. The ruthenium( )-catalyzed... 
BORONIC ACIDS | C-H ARYLATION | CROSS-COUPLING REACTION | ALPHA-FUNCTIONALIZATION | BOND ACTIVATION | REGIOSELECTIVE ARYLATION | WEAK COORDINATION | CHEMISTRY, MULTIDISCIPLINARY | ORTHO-METALATION | CATALYZED DIRECT ARYLATION | BENZOIC-ACIDS | Silanes | Cross coupling | Halides | Metalorganic compounds | Reagents | Biocompatibility | Coupling | Benzamide
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2013, Volume 52, Issue 4, pp. 1245 - 1247
Journal Article
Green chemistry : an international journal and green chemistry resource : GC, ISSN 1463-9270, 2016, Volume 18, Issue 20, pp. 5635 - 5642
In this report synthesis of isoquinolinones, isocoumarins, and -methyl isoquinolinones and olefination of Weinreb amides by C–H bond activation using Ru(... 
GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY | CROSS-COUPLING REACTIONS | ONE-POT SYNTHESIS | INTERNAL OXIDANT | WEINREB AMIDES | TERMINAL ALKYNES | IONIC LIQUID | WEAK COORDINATION | ISOQUINOLONE SYNTHESIS | ORTHO-ACYLATION | CHEMISTRY, MULTIDISCIPLINARY | BENZOIC-ACIDS | Economics | Ruthenium | Catalysts | Media | Cleavage | Activation | Catalysis | Bonding
Journal Article
ACS Catalysis, ISSN 2155-5435, 02/2016, Volume 6, Issue 2, pp. 709 - 713
Organic molecules containing imidazolium and pyridine backbone are of special interest in many branches of chemistry, and therefore, overcoming the scarcity of... 
N-heterocyclic carbene | rhodium(III) | pyridine | alkyne | rollover C-H activation | CATALYSIS | RHODIUM | ANNULATION | COMPLEXES | BOND FUNCTIONALIZATION | CHEMISTRY, PHYSICAL | METAL-ORGANIC FRAMEWORK | N-HETEROCYCLIC CARBENES | WEAK COORDINATION | CYCLOMETALATION | OXIDANT
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 11/2018, Volume 24, Issue 62, pp. 16548 - 16552
Ruthenium(IV) complexes were identified as key intermediates of C−H/O−H activations by weak O‐coordination. Thus, the annulations of sulfoxonium ylides by... 
ylides | sulfoxonium ylide | C−H activation | mechanism | weak coordination | ruthenium(IV) | ACIDS | ALKYLATION | SULFOXONIUM YLIDES | DIRECT ARYLATIONS | CHEMISTRY, MULTIDISCIPLINARY | FUNCTIONALIZATION | C-H activation | AROMATIC AMIDES | BIDENTATE | GAMMA-LACTAMS | CHLORIDES | BOND ACTIVATION | Benzoic acid | Substitution reactions | Ruthenium | Catalysis
Journal Article
Advanced synthesis & catalysis, ISSN 1615-4150, 2016, Volume 358, Issue 14, pp. 2352 - 2358
The 8‐aminoquinoline‐directed, nickel(II)‐mediated ortho‐iodination of benzamides using molecular iodine has been developed. The process is highly... 
regioselectivity | nickel | CH activation | halogenation | ALKYLATION | CHEMISTRY, ORGANIC | IODINATION | DIRECTING-GROUP | WEAK COORDINATION | ACID-DERIVATIVES | ORTHO-HALOGENATION | C-H activation | CROSS-COUPLINGS | AROMATIC AMIDES | BONDS | PALLADIUM-CATALYZED ARYLATION | CHEMISTRY, APPLIED | Synthesis | Catalysis | Aromatic compounds | Benzamide | Functional groups | Iodine
Journal Article
Angewandte Chemie (International ed. in English), ISSN 1433-7851, 1/2013, Volume 52, Issue 4, pp. 1245 - 1247
Weak coordination is powerful! A Pd II -catalyzed olefination of ortho -C–H bonds of arenes directed by weakly coordinating ethers is developed using... 
palladium | C–H activation | ether | weak coordination | olefination
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2016, Volume 55, Issue 18, pp. 5555 - 5559
A general catalyzed direct C−H functionalization of s‐tetrazines is reported. Under mild reaction conditions, N‐directed ortho‐C−H activation of tetrazines... 
palladium | halogenation | C−H activation | heterocycles | fluorine | C-H activation | CELLS | WEAK-COORDINATION | IMAGING PROBES | 1,2,4,5-TETRAZINES | CHEMISTRY, MULTIDISCIPLINARY | S-TETRAZINES | MOLECULES | BOND FLUORINATION | FLUORESCENCE | CYCLOADDITIONS | CHEMISTRY | Palladium | Fluorides | Chemical bonds | Chemical Sciences
Journal Article
RSC Advances, ISSN 2046-2069, 2017, Volume 7, Issue 74, pp. 46636 - 46643
We have developed a protocol for the auxillary directed C-H chlorination of phenol derivatives using catalytic amounts of palladium acetate that is amenable to... 
FUNCTIONALIZATION | REMOVABLE DIRECTING GROUPS | HETEROARENES | ACTIVATION | ARENES | ARYLATION | 2-ARYLOXYPYRIDINES | BONDS | CATALYZED ORTHO-HALOGENATION | WEAK COORDINATION | CHEMISTRY, MULTIDISCIPLINARY
Journal Article