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chemistry, multidisciplinary (6) 6
insertion (6) 6
catalysis (5) 5
chemistry (5) 5
chemistry, inorganic & nuclear (5) 5
chemistry, organic (5) 5
x = h (4) 4
x-h insertion (4) 4
carbene (3) 3
carbenoids (3) 3
cyclopropanation (3) 3
diazo-compounds (3) 3
highly enantioselective insertion (3) 3
hydrogen-bonds (3) 3
x-h (3) 3
access (2) 2
c-h insertion (2) 2
catalysts (2) 2
chemistry, physical (2) 2
closed-shell attraction (2) 2
cross-coupling reactions (2) 2
deficient alkenes (2) 2
density-functional theory (2) 2
derivatives (2) 2
gaussian-basis sets (2) 2
iridium (2) 2
n-h insertion (2) 2
n-heterocyclic carbenes (2) 2
n-tosylhydrazones (2) 2
organic chemistry (2) 2
organic-synthesis (2) 2
oxidative addition (2) 2
physical chemistry (2) 2
reagents (2) 2
route (2) 2
sulfonylhydrazones (2) 2
thermodynamics (2) 2
transition-metal complexes (2) 2
x-h x (2) 2
ylides (2) 2
2-diazo-3-oxo-5,10,15,20-tetraphenylchlorins (1) 1
ab-initio (1) 1
abinitio mo (1) 1
adult (1) 1
alkaloids (1) 1
alkene complexes (1) 1
alkene insertion (1) 1
alkylzinc compounds (1) 1
allyl complexes (1) 1
allylglycine (1) 1
alpha-diazocarbonyl compounds (1) 1
alpha-diazocarbonyls (1) 1
asymmetrische katalyse (1) 1
asymmetry (1) 1
beta-keto-esters (1) 1
biochemistry & molecular biology (1) 1
biologically important ligands (1) 1
biomimetics (1) 1
bis-diazo compounds (1) 1
bisrhodium poly (1) 1
bond insertion (1) 1
c-c bonds (1) 1
c-c bonds activation (1) 1
c-c coupling (1) 1
c-h (1) 1
c-h activation (1) 1
c-h bonds (1) 1
calix arene ligands (1) 1
carbene complexes (1) 1
carbenes (1) 1
carbon aerogel (1) 1
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carbonyls (1) 1
catalytic-activity (1) 1
catalyzed cycloisomerization reactions (1) 1
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center-dot-o (1) 1
chemical bonds (1) 1
chemical reactions (1) 1
chemical synthesis (1) 1
chemistry, physical and theoretical (1) 1
chemists (1) 1
chiral iridium complex (1) 1
chlorides (1) 1
co-based metalloradical catalysis (1) 1
complexes (1) 1
computational modeling (1) 1
containing carbonyl ylides (1) 1
coordinatively unsaturated rhcl2 (1) 1
copper (1) 1
coupling reaction (1) 1
crystal-structures (1) 1
cyclization (1) 1
cyclopropane (1) 1
cyclopropanes (1) 1
cyclopropenation (1) 1
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Angewandte Chemie, ISSN 0044-8249, 03/2016, Volume 128, Issue 11, pp. 3849 - 3853
Copper‐catalyzed Si−H, B−H, P−H, S−H, and N−H insertion reactions of 2,2,2‐trifluoro‐1‐diazoethane and 1‐aryl 2,2,2‐trifluorodiazoethanes generated a large... 
Carbene | Asymmetrische Katalyse | Kupferkatalyse | X-H-Bindungsinsertion | Diazoverbindungen | Copper | Hydrogen | Insertion | Chemical bonds | Chemical reactions | Catalysis | Asymmetry | Chemists
Journal Article
Current Organic Chemistry, ISSN 1385-2728, 01/2016, Volume 20, Issue 1, pp. 102 - 118
Recently, non-diazo carbene precursors have attracted more and more interest because of the apparent safety reason. As one of the most reliable and useful... 
Cyclopropanation | X-H insertion | Carbene | Enynal | C-H insertion | Enynone | ALPHA-DIAZOCARBONYL COMPOUNDS | PROPARGYLIC ESTERS | GOLD CATALYSIS | H BOND | CHEMISTRY, ORGANIC | enynal | N-HETEROCYCLIC CARBENES | enynone | CATALYZED CYCLOISOMERIZATION REACTIONS | (2-FURYL)CARBENE COMPLEXES | cyclopropanation | CONTAINING CARBONYL YLIDES | ENE-YNE-KETONES | REGIOSELECTIVE SYNTHESIS
Journal Article
Dalton transactions (Cambridge, England : 2003), ISSN 1477-9226, 06/2016, Volume 45, Issue 25, pp. 10194 - 10199
Agostic interactions are often used to activate inert C-H bonds, and thus facilitate new reactions. We report the first example of designed catalysts based on... 
Journal Article
Research on Chemical Intermediates, ISSN 0922-6168, 11/2017, Volume 43, Issue 11, pp. 6447 - 6504
Journal Article
Chemical Communications, ISSN 1359-7345, 11/2018, Volume 54, Issue 94, pp. 13256 - 13259
The modular synthesis of a variety of trans 1,2-disubstituted cyclopropanes in a safe and user-friendly one-pot iron-catalyzed cyclopropanation reaction is... 
Journal Article
Synthesis, ISSN 0039-7881, 07/2016, Volume 48, Issue 14, pp. 2213 - 2225
Abstract Rhodium(II) acetate catalyzed domino reactions of bis-diazo compounds afford epoxy- and epithio-bridged heterocycle-fused quinolizinone systems in a... 
paper | X-H insertion | rhodium(II) acetate | diastereoselectivity | domino reactions | isomünchnones | bis-diazo compounds | ORGANIC-SYNTHESIS | CARBENOIDS | DECOMPOSITION | INDOLIZIDINE | CHEMISTRY, ORGANIC | H INSERTION REACTIONS | isomunchnones | DIMETHYL DIAZOMALONATE | DIAZOCARBONYL | YLIDE | CYCLIZATION | ALKALOIDS
Journal Article
Synthesis, ISSN 0039-7881, 07/2018, Volume 50, Issue 14, pp. 2678 - 2692
Abstract Carbenes and NHCs play an important role in porphyrin chemistry and several synthetically useful transformations leading to the preparation of new... 
short review | NHC | X-H insertion | porphyrin | cyclopropanation | carbene | OXIDATION | DIAZOACETATES | MACROCYCLES | REACTIVITY | CHEMISTRY, ORGANIC | N-HETEROCYCLIC CARBENES | GOLD(I) COMPLEXES | LIGANDS | CATALYTIC-ACTIVITY | CYTOCHROME-P-450 | 2-DIAZO-3-OXO-5,10,15,20-TETRAPHENYLCHLORINS
Journal Article
Dalton Transactions, ISSN 1477-9226, 2016, Volume 45, Issue 25, pp. 10194 - 10199
Agostic interactions are often used to activate inert C-H bonds, and thus facilitate new reactions. We report the first example of designed catalysts based on... 
X-H | CARBENOIDS | HIGHLY ENANTIOSELECTIVE INSERTION | CHEMISTRY | DIAZO-COMPOUNDS | CLOSED-SHELL ATTRACTION | N-H INSERTION | DENSITY-FUNCTIONAL THEORY | DERIVATIVES | HYDROGEN-BONDS | CHEMISTRY, INORGANIC & NUCLEAR | Solvents | Catalysts | Switches | Insertion | Inert | Steric effects | Catalysis | Pyrazole
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 05/2014, Volume 757, pp. 51 - 56
The reaction between the electron-rich iridium(I) complex, [Ir(COD)(PMe3)3]Cl, and the amino acid, 2-aminopent-4-enoic acid leads to the direct formation of a... 
Metal–carbon bonding | Alkene insertion | Iridium | Extended lattice motif | Tridentate coordination | Hydrogen bonding | Metal-carbon bonding | BIOLOGICALLY IMPORTANT LIGANDS | CENTER-DOT-O | CHEMISTRY, ORGANIC | CRYSTAL-STRUCTURES | HYDROGEN-BONDS | CHEMISTRY, INORGANIC & NUCLEAR | PI-INTERACTIONS | X-H | IRIDIUM COMPLEXES | PROTEINS | METAL-COMPLEXES | ALLYLGLYCINE
Journal Article
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 12/2018, Volume 54, Issue 94, pp. 13256 - 13259
The modular synthesis of a variety of trans 1,2-disubstituted cyclopropanes in a safe and user-friendly one-pot iron-catalyzed cyclopropanation reaction is... 
ROUTE | CROSS-COUPLING REACTIONS | INSERTION | REAGENTS | X-H X | SULFONYLHYDRAZONES | YLIDES | DEFICIENT ALKENES | CHEMISTRY, MULTIDISCIPLINARY | ACCESS | N-TOSYLHYDRAZONES
Journal Article
Chemical Communications, ISSN 1359-7345, 02/2002, Volume 2, Issue 4, pp. 338 - 339
A novel dirhodium tetracarboxylate complex is described in which two calix[4]arene macrocycles, bridged at the upper rim by a Rh-Rh unit, serve as ligands and... 
INSERTION | CALIX ARENE LIGANDS | CAVITY | AB-INITIO | CHEMISTRY | X = H | UPPER-RIM | RHODIUM(II) | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS
Journal Article
The Journal of Physical Chemistry A, ISSN 1089-5639, 03/2002, Volume 106, Issue 11, pp. 2614 - 2616
Substituent effects on the potential energy surfaces of X2GeSe (X = H, F, Cl, Br, and CH3) were investigated by density functional theory and CCSD(T) methods.... 
HEAVY KETONES | GERMYLENE INSERTION | GERMANIUM | MOLECULAR-ORBITAL METHODS | DOUBLE-BONDS | STABILITIES | CHEMISTRY, PHYSICAL | X = H | MAIN-GROUP ELEMENTS | GAUSSIAN-BASIS SETS | Thermodynamics | Usage | Halogens | Density functionals | Physiological aspects | Germanium | Research | Selenium | Chemistry, Physical and theoretical
Journal Article
CHEMISTRY-A EUROPEAN JOURNAL, ISSN 0947-6539, 06/1997, Volume 3, Issue 6, pp. 860 - 873
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 07/1995, Volume 34, Issue 14, pp. 3829 - 3832
A qualitative model which is based on the theory of Press and Shaik is; presented in this work. It was found that a knowledge of the ground spin state and the... 
TRANSITION-METAL COMPLEXES | HOMOGENEOUS OLEFIN POLYMERIZATION | SILYLENE INSERTION REACTIONS | ORGANOMETALLIC REACTION-MECHANISMS | COORDINATIVELY UNSATURATED RHCL(PH3)2 | C-C BONDS | X = H | OXIDATIVE ADDITION | ABINITIO MO | THERMAL-DECOMPOSITION | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 2010, Volume 695, Issue 2, pp. 280 - 290
Journal Article
Hinyokika kiyo. Acta urologica Japonica, ISSN 0018-1994, 05/1986, Volume 32, Issue 5, p. 769
A 23-year-old man was admitted to Osaka University Hospital with complaints of breast enlargement and defect of bilateral scrotal content. A gonad-like organ... 
H-Y Antigen - analysis | Disorders of Sex Development - pathology | Genitalia - pathology | Humans | X Chromosome | Adult | Female | Disorders of Sex Development - genetics
Journal Article
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