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2011, Structure and bonding, ISBN 3642211496, Volume 139., xi, 164
Book
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2014, Volume 53, Issue 13, pp. 3422 - 3426
Experimentally, AZn2Sb2 samples (A=Ca, Sr, Eu, Yb) are found to have large charge carrier concentrations that increase with increasing electronegativity of A.... 
defect formation | electronic transport | phase stability | Zintl phases | THERMOELECTRIC-MATERIALS | CAAL2SI2 | ELECTRONEGATIVITY | COMPOUND | CHEMISTRY | EFFICIENCY | CHEMISTRY, MULTIDISCIPLINARY | Specific gravity
Journal Article
Proceedings of the National Academy of Sciences of the United States of America, ISSN 0027-8424, 7/2016, Volume 113, Issue 29, pp. E4125 - E4132
Complex Zintl phases, especially antimony (Sb)-based YbZn Cd Sb₂ with figure-of-merit ( ) of ∼1.2 at 700 K, are good candidates as thermoelectric materials... 
Bi-based zintl phases | Band engineering | Strain-field fluctuation | Thermoelectric properties | Physical Sciences | band engineering | PNAS Plus | strain-field fluctuation | thermoelectric properties | Bi-based Zintl phases
Journal Article
Dalton Transactions, ISSN 1477-9226, 09/2014, Volume 43, Issue 40, pp. 14959 - 14970
A reinvestigation of the lithium-rich section of the Li-Ge phase diagram reveals the existence of two new phases, Li17Ge4 and Li4.10Ge (Li16.38Ge4). Their... 
ZINTL PHASE | CAPACITY | GERMANIUM | ALLOYS | LI12SI7 | SOLID-STATE AMORPHIZATION | X-RAY | ELECTRODES | SILICIDES | ANODES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
2011, Structure and bonding, ISBN 3642211496, Volume 139
Web Resource
1996, The chemistry of metal clusters., ISBN 1560819006, xxx, 306
Book
2011, Structure and bonding, ISBN 3642211496, Volume 139.
Web Resource
European Journal of Inorganic Chemistry, ISSN 1434-1948, 06/2016, Volume 2016, Issue 18, pp. 2912 - 2922
Eight new compounds with a general formula Ca14–xRExMnSb11 (RE = La–Nd, Sm, Gd–Dy; x ≈ 1) were synthesized by the molten flux method and their structures were... 
Thermoelectrics | Lanthanides | Structure elucidation | Antimonides | Zintl phases | SEMICONDUCTOR | THERMOELECTRIC PROPERTIES | CHEMISTRY, INORGANIC & NUCLEAR | TRANSITION | YB14MN1-XALXSB11 | MAGNETIC-PROPERTIES | YB14MNSB11 | COLOSSAL MAGNETORESISTANCE | Structure | Crystals | Rare earth metals | Phases | Doping | Cations | Atomic structure | Order disorder | Physical properties | Crystal structure
Journal Article
Advanced Functional Materials, ISSN 1616-301X, 11/2005, Volume 15, Issue 11, pp. 1860 - 1864
Zintl phases are ideal candidates for efficient thermoelectric materials, because they are typically small‐bandgap semiconductors with complex structures.... 
Semiconductors | Thermoelectric materials | Zintl phases | PHYSICS, CONDENSED MATTER | PHYSICS, APPLIED | SEMICONDUCTOR | MATERIALS SCIENCE, MULTIDISCIPLINARY | CLATHRATE COMPOUND | CHEMISTRY, PHYSICAL | ZN4SB3 | Material chemistry | Chemical Sciences
Journal Article
by Shuai, J and Geng, HY and Lan, YC and Zhu, Z and Wang, C and Liu, ZH and Bao, JM and Chu, CW and Sui, JH and Ren, ZF
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, ISSN 0027-8424, 07/2016, Volume 113, Issue 29, pp. E4125 - E4132
Complex Zintl phases, especially antimony (Sb)-based YbZn0.4Cd1.6Sb2 with figure-of-merit (ZT) of similar to 1.2 at 700 K, are good candidates as... 
TRANSPORT-PROPERTIES | thermoelectric properties | MULTIDISCIPLINARY SCIENCES | Bi-based Zintl phases | POWER | band engineering | strain-field fluctuation | EFFICIENCY | LATTICE THERMAL-CONDUCTIVITY
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 11/2013, Volume 2013, Issue 32, pp. 5541 - 5546
The quaternary phases NaRb7(Si4–xGex)2 (x = 1–3) crystallize with an NaRb7Ge8‐type structure and contain tetrahedral four‐atom clusters that consist of Si and... 
Germanium | Silicon | Heteroatomic Zintl anions | Solid‐state NMR spectroscopy | Cluster compounds | Zintl phases | Solid-state NMR spectroscopy | Ammonia | Nuclear magnetic resonance--NMR
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2017, Volume 56, Issue 40, pp. 12344 - 12347
The hydrogenation of Zintl phases enables the formation of new structural entities with main‐group‐element–hydrogen bonds in the solid state. The hydrogenation... 
metal hydrides | neutron diffraction | hydrogen | electron diffraction | Zintl phase | CRYSTAL-STRUCTURE | CHEMISTRY, MULTIDISCIPLINARY | Structure | Hydrogen | Hydrogenation | Hydrogen bonding | Crystals | Hydrogen storage | Electron diffraction | Chains | Hydrides | Solid state | Polyanions | Hydrogen bonds | Germanium | Hydrogen atoms | Hydrogen ion concentration | Crystal structure
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2016, Volume 55, Issue 3, pp. 1075 - 1079
The novel ternary Zintl phase Li3NaGe2 comprises alkali‐metal cations and [Ge2]4− dumbbells. The diatomic [Ge2]4− unit is characterized by the shortest Ge−Ge... 
double bonds | lithium | sodium | germanium dumbbells | Zintl phases | Dumbbells | Chemical properties | Oxygen | Orbitals | Nuclear magnetic resonance--NMR | Molecular structure | Phase shift | Alkali metals | Ternary systems | Metals | Crystallography | Electronic structure | Equivalence | Fermi level | Mathematical analysis | Chemical bonds | Germanium | Cations | Bonding
Journal Article
Journal of Solid State Chemistry, ISSN 0022-4596, 06/2016, Volume 238, Issue C, pp. 303 - 310
Crystals of two new Zintl compounds, Eu Mn Sb and Eu Cd Sb have been synthesized using the molten metal flux method, and their structures have been established... 
Antimony | Europium | Single-crystal X-ray diffraction | Crystal structure | Zintl phases | PHYSICAL-PROPERTIES | CRYSTAL-STRUCTURE | CHEMISTRY, PHYSICAL | CHEMISTRY, INORGANIC & NUCLEAR | RARE-EARTH | TRANSITION-METAL | MAGNETIC-PROPERTIES | POLAR INTERMETALLIC COMPOUNDS
Journal Article
MATERIALS, ISSN 1996-1944, 08/2019, Volume 12, Issue 16, p. 2554
Zintl phases have garnered a great deal of attention for many applications. The term Zintl phase recognizes the contributions of the German chemist Eduard... 
intermetallics | Zintl | thermoelectrics | energy storage | MATERIALS SCIENCE, MULTIDISCIPLINARY | energy conversion | photovoltaics | structure-property relationships | structure–property relationships
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2016, Volume 55, Issue 10, pp. 3264 - 3266
Ge−Ge double bonds: The reaction of elemental lithium, sodium, and germanium at 750 °C results in the Zintl phase Li3NaGe2, which, according to the Zintl–Klemm... 
double bonds | germanides | zintl phases | solid-state chemistry | alkali metals | Sodium | Lithium | Germanium
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 01/2016, Volume 2016, Issue 1, pp. 169 - 176
Single crystals of a new ternary phase, Ca7Ag2+xGe7–x [x = 0.48(3)], were obtained from as side‐product of high‐temperature solid‐state reactions, and its... 
Germanium | Electronic structure | Intermetallic compounds | Coloring problem | Zintl phases | CRYSTAL-STRUCTURE | CHEMISTRY, INORGANIC & NUCLEAR | DENSITY | SOLIDS | METAL | CLUSTER | LITHIUM | ELECTRONIC-STRUCTURE | Crystal structure | Naturvetenskap | Kemi | Oorganisk kemi | Natural Sciences | Inorganic Chemistry | Chemical Sciences
Journal Article
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