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Angewandte Chemie International Edition, ISSN 1433-7851, 07/2016, Volume 55, Issue 31, pp. 9084 - 9087
Herein, we report the palladium‐catalyzed direct arylation of unactivated aliphatic C−H bonds in free primary amines. This method takes advantage of an exo... 
palladium catalysis | C−H activation | directing groups | primary amines | arylation | ROOM-TEMPERATURE | C(SP)-H BONDS | PALLADIUM | NITROGEN-HETEROCYCLES | UNACTIVATED C(SP)-H | CARBON-HYDROGEN BONDS | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | FUNCTIONALIZED MOLECULES | C-H activation | ALIPHATIC-AMINES | ETHER SYNTHESIS | Aniline | Palladium | Catalysis
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2019, Volume 58, Issue 12, pp. 4002 - 4006
The synthetic utility of tertiary amines to oxidatively generate α‐amino radicals is well established, however, primary amines remain challenging because of... 
amines | reaction mechanisms | radicals | photochemistry | synthetic methods | ACIDS | ALPHA-AMINOALKYL RADICALS | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | ATOM | FUNCTIONALIZATION | ABSTRACTION | ADDITION-REACTIONS | ARENECARBONITRILES | ALIPHATIC-AMINES | PHOTOCHEMICAL-REACTIONS | Side reactions | Divergence | Amines | Alkenes | Sulfonamides | Selectivity | Catalysis | Derivatives | Amino radical | Alkylation | Intermediates
Journal Article
Journal of Physical Chemistry C, ISSN 1932-7447, 12/2014, Volume 118, Issue 50, pp. 29431 - 29440
Aerosol particles are ubiquitous in the atmosphere and have been shown to impact the Earths climate, reduce visibility, and adversely affect human health.... 
SECONDARY ORGANIC AEROSOL | DIMETHYL SULFIDE | BINARY NUCLEATION | MATERIALS SCIENCE, MULTIDISCIPLINARY | AMMONIUM BISULFATE | CHEMISTRY, PHYSICAL | NANOSCIENCE & NANOTECHNOLOGY | REDUCED SULFUR | PARTICLE FORMATION | MASS-SPECTROMETRY | SULFURIC-ACID-WATER | PARTICULATE AIR-POLLUTION | ALIPHATIC-AMINES
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 11/2016, Volume 138, Issue 44, pp. 14554 - 14557
Pd(II)-catalyzed gamma-C(sp(3))-H arylation of primary amines is realized by using 2-hydroxy-nicotinaldehyde as a catalytic transient directing group.... 
FUNCTIONALIZATION | UNACTIVATED C(SP)-H BONDS | C(SP)-H BONDS | PALLADIUM | ACTIVATION | AMINATION | NITROGEN-HETEROCYCLES | ALIPHATIC-AMINES | CARBON-HYDROGEN BONDS | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | Amines - chemistry | Molecular Structure | Catalysis | Palladium - chemistry | Alkylation | Chemical reactions | Usage | Palladium | Amines | Chemical properties | Index Medicus
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2019, Volume 58, Issue 17, pp. 5633 - 5638
Directed C−H functionalization has been realized as a complementary tool to the traditional approaches for a straightforward access of non‐proteinogenic amino... 
density functional calculations | natural products | mechanistic studies | BODIPY labeling | arylation | CHEMISTRY, MULTIDISCIPLINARY | Amines | Computation | Computer applications | Exploration | Amino acids | Iterative methods | Crystallography | Substrates | Aliphatic compounds | Aliphatic amines
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 12/2018, Volume 24, Issue 67, pp. 17838 - 17843
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 06/2018, Volume 140, Issue 22, pp. 6818 - 6822
Elaborating amines via C-H functionalization has been an important area of research over the past decade but has generally relied on an added directing group... 
DIRECTING GROUP | FUNCTIONALIZATION | CARBONYLATION | CATALYZED OXIDATION | COMPLEXES | ALIPHATIC-AMINES | BOND ACTIVATION | CYCLOPALLADATION | C-H ACTIVATION | SELECTIVITY | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2015, Volume 54, Issue 43, pp. 12645 - 12648
Journal Article