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1. Full Text Catalytic Enantioselective Allylation of Carbonyl Compounds and Imines
by Yus, Miguel and González-Gómez, José C and Foubelo, Francisco
Chemical Reviews, ISSN 0009-2665, 12/2011, Volume 111, Issue 12, pp. 7774 - 7854
NOZAKI-HIYAMA ALLYLATION | CHIRAL BIPYRIDINE N,N'-DIOXIDES | BARBIER-TYPE ALLYLATION | C-C BONDS | PYRIDINE N-OXIDES | INDIUM-MEDIATED ALLYLATION | HIGHLY EFFICIENT CATALYSTS | CHEMISTRY, MULTIDISCIPLINARY | SAKURAI-HOSOMI ALLYLATION | ASYMMETRIC ALLYLATION | TUMOR AGENTS CI-920 | Carbonyl compounds | Schiff bases | Usage | Allylic compounds | Metal catalysts | Analysis | Chemical properties | Catalysis | Ring formation (Chemistry) | Aldehydes
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2. Full Text Transition metal catalyzed nucleophilic allylic substitution: activation of allylic alcohols via pi-allylic species
by Sundararaju, B and Achard, M and Bruneau, C
CHEMICAL SOCIETY REVIEWS, ISSN 0306-0012, 2012, Volume 41, Issue 12, pp. 4467 - 4483
Modern organic synthesis now requires efficient atom economical synthetic methods operating under greener pathways to achieve C-C and C-heteroatom bond... 
TANDEM ALLYLATION | PALLADIUM(II) COMPLEXES | C-N BONDS | COORDINATION PROPERTIES | ACTIVE METHYLENE-COMPOUNDS | RUTHENIUM(IV) COMPLEXES | REGIOSELECTIVE ALLYLATION | ALPHA-ALLYLATION | ALIPHATIC-ALDEHYDES | CHEMISTRY, MULTIDISCIPLINARY | DEHYDRATIVE ALLYLATION
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3. Full Text Allylic ruthenium(IV) complexes in catalysis
by Bruneau, Christian and Achard, Mathieu
Coordination Chemistry Reviews, ISSN 0010-8545, 03/2012, Volume 256, Issue 5-8, pp. 525 - 536
Two types of allylic ruthenium(IV) complexes. Two families of ruthenium catalysts with wide applications. ► Applications of bis(allyl)ruthenium(IV) complexes... 
Ruthenium allyl species | Ruthenium(IV) | Homogeneous catalysis | Allylation | AQUEOUS-MEDIA | NUCLEOPHILIC-SUBSTITUTION | CARBONYL-COMPOUNDS | DEHYDRATIVE ALLYLATION | CHEMISTRY, INORGANIC & NUCLEAR | DECARBOXYLATIVE ALLYLATION | O-ALLYLATION | BIS(ALLYL)-RUTHENIUM(IV) COMPLEXES | 2+2+2 ALKYNE CYCLOTRIMERIZATION | ENANTIOSELECTIVE ALLYLATION | REGIOSELECTIVE ALLYLATION | Ruthenium | Catalysis | Chemical Sciences
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4. Full Text Iridium-Catalyzed Allylation of Chiral β‑Stereogenic Alcohols: Bypassing Discrete Formation of Epimerizable Aldehydes
by Schmitt, Daniel C and Dechert-Schmitt, Anne-Marie R and Krische, Michael J
Organic Letters, ISSN 1523-7060, 12/2012, Volume 14, Issue 24, pp. 6302 - 6305
The cyclometalated π-allyliridium 3,4-dinitro-C,O-benzoate complex modified by (R)- or (S)-Cl,MeO-BIPHEP promotes the transfer hydrogenative coupling of allyl... 
NOZAKI-HIYAMA ALLYLATION | ORGANOMETALLIC REAGENTS | HOMOALLYL ALCOHOLS | C BOND FORMATION | ALLYLBORATION | CARBONYL ALLYLATION | CHEMISTRY, ORGANIC | UMPOLUNG ALLYLATION | ENANTIOSELECTIVE ALLYLATION | ASYMMETRIC ALLYLATION | OXIDATION LEVEL | Alcohols - chemistry | Stereoisomerism | Alcohols - chemical synthesis | Molecular Structure | Catalysis | Iridium - chemistry | Aldehydes - chemistry
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5. Full Text Nickel-Catalyzed Allylation of a-Amido Sulfones To Form Protected Homoallylic Amines
by Caputo, JA and Naodovic, M and Weix, DJ
SYNLETT, ISSN 0936-5214, 02/2015, Volume 26, Issue 3, pp. 323 - 326
The allylation of stable, protected imine precursors, a-amiclo sulfones, with allylic acetates to form homoallylic amines is catalyzed by nickel under mild... 
HYDRAZONES | nickel | ALLYLIC CARBONATES | AQUEOUS-MEDIA | amines | REDUCTIVE ALLYLATION | CHEMISTRY, ORGANIC | imines | TERT-BUTANESULFINYL IMINES | MEDIATED ALLYLATION | ENANTIOSELECTIVE ALLYLATION | STEREOSELECTIVE-SYNTHESIS | reduction | allylation | ASYMMETRIC ALLYLATION | IN-SITU
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6. Full Text Pd‐Catalyzed Atroposelective C−H Allylation through β‐O Elimination: Diverse Synthesis of Axially Chiral Biaryls
by Liao, Gang and Li, Bing and Chen, Hao‐Ming and Yao, Qi‐Jun and Xia, Yu‐Nong and Luo, Jun and Shi, Bing‐Feng
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2018, Volume 57, Issue 52, pp. 17151 - 17155
Biaryl atropisomers are of great importance in natural products, pharmaceuticals, and asymmteric synthesis. The efficient synthesis of these chiral scaffolds... 
C−H allylation | ligands | palladium | atroposelectivity | biaryls | BRONSTED ACID | DICARBOXYLIC-ACID | ACTIVATION | BAYLIS-HILLMAN REACTION | N-BOC IMINES | CHEMISTRY, MULTIDISCIPLINARY | FUNCTIONALIZATION | ALLYLIC ALCOHOLS | KINETIC RESOLUTION | ENANTIOSELECTIVE ALLYLATION | C-H allylation | Asymmetric synthesis | Natural products | Chemical reactions | Carboxylic acids | Catalysis | Leucine | Aldehydes | Enantiomers | Allyl compounds | Chemical synthesis | Erosion
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7. Full Text F– Nucleophilic-Addition-Induced Allylic Alkylation
by Tian, Panpan and Wang, Cheng-Qiang and Cai, Sai-Hu and Song, Shengjin and Ye, Lu and Feng, Chao and Loh, Teck-Peng
Journal of the American Chemical Society, ISSN 0002-7863, 12/2016, Volume 138, Issue 49, pp. 15869 - 15872
Herein we present a novel strategy based on palladium-catalyzed allylic alkylation by taking advantage of the nucleophilic addition of external fluoride onto... 
DECARBOXYLATIVE ALLYLATION | IRIDIUM | ENANTIOSELECTIVE FLUORINATION | CATALYZED ALLYLATION REACTION | REGIO | ALPHA-ALLYLATION | CHEMISTRY, MULTIDISCIPLINARY | 3+2 CYCLOADDITION | DIASTEREO | ACTIVATED OLEFINS | TRIFLUOROMETHYLATION
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8. Full Text Palladium Catalyzed Decarboxylative Rearrangement of N‑Alloc Indoles
by Chen, Jun and Cook, Matthew J
Organic Letters, ISSN 1523-7060, 03/2013, Volume 15, Issue 5, pp. 1088 - 1091
A highly efficient palladium catalyzed decarboxylative allylic rearrangement of alloc indoles has been developed. This can also be combined with a... 
CHEMISTRY, ORGANIC | ALLYLATION
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9. Full Text Diastereoselective Allylation of Carbonyl Compounds and Imines: Application to the Synthesis of Natural Products
by Yus, Miguel and González-Gómez, José C and Foubelo, Francisco
Chemical Reviews, ISSN 0009-2665, 07/2013, Volume 113, Issue 7, pp. 5595 - 5698
TERT-BUTANESULFINYL IMINES | CHONDROMYCES-SPECIES MYXOBACTERIA | INFLUENZA-A VIRUS | METHYLENE-GAMMA-BUTYROLACTAMS | STEREOCONTROLLED TOTAL-SYNTHESIS | CATALYTIC ENANTIOSELECTIVE ALLYLATION | 1ST TOTAL-SYNTHESIS | DOUBLE-ALLYLBORATION REACTION | EFFICIENT ASYMMETRIC-SYNTHESIS | INDIUM-MEDIATED ALLYLATION | CHEMISTRY, MULTIDISCIPLINARY | Alkenes - chemistry | Biological Products - chemical synthesis | Biological Products - chemistry | Stereoisomerism | Imines - chemistry | Ketones - chemistry | Alkynes - chemistry | Aldehydes - chemistry | Carbonyl compounds | Schiff bases | Allylic compounds | Chemical properties | Research
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10. Full Text Preparation of Organozinc Reagents via Catalyst Controlled Three Component Coupling between Alkyne, lodoarene, and Bis(iodozincio)methane
by Shimada, Y and Ikeda, Z and Matsubara, S
ORGANIC LETTERS, ISSN 1523-7060, 07/2017, Volume 19, Issue 13, pp. 3335 - 3337
Three-component coupling between an alkyne, iodoarene, and bis(iodozincio)methane yields allylic zinc with a tetrasubstituted alkene moiety in the presence of... 
ALLYLATION | CHEMISTRY, ORGANIC
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11. Recent Advance of Allylic Alcohol Reagents in Organic Synthesis
by Zhang, J and Liao, JH and Wei, YF and Cheng, GJS and Luo, RS
MINI-REVIEWS IN ORGANIC CHEMISTRY, ISSN 1570-193X, 2018, Volume 15, Issue 6, pp. 476 - 487
Allylation reaction has been considered to be the most intriguing means for building collections of functionalized allylic compounds. The application of... 
regio-/stereo-selective | C-H ALLYLATION | CHEMISTRY, ORGANIC | ketones | BETA-ARYL KETONES | SUBSTITUTION-REACTIONS | transition-metal catalyzed | PALLADIUM-CATALYZED AMINATION | aldehydes | Allylic alcohol | REGIOSELECTIVE ALLYLATION | ALPHA-ALLYLATION | ENANTIOSELECTIVE ALLYLATION | activation | DUAL CATALYSIS | HECK REACTION | allylation | MOLECULAR-OXYGEN
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12. Full Text Noncovalent Interactions in Organocatalysis and the Prospect of Computational Catalyst Design
by Wheeler, Steven E and Seguin, Trevor J and Guan, Yanfei and Doney, Analise C
Accounts of Chemical Research, ISSN 0001-4842, 05/2016, Volume 49, Issue 5, pp. 1061 - 1069
Noncovalent interactions are ubiquitous in organic systems, and can play decisive roles in the outcome of asymmetric organocatalytic reactions. Their... 
LONDON DISPERSION | ACTIVATION | PROPARGYLATION | KINETIC RESOLUTION | AROMATIC RINGS | ENANTIOSELECTIVE ALLYLATION | ALDEHYDES | N,N'-DIOXIDE | CHEMISTRY, MULTIDISCIPLINARY | ASYMMETRIC ALLYLATION | BRONSTED-ACID
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13. Full Text Allylation of aldehydes with potassium allyltrifluoroborate catalyzed by Amberlyst A-15
by Couto, Túlio R and Freitas, Juliano C.R and Cavalcanti, Italo H and Oliveira, Roberta A and Menezes, Paulo H
Tetrahedron, ISSN 0040-4020, 08/2013, Volume 69, Issue 34, pp. 7006 - 7010
The use of the commercially available resin Amberlyst-15 as catalyst for allylation of aldehydes by potassium allyltrifluoroborate is described. The method... 
Amberlyst A-15 | Potassium allyltrifluoroborate | Allylation | BARBIER ALLYLATION | ACTIVATION | REAGENTS | LEWIS-ACID | AQUEOUS-MEDIA | CHEMISTRY, ORGANIC | AROMATIC-ALDEHYDES | CHEMOSELECTIVE ALLYLATION | DIASTEREOSELECTIVE ALLYLATION | CROTYLATION | ASYMMETRIC ALLYLATION | Aldehydes | Purification | Catalysts | Tetrahedrons | Chemical reactions | Allyl compounds | Polymers | Potassium
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14. Full Text Asymmetric cinnamylation of N-tert-butanesulfinyl imines with cinnamyl acetates: total syntheses of (+)-lycoricidine and (+)-7-deoxypancratistatin
by Cai, Sen-Lin and Yuan, Bin-Hua and Jiang, Yi-Xiang and Lin, Guo-Qiang and Sun, Xing-Wen
Chemical Communications, ISSN 1359-7345, 2017, Volume 53, Issue 25, pp. 3520 - 3523
Highly diastereoselective palladium catalyzed cinnamylation of N-tert-butanesulfinyl imines with cinnamyl acetates has been established to provide... 
AMARYLLIDACEAE ALKALOIDS | ALLYLIC ALCOHOLS | CARBONYL ALLYLATION | EFFICIENT SYNTHESIS | GLYOXYLIC OXIME ETHER | ALPHA-AMINO-ACIDS | UMPOLUNG ALLYLATION | INDIUM-MEDIATED ALLYLATION | NARCICLASINE ALKALOIDS | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY
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15. Full Text Pd/Phosphoramidite Thioether Complex-Catalyzed Asymmetric N‑Allylic Alkylation of Hydrazones with Allylic Acetates
by Lu, Bin and Feng, Bin and Ye, Hui and Chen, Jia-Rong and Xiao, Wen-Jing
Organic Letters, ISSN 1523-7060, 06/2018, Volume 20, Issue 12, pp. 3473 - 3476
A general and efficient Pd/phosphoramidite thioether complex-catalyzed asymmetric N-allylic alkylation of hydrazones with allylic acetates has been developed... 
CHEMISTRY, ORGANIC | DESIGN | LIGANDS | ALLYLATION
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16. Full Text Enantio- and diastereoselective asymmetric allylic alkylation catalyzed by a planar-chiral cyclopentadienyl ruthenium complex
by Kanbayashi, Naoya and Hosoda, Kazuki and Kato, Masanori and Takii, Koichiro and Okamura, Taka-aki and Onitsuka, Kiyotaka
Chemical communications (Cambridge, England), ISSN 1359-7345, 07/2015, Volume 51, Issue 54, pp. 10895 - 10898
We report asymmetric allylic alkylation of allylic chloride with β-diketones as the prochiral carbon nucleophiles using a planar-chiral Cp'Ru catalyst. The... 
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17. Full Text Palladium-catalyzed diastereoselective synthesis of homoaldol equivalent products
by Horino, Yoshikazu and Sugata, Miki and Sugita, Tetsu and Aimono, Ataru and Abe, Hitoshi
Tetrahedron Letters, ISSN 0040-4039, 05/2017, Volume 58, Issue 22, pp. 2131 - 2134
A palladium-catalyzed reaction of easily accessible 3-(pinacolatoboryl)allyl acetates and aldehydes provides facile access to synthetically useful homoaldol... 
Allylpalladium | Homoaldol equivalent reaction | Palladium catalysis | Allylation | C-BOND FORMATION | 3-COMPONENT REACTION | CHEMISTRY, ORGANIC | UMPOLUNG ALLYLATION | GAMMA-BUTYROLACTONES | PI-ALLYLPALLADIUM COMPLEXES | ALLYLIC ALCOHOLS | CARBONYL ALLYLATION | STEREOSELECTIVE-SYNTHESIS | BITE ANGLE | ASYMMETRIC ALLYLATION | Palladium | Catalysis | Aldehydes | Acetates | Isomerization
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18. Full Text Indium-Mediated Stereoselective Allylation
by Kumar, Dinesh and Vemula, Sandeep R and Balasubramanian, Narayanaganesh and Cook, Gregory R
Accounts of Chemical Research, ISSN 0001-4842, 10/2016, Volume 49, Issue 10, pp. 2169 - 2178
Stereoselective indium-mediated organic reactions have enjoyed tremendous growth in the last 25 years. This is in part due to the insensitivity of allylindium... 
ORGANIC-SYNTHESIS | BARBIER-TYPE ALLYLATION | AQUEOUS-MEDIA | CARBONYL-COMPOUNDS | CHIRAL HYDRAZONES | NEUTRAL-COORDINATE-ORGANOCATALYSTS | ENANTIOSELECTIVE ALLYLATION | ORGANOINDIUM REAGENTS | ALLYLIC SUBSTITUTION | CHEMISTRY, MULTIDISCIPLINARY | ASYMMETRIC ALLYLATION
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19. Full Text Catalytic Activation of Pinacolyl Allylboronate with Indium(I): Development of a General Catalytic Allylboration of Ketones
by Schneider, Uwe and Kobayashi, Shū
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2007, Volume 46, Issue 31, pp. 5909 - 5912
Have to B In it to win it! The unprecedented catalytic activation of a Group 13 metal reagent (boron) with a Group 13 metal catalyst in its low oxidation state... 
indium | ketones | allylation | boron | CC coupling | C-C coupling | Boron | Ketones | Indium | Allylation | ASYMMETRIC ALLYLBORATION | GLYOXYLIC OXIME ETHER | CARBONYL-COMPOUNDS | CHIRAL BIS-TITANIUM(IV) CATALYST | CHEMISTRY, MULTIDISCIPLINARY | IODIDE-MEDIATED ALLYLATION | HOMOALLYL ALCOHOLS | RETRO-ALLYLATION | DIASTEREOSELECTIVE ALLYLATION | OXIDATION-STATES | ENANTIOSELECTIVE ALLYLATION | Alkenes - chemistry | Indium - chemistry | Acetophenones - chemistry | Ketones - chemistry | Boronic Acids - chemistry | Butanes - chemistry | Catalysis
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20. Full Text Self-assembled organic nanotube promoted allylation of ketones in aqueous phase
by Sun, Hui and Jiang, Jian and Sun, Yimeng and Zhang, Qingwu and Liu, Minghua
Chemical Communications, ISSN 1359-7345, 2019, Volume 55, Issue 22, pp. 3254 - 3257
A self-assembled organic nanotube was found to promote the allylation of ketones in the aqueous phase. 
ACID | ACETYLCHOLINESTERASE | ACTIVE-SITE | OXYANION HOLE | ENANTIOSELECTIVE ALLYLATION | SUPRAMOLECULAR CATALYSIS | ALDEHYDES | STEREOSELECTIVE-SYNTHESIS | CHEMISTRY, MULTIDISCIPLINARY | CATALYTIC ASYMMETRIC ALLYLATION | CHEMOSELECTIVE ALLYLATION
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