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The Journal of Organic Chemistry, ISSN 0022-3263, 05/2018, Volume 83, Issue 9, pp. 5027 - 5034
A catalytic asymmetric α-arylation of aldehydes using 2-indolylmethanols as arylation reagents has been established. This reaction was enabled by a cooperative... 
QUATERNARY STEREOGENIC CENTERS | ENANTIOSELECTIVE SYNTHESIS | ALLYLIC ALCOHOLS | PHOSPHORIC-ACID | DIENAMINE ACTIVATION | S(N)1-TYPE REACTION | STRONGER BRONSTED ACIDS | ALPHA,BETA-UNSATURATED ALDEHYDES | CHEMISTRY, ORGANIC | BRANCHED ALDEHYDES | INDOLE-DERIVATIVES
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2018, Volume 57, Issue 46, pp. 15248 - 15252
Herein, we report the selective, non‐directed and cross‐dehydrogenative coupling of allylic C(sp3)−H bonds with C(sp2)−H bonds of (hetero)arenes. The... 
heteroarenes | allylic arylation | cross-dehydrogenative coupling | rhodium | OXIDATION | ALKYLATION | SULFONAMIDES | CATALYST | CHEMISTRY, MULTIDISCIPLINARY | FUNCTIONALIZATION | AMINATION | OLEFINS | SELECTIVITY | TERMINAL ALKENES | CARBOXYLIC-ACIDS | Olefins | Organic chemistry | Alkenes | Preservation | Dehydrogenation | Aromatic compounds | Chemical reactions | Coupling
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2016, Volume 55, Issue 8, pp. 2825 - 2829
A unique chemo‐ and regioselective α‐ and γ‐arylation of palladium azapentadienyl intermediates is presented. Two distinct catalysts and sets of conditions... 
regioselectivity | enamines | allylic amines | divergent synthesis | arylation | ANIONS | AROMATIC RINGS | REGIOSELECTIVE ARYLATION | CHEMISTRY, MULTIDISCIPLINARY | DECARBOXYLATIVE ALLYLATION | DIPHENYLGLYCINATE IMINES | ACETATES | LIGAND | ALLYLAMINE DERIVATIVES | Amines - chemistry | Catalysis | Palladium - chemistry | Imines - chemistry
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 09/2019, Volume 25, Issue 50, pp. 11630 - 11634
The reaction of readily available and bench‐stable N‐alkoxypyridinium salts with arylboronic and vinylboronic acids afforded δ‐aryl and δ‐vinyl alcohols,... 
cross-coupling | alkoxyl radical | C−H activation | dual catalysis | photoredox catalyst | NITROGEN-RADICALS | HYDROGEN-ATOM | COPPER | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | PHOTOREDOX CATALYSIS | FUNCTIONALIZATION | ALKENES | C-H activation | ALLYLIC ALCOHOLS | ALKOXYL RADICALS | RELAY CYCLIZATIONS | Catalysis | Copper | Hydrogen | Alcohols | Salts | Catalysts | Acids | Aromatic compounds | Alcohol | Radicals
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2007, Volume 46, Issue 44, pp. 8484 - 8487
Bring on the big cats: New, C2‐symmetric bulky N‐heterocyclic carbene ligands bring major improvements in the palladium‐catalyzed asymmetric intramolecular... 
oxindoles | palladium | asymmetric catalysis | NHC ligands | heterocycles | Heterocycles | Oxindoles | Palladium | Asymmetric catalysis | ENANTIOSELECTIVE SYNTHESIS | COMPLEXES | N-HETEROCYCLIC CARBENES | CHEMISTRY, MULTIDISCIPLINARY | CONSTRUCTION | BEARING | ALLYLIC SUBSTITUTION | GRIGNARD-REAGENTS | CONJUGATE ADDITION
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 12/2016, Volume 81, Issue 23, pp. 11646 - 11655
Palladium-catalyzed stereoselective β-arylations of phenylalanine, proline- and pipecolinic acid-containing peptides are a versatile tool for peptide... 
C(SP)-H BONDS | PIPECOLIC ACID | BIDENTATE | CHEMISTRY, ORGANIC | ALPHA-AMINO-ACIDS | C-ALKYLATION | H BOND FUNCTIONALIZATION | DERIVATIVES | SP | CATALYZED ALLYLIC ALKYLATIONS | BETA-LACTAMS | Palladium catalysts | Proline | Arylation | Research | Chemical properties | Phenylalanine
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 12/2016, Volume 138, Issue 50, pp. 16240 - 16243
Asymmetric arylation of alkylnitriles forms quaternary stereocenters in good enantiocontrol for the first time. A lithium heterodimer consisting of an... 
P,N LIGANDS | COUPLING REACTIONS | ARYL HALIDES | PHOSPHORAMIDITE LIGANDS | ALLYLIC ALKYLATION | DIARYLIODONIUM SALTS | INTRAMOLECULAR ARYLCYANATION | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | CONJUGATE ADDITION | GENERAL-METHOD | Arylation | Amides | Usage | Chemical properties | Catalysis
Journal Article
Organic Letters, ISSN 1523-7060, 04/2017, Volume 19, Issue 7, pp. 1542 - 1545
The first catalytic asymmetric α-arylation of pyrazol-5-ones has been established by using 2-indolylmethanols as direct electrophilic arylation reagents under... 
BRONSTED ACID | ASYMMETRIC-SYNTHESIS | INDOL-2-YL CARBINOLS | ALLYLIC ALCOHOLS | TERTIARY STEREOCENTERS | CHEMISTRY, ORGANIC | VICINAL TETRASUBSTITUTED STEREOCENTERS | STEREOCONTROLLED CONSTRUCTION | INDOLE-DERIVATIVES | CHIRAL PHOSPHORIC-ACID | MICHAEL ADDITION
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2019, Volume 141, Issue 2, pp. 998 - 1009
The use of more than one catalyst in one-pot reaction conditions has become a rapidly evolving protocol in the development of asymmetric catalysis. The lack of... 
ANION PHASE-TRANSFER | ALLYLIC ALCOHOLS | ACYCLIC OLEFINS | COMPUTATIONAL INSIGHTS | METAL CATALYSIS | STEREOGENIC CENTERS | CHIRAL PHOSPHORIC-ACID | C-H ACTIVATION | SELECTIVITY | CHEMISTRY, MULTIDISCIPLINARY | ELECTRON-DENSITY
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 01/2009, Volume 15, Issue 5, pp. 1205 - 1216
Journal Article
Organic Letters, ISSN 1523-7060, 11/2018, Volume 20, Issue 21, pp. 6882 - 6885
The first catalytic asymmetric conjugate addition to γ,δ-unsaturated β-dicarbonyl compounds was developed. With a chiral diene–rhodium­(I) μ-chloro dimer as... 
MULTICOMPONENT REACTIONS | CROSS-COUPLING REACTIONS | ENANTIOSELECTIVE ALLYLIC SUBSTITUTION | 1,4-ADDITION REACTIONS | CHIRAL DIENE LIGANDS | 1,3-DICARBONYL COMPOUNDS | QUATERNARY STEREOCENTERS | CHEMISTRY, ORGANIC | STEREOSELECTIVE-SYNTHESIS | ARYLBORONIC ACIDS | ALPHA,BETA-UNSATURATED CARBONYL
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2008, Volume 47, Issue 42, pp. 8108 - 8111
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2018, Volume 57, Issue 14, pp. 3682 - 3686
Journal Article