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1. Full Text Chiral Primary Amine/Palladium Dual Catalysis for Asymmetric Allylic Alkylation of β‐Ketocarbonyl Compounds with Allylic Alcohols
by Zhou, Han and Zhang, Long and Xu, Changming and Luo, Sanzhong
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2015, Volume 54, Issue 43, pp. 12645 - 12648
An efficient dual catalytic system composed of a chiral primary amine and a palladium complex was developed to promote the direct asymmetric allylic alkylation... 
palladium | asymmetric allylic alkylation | β‐ketocarbonyl compounds | allylic alcohols | chiral primary amines | β-ketocarbonyl compounds | TRANSITION-METAL CATALYSIS | AMINE CATALYSIS | CARBON QUATERNARY STEREOCENTERS | beta-ketocarbonyl compounds | ENAMINE CATALYSIS | ALDEHYDES | BOND-CLEAVAGE | CHEMISTRY, MULTIDISCIPLINARY | KETONES | PHOSPHORIC-ACID | ALPHA-ALLYLATION | Diamines | Amines | Asymmetry | Catalysts | Palladium | Catalysis | Aliphatic compounds | Alkylation
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2. Full Text Monofluorination of Organic Compounds: 10 Years of Innovation
by Champagne, Pier Alexandre and Desroches, Justine and Hamel, Jean-Denys and Vandamme, Mathilde and Paquin, Jean-François
Chemical Reviews, ISSN 0009-2665, 09/2015, Volume 115, Issue 17, pp. 9073 - 9174
SILVER-MEDIATED FLUORINATION | CATALYTIC ENANTIOSELECTIVE FLUORINATION | CHIRAL PALLADIUM COMPLEXES | ASYMMETRIC ELECTROPHILIC FLUORINATION | SELECTIVE ELECTROCHEMICAL FLUORINATION | PHASE-TRANSFER CATALYSIS | ANHYDROUS TETRABUTYLAMMONIUM FLUORIDE | NUCLEOPHILIC-SUBSTITUTION REACTIONS | C-F BOND | BETA-KETO-ESTERS | CHEMISTRY, MULTIDISCIPLINARY | Chemistry Techniques, Synthetic - trends | Hydrocarbons, Fluorinated - chemical synthesis | Chemistry Techniques, Synthetic - history | History, 21st Century | Halogenation | Allylic compounds | Chemical properties | Research | Fluorination | Organic compounds
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3. Full Text Synthesis and Applications of α‐Trifluoromethylated Alkylboron Compounds
by Argintaru, O. Andreea and Ryu, DaWeon and Aron, Ioana and Molander, Gary A
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2013, Volume 52, Issue 51, pp. 13656 - 13660
RBF3K is a chemist's BFF: A metal‐free synthetic route to unprecedented organoboron compounds bearing an α‐trifluoromethyl substituent, employing a variety of... 
silanes | trifluoromethylation | diazo compounds | boron | synthetic methods | ASYMMETRIC-SYNTHESIS | CARBONYL-COMPOUNDS | CHIRAL SECONDARY | BORONIC ESTERS | CHEMISTRY, MULTIDISCIPLINARY | UNACTIVATED ALKENES | CROSS-COUPLING REACTIONS | COPPER-CATALYZED TRIFLUOROMETHYLATION | ALLYLIC ALCOHOLS | HIGHLY STEREOSELECTIVE-SYNTHESIS | TERMINAL ALKENES | Molecular Structure | Catalysis | Boron - chemistry | Oxidation-Reduction | Methylation | Stereoisomerism
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4. Full Text Phosphine-triggered synthesis of functionalized cyclic compounds
by Ye, Long-Wu and Zhou, Jian and Tang, Yong
Chemical Society Reviews, ISSN 0306-0012, 2008, Volume 37, Issue 6, pp. 1140 - 1152
Nucleophilic phosphine catalysis has proven to be a powerful tool in organic synthesis, which can provide easy access to cyclic, bicyclic or polycyclic... 
CATALYZED 3+2 CYCLOADDITION | MORITA-BAYLIS-HILLMAN | 4+2 ANNULATION | ALLYLIC COMPOUNDS | ASYMMETRIC ORGANOCATALYSIS | SALICYL N-TOSYLIMINES | ENANTIOSELECTIVE CONSTRUCTION | CHEMISTRY, MULTIDISCIPLINARY | HIGHLY DIASTEREOSELECTIVE SYNTHESIS | PHOSPHORUS YLIDE REACTION | ELECTRON-DEFICIENT OLEFINS | Organic Chemicals - chemical synthesis | Molecular Structure | Phosphines - chemistry | Catalysis | Cyclization | Organic Chemicals - chemistry
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5. Full Text Metal‐Free Oxidative Radical Addition of Carbonyl Compounds to α,α‐Diaryl Allylic Alcohols: Synthesis of Highly Functionalized Ketones
by Chu, Xue‐Qiang and Meng, Hua and Zi, You and Xu, Xiao‐Ping and Ji, Shun‐Jun
Chemistry – A European Journal, ISSN 0947-6539, 12/2014, Volume 20, Issue 51, pp. 17198 - 17206
A metal‐free direct alkylation of simple carbonyl compounds (ketones, esters, and amides) with α,α‐diaryl allylic alcohols is described. The protocol provides... 
1,2‐aryl migration | radical reactions | dicarbonyl compounds | domino reactions | allylic compounds | INSERTION | EFFICIENT SYNTHESIS | BOND FUNCTIONALIZATION | CHEMISTRY, MULTIDISCIPLINARY | 1,2-aryl migration | REARRANGEMENT | ALKENES | CATALYZED TRIFLUOROMETHYLATION | SIMPLE ALKANES | CYCLIC ETHERS | C(SP)-H | ALKENYLATION | Carbonyl compounds | Ketones | Cascades | Migration | Esters | Radicals | Alkylation | Alcohols
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6. Full Text Iminoxyl Radical‐Based Strategy for Intermolecular CO Bond Formation: Cross‐Dehydrogenative Coupling of 1,3‐Dicarbonyl Compounds with Oximes
by Krylov, Igor B and Terent'ev, Alexander O and Timofeev, Vladimir P and Shelimov, Boris N and Novikov, Roman A and Merkulova, Valentina M and Nikishin, Gennady I
Advanced Synthesis & Catalysis, ISSN 1615-4150, 07/2014, Volume 356, Issue 10, pp. 2266 - 2280
Cross‐dehydrogenative CO coupling of 1,3‐diketones and 1,3‐keto esters with oximes was realized for the first time. The reaction proceeds in the presence of... 
1,3‐dicarbonyl compounds | oxidation | iminoxyl radicals | cross‐coupling | oximes | cross-coupling | 13-dicarbonyl compounds | P-TOLUENESULFONIC ACID | ELECTRON-SPIN-RESONANCE | AEROBIC OXIDATIVE AMINATION | CHEMISTRY, ORGANIC | BETA-DICARBONYL COMPOUNDS | TERT-BUTYL HYDROPEROXIDE | M-CHLOROPERBENZOIC ACID | CATALYZED ALLYLIC ACETOXYLATION | CORRESPONDING CARBONYL-COMPOUNDS | H BONDS | 1,3-dicarbonyl compounds | CHEMISTRY, APPLIED | MOLECULAR-OXYGEN | Oximes | Synthesis | Oxidizing agents | Esters | Joining | Potassium permanganate | Acetates | Radicals
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7. Full Text Proline Catalyzed α‑Aminoxylation Reaction in the Synthesis of Biologically Active Compounds
by Kumar, Pradeep and Dwivedi, Namrata
Accounts of Chemical Research, ISSN 0001-4842, 02/2013, Volume 46, Issue 2, pp. 289 - 299
The search for new and efficient ways to synthesize optically pure compounds is an active area of research in organic synthesis. Asymmetric catalysis provides... 
LEUKEMIA HL-60 CELLS | ACID | ABSOLUTE-CONFIGURATION | ENANTIOSELECTIVE SYNTHESIS | FORMAL SYNTHESIS | ITERATIVE APPROACH | ALLYLIC ALCOHOLS | CYTOTRIENIN-A | ENAMINE CATALYSIS | CHEMISTRY, MULTIDISCIPLINARY | ASYMMETRIC ALDOL | Thioctic Acid - chemical synthesis | Proline - chemistry | Biological Products - chemical synthesis | Biological Products - chemistry | Lactones - chemical synthesis | Pyrones - chemistry | Furans - chemistry | Pentanoic Acids - chemistry | Catalysis | Furans - chemical synthesis | Pyrones - chemical synthesis | Pentanoic Acids - chemical synthesis | Thioctic Acid - chemistry | Lactones - chemistry | Index Medicus | Proteins | Toxicology | Synthesis | Asymmetry | Chemists | Chemical reactions | Strategy
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8. Full Text C‐Alkylation of Ketones and Related Compounds by Alcohols: Transition‐Metal‐Catalyzed Dehydrogenation
by Huang, Fei and Liu, Zhuqing and Yu, Zhengkun
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2016, Volume 55, Issue 3, pp. 862 - 875
Transition‐metal‐catalyzed C‐alkylation of ketones and secondary alcohols, with alcohols, avoids use of organometallic or environmentally unfriendly alkylating... 
borrowing hydrogen | alkylation | alcohols | green chemistry | transition metals | AMINO-ALCOHOLS | IRIDIUM | C-3 ALKYLATION | CHEMISTRY, MULTIDISCIPLINARY | DIRECT ALPHA-ALKYLATION | SECONDARY ALCOHOLS | MILD CONDITIONS | BETA-ALKYLATION | ALLYLIC ALCOHOLS | N BOND FORMATION | Ketones | Hydrogen | Dehydrogenation | Alcohol | Carbon-carbon composites | Economics | Hydrogen storage | Transformation | Catalysts | Metals | Alkylating agents | Benign | Byproducts | Activation | Substrates | Alkylation | Alcohols | Reviews | Rendering | Bonding
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9. Full Text Enantioselective methodologies for the synthesis of spiro compounds
by Rios, Ramon
Chemical Society Reviews, ISSN 0306-0012, 1/2012, Volume 41, Issue 3, pp. 16 - 174
The enantioselective synthesis of spirocycles has been a long time pursued dream for organic chemists. Since the first pioneering efforts of Tamao and... 
PALLADIUM(II) COMPLEXES | DOMINO REACTIONS | RHODIUM(I) COMPLEX | ASYMMETRIC ALDOL REACTIONS | ALLYLIC ALKYLATION | BETA-LACTONES | SPIROCYCLIC OXINDOLES | 2+2+2 CYCLOADDITION | ORGANOCATALYTIC CASCADE REACTIONS | CONCISE SYNTHESIS | CHEMISTRY, MULTIDISCIPLINARY | Construction | Synthesis | Asymmetry | Chemists | Trends | Spiro compounds | Dreams
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10. Full Text Palladium-Catalyzed Cyclization of Propargylic Compounds
by Guo, Li-Na and Duan, Xin-Hua and Liang, Yong-Min
Accounts of Chemical Research, ISSN 0001-4842, 02/2011, Volume 44, Issue 2, pp. 111 - 122
Many groups have explored the scope of the palladium-based cyclization of propargylic compounds since Tsuji’s first report in 1985. Through the proper... 
SUBSTITUTED 2,3-DIHYDROFURANS | MULTICOMPONENT REACTIONS | RING EXPANSION REACTION | ONE-POT SYNTHESIS | ORGANOZINC COMPOUNDS | HIGHLY REGIOSELECTIVE SYNTHESIS | BETA-KETO-ESTERS | STEREOSELECTIVE-SYNTHESIS | ALLYLIC ALKYLATIONS | CHEMISTRY, MULTIDISCIPLINARY | ANNULATION REACTIONS | Palladium catalysts | Catalysis | Ring formation (Chemistry) | Chemical properties | Nucleophiles | Analysis
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