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allylsilanes (44) 44
chemistry, organic (44) 44
allylsilane (18) 18
chemistry (18) 18
carbonyl-compounds (13) 13
organic-synthesis (11) 11
aldehydes (10) 10
derivatives (10) 10
optically-active allylsilanes (10) 10
allylation (9) 9
chemistry, multidisciplinary (9) 9
catalysis (7) 7
alcohols (6) 6
cyclization (6) 6
cycloaddition (6) 6
alkenes (5) 5
complexes (5) 5
reactivity (5) 5
research (5) 5
silicon (5) 5
stereochemistry (5) 5
stereoisomerism (5) 5
chemical properties (4) 4
chemistry, inorganic & nuclear (4) 4
chemistry, physical (4) 4
efficient (4) 4
enantioselective synthesis (4) 4
esters (4) 4
ketones (4) 4
organosilicon compounds (4) 4
reagents (4) 4
反応 (4) 4
aldol reaction (3) 3
alkylation (3) 3
construction (3) 3
cross-coupling reaction (3) 3
cycloisomerization (3) 3
electrophilic substitution (3) 3
hydroboration (3) 3
hydrosilylation (3) 3
imines (3) 3
index medicus (3) 3
letter (3) 3
methods (3) 3
molecular structure (3) 3
one-pot synthesis (3) 3
organic synthesis (3) 3
organometallic compounds - chemistry (3) 3
silanes (3) 3
silanes - chemistry (3) 3
silyl enol ethers (3) 3
stereoselectivity (3) 3
tetrahydrofuran (3) 3
total synthesis (3) 3
transition-metal-complexes (3) 3
新規 (3) 3
1,4-addition (2) 2
[2,3]-sigmatropic rearrangement (2) 2
[methylene]cyclohexanone oxime (2) 2
acetal (2) 2
acetals (2) 2
acids (2) 2
acylaziridines (2) 2
alcohols - chemical synthesis (2) 2
alcohols - chemistry (2) 2
aldehyde (2) 2
allene (2) 2
allenylsilanes (2) 2
allyl compounds - chemistry (2) 2
allylic alkylation (2) 2
allylic amine (2) 2
allylic silanes (2) 2
allylsilanes oxime (2) 2
allylstannanes (2) 2
allyltin (2) 2
allyltrimethylsilane (2) 2
alpha (2) 2
amines (2) 2
amino polyol (2) 2
aminomethano desilylation (2) 2
anionic cyclization (2) 2
anti stereochemistry (2) 2
asymmetric-synthesis (2) 2
catalysts (2) 2
catalytic asymmetric hydrosilylation (2) 2
chemistry, medicinal (2) 2
chirality (2) 2
cross-coupling reactions (2) 2
cyclizations (2) 2
cycloaddition reaction (2) 2
cycloadditions (2) 2
cyclopentane (2) 2
ene-like reaction (2) 2
epoxide (2) 2
epoxides (2) 2
epoxy-allylsilane (2) 2
epoxy-allylstannane (2) 2
ethers (2) 2
facile synthesis (2) 2
formal synthesis (2) 2
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Chemical and Pharmaceutical Bulletin, ISSN 0009-2363, 2018, Volume 66, Issue 5, pp. 568 - 574
Surfactant-type protonic acid-promoted intramolecular cyclization of functionalized allylsilanes was studied in water for the synthesis of... 
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 7/2017, Volume 15, Issue 26, pp. 5441 - 5456
The following review will explore the historical development of Si-H bond insertion reactions, giving an up-to-date account on the metal catalysts often... 
FUNCTIONALIZATION | ENANTIOSELECTIVE RH(II) | ORGANIC-SYNTHESIS | DIAZOACETATE | DIAZO ESTERS | CHEMISTRY, ORGANIC | ALPHA-(ALKOXYSILYL)ACETIC ESTERS | ALLYLSILANES | METALLOPEPTIDES | SI-H BOND | C-H
Journal Article
Chemical Communications, ISSN 1359-7345, 09/2010, Volume 46, Issue 33, pp. 6180 - 6182
In the presence of 2-10 mol% of Tf2NH, a range of N-benzylic sulfonamides smoothly react with allylic, propargylic, benzylic, or hydrido silanes at room... 
ACIDS | ALKYLATION | IMINES | SILICON | CARBONYL-COMPOUNDS | ALLYLSILANES | BOND | CLEAVAGE | CHEMISTRY, MULTIDISCIPLINARY | SOLVENT
Journal Article
Catalysis Science & Technology, ISSN 2044-4753, 2015, Volume 5, Issue 4, pp. 2081 - 2084
A series of (salicylaldiminato)methylnickel complexes efficiently catalyse hydrosilylation of various olefins. The complexes are highly active for secondary... 
Journal Article
ACS Catalysis, ISSN 2155-5435, 02/2019, Volume 9, Issue 2, pp. 1612 - 1618
The asymmetric 1,2-Markovnikov hydrosilylation of conjugated dienes with primary silanes catalyzed by a quinoline-oxazoline cobalt complex has been described.... 
conjugated dienes | hydrosilylation | cobalt | asymmetric catalysis | polyorganosiloxane | allylsilane | ALLYLIC SILANES | ASYMMETRIC HYDROSILYLATION | HYDROBORATION | CHEMISTRY, PHYSICAL | POLYMERIZATION | ALKENES | OPTICALLY-ACTIVE ALLYLSILANES | ALPHA,OMEGA-DIKETONES | 1,4-HYDROSILYLATION | COPOLYMERIZATION | POLY(SILYL ETHER)S
Journal Article
Organic Letters, ISSN 1523-7060, 06/2014, Volume 16, Issue 11, pp. 2923 - 2925
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 01/2020, Volume 61, Issue 2, p. 151384
[Display omitted] The halogenation of various α-ester allylsilanes with halo-succinimides (NXS, X = Cl, Br, and I) has been investigated. It has been shown... 
Diastereoselective synthesis | Allylsilane | Olefination | Halogenation | HALIDES | DEPROTONATION | 2-CHLOROACETATES | CHEMISTRY, ORGANIC | CATALYZED ALPHA-ARYLATION | ALKYNYLATION
Journal Article
Accounts of Chemical Research, ISSN 0001-4842, 06/2000, Volume 33, Issue 6, pp. 354 - 362
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 12/2013, Volume 78, Issue 23, pp. 12268 - 12273
A convenient method for the synthesis and isolation of highly reactive formylsilanes by oxidative cleavage of α-silyl glycols is presented. The mild conditions... 
CYCLOADDITIONS | ASYMMETRIC DIHYDROXYLATION | CHEMISTRY | REACTIVITY | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | ALLYLSILANES | STABLE FORMYLSILANE | BROOK REARRANGEMENT | DERIVATIVES | ACYLSILANES | Glycols | Chemical properties | Research | Chemical synthesis | Methods | Methyl groups | Naturvetenskap | Natural Sciences | Kemi | Chemical Sciences
Journal Article
Journal of the Chinese Chemical Society, ISSN 0009-4536, 01/2018, Volume 65, Issue 1, pp. 81 - 86
We report here the silylation of α,β‐unsaturated acceptors in water at room temperature using a copper catalyst. A broad substrate scope, including chalcone... 
Acyclic and cyclic dienones | C─Si bond formation | Reaction in water | Basic copper carbonate | ORGANIC-SYNTHESIS | ASYMMETRIC-SYNTHESIS | 1,4-DISILYLATION | SILICON | SI BOND FORMATION | ALLYLSILANES | CHEMISTRY, MULTIDISCIPLINARY | C-Si bond formation | ACCEPTORS | ENONES | 1,4-ADDITION | BETA-HYDROXY KETONES
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 05/2011, Volume 76, Issue 10, pp. 4112 - 4118
Journal Article
Synlett, ISSN 0936-5214, 05/2009, Volume 2009, Issue 8, pp. 1303 - 1306
Abstract A highly efficient asymmetric total synthesis of (+)-brefeldin A was accomplished by using intramolecular epoxide opening of an epoxy allylsilane and... 
letter | (+)-brefeldin A | Cyclizations | Epoxides | Total synthesis | Metathesis | OXIDE | FORMAL SYNTHESIS | OLEFIN CROSS-METATHESIS | CHEMISTRY, ORGANIC | ALLYLSILANES | cyclizations | metathesis | KINETIC RESOLUTION | ESTERS | BREFELDIN-A | epoxides | total synthesis | CYCLIZATION
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 09/2003, Volume 68, Issue 19, pp. 7329 - 7333
The catalytic cycles of CdF2·1-catalyzed and AgF·BINAP-catalyzed allylation using allyltrimethoxysilane in protic solvents were investigated. The experimental... 
IMINES | CHEMISTRY | REACTIVITY | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | ION | ALDEHYDES | ALLYLSILANES | PENTACOORDINATE | ORGANO-SILICON COMPOUNDS | ASYMMETRIC ALLYLATION
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 2002, Volume 43, Issue 49, pp. 8959 - 8962
Iron(III) chloride-catalyzed allylation reactions of a variety of aldehydes with allyltrimethylsilane proceeded efficiently and smoothly to afford the... 
KETONES | SCANDIUM TRIFLUOROMETHANESULFONATE | YB(OTF) | LEWIS-ACID | AQUEOUS-MEDIA | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | ALLYLSILANES | ALLYLTRIMETHYLSILANE | DERIVATIVES | HIGHLY EFFICIENT
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 04/2019, Volume 60, Issue 14, pp. 953 - 956
[Display omitted] •Direct trifluoromethylthiolation of allylic and propargylic alcohols.•SN2′-type nucleophilic substitution reaction as the key step.•Broad... 
Regioselective | Trifluoromethylthiolation | Allylic alcohol | Propargylic alcohol | REAGENT | DIFLUOROCARBENE | ENANTIOSELECTIVE FLUORINATION | CHEMISTRY, ORGANIC | CASCADE | ALLYLSILANES | OXIDATIVE TRIFLUOROMETHYLATION | NUCLEOPHILIC TRIFLUOROMETHYLTHIOLATION | COPPER-CATALYZED TRIFLUOROMETHYLATION | SILYL ENOL ETHERS | TERMINAL ALKENES
Journal Article
Journal Article
Russian Journal of Organic Chemistry, ISSN 1070-4280, 6/2017, Volume 53, Issue 6, pp. 836 - 845
Treatment of methyl (2E)-3-[(1S,2R,5R)-2-({[tert-butyl(dimethyl)silyl]oxy}methyl)-5-(trimethylsilyl) cyclopent-3-en-1-yl]prop-2-enoate with Bu4NF in THF... 
Chemistry | Organic Chemistry | REACTIVITY | CHEMISTRY, ORGANIC | ORGANIC-SYNTHESIS | ALLYLSILANE
Journal Article
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