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Angewandte Chemie International Edition, ISSN 1433-7851, 04/2014, Volume 53, Issue 18, pp. 4608 - 4613
Dicarbon (C2), the simplest bare carbon molecule, is ubiquitous in the interstellar medium and in combustion flames. A gas‐phase synthesis is presented of the... 
benzyl radical | reaction dynamics | gas‐phase chemistry | bimolecular reactions | combustion chemistry | gas-phase chemistry | FLAMES | MECHANISM | ACETYLENE | POLYCYCLIC AROMATIC-HYDROCARBONS | PHENYL RADICALS | AB-INITIO | DECOMPOSITION | CHEMISTRY, MULTIDISCIPLINARY | GROWTH | Chemical properties | Hydrogen | Isomerization | Butadiene | Carbon
Journal Article
MOLECULAR PHYSICS, ISSN 0026-8976, 2007, Volume 105, Issue 19-22, pp. 2541 - 2549
The reaction pathways to C7H(7)(+)(tolyl, benzyl, and tropylium) from o-, m-, and p-chlorotoluene radical cations have been studied at the SCF level of theory... 
PARA-TOLYL | FIRST-ROW ATOMS | MOLECULAR CALCULATIONS | PHYSICS, ATOMIC, MOLECULAR & CHEMICAL | ION | MASS-SPECTROMETRY | Ab initio | tolyl | and tropylium | reaction mechanism | CONTRACTION | and p-chlorotoluene | TIME-RESOLVED PHOTODISSOCIATION | ATOMIC BASIS SETS | C7H7 | benzyl | GAUSSIAN BASIS FUNCTIONS
Journal Article
FEBS Letters, ISSN 0014-5793, 2000, Volume 477, Issue 1, pp. 79 - 83
The extracellular enzyme manganese peroxidase is believed to degrade lignin by a hydrogen peroxide-dependent oxidation of Mn(II) to the reactive species... 
Lignin biodegradation | Cellobiose dehydrogenase | Manganese peroxidase | Phanerochaete chrysosporium | Hydroxyl radical | MnP, manganese peroxidase | LP, lignin peroxidase | RP-HPLC, reverse-phase high-pressure liquid chromatography | SDS-PAGE, sodium dodecyl sulphate–polyacrylamide gel electrophoresis | CDH, cellobiose dehydrogenase | VG, veratryl glycol | MS, mass spectroscopy | GC, gas chromatography | NIST, National Institute of Standards and Technology | GC–MS, gas chromatography connected to mass spectroscopy | MSA, α-methylsyringylalcohol | OXIDATION | MN-PEROXIDASE | MECHANISM | BASIDIOMYCETE PHANEROCHAETE-CHRYSOSPORIUM | BIOCHEMISTRY & MOLECULAR BIOLOGY | WOOD DEGRADATION | LACCASE | CELLOBIOHYDROLASE | cellobiose dehydrogenase | HYDROXYL RADICAL GENERATION | PHENOL OXIDASE ACTIVITY | CELL BIOLOGY | hydroxyl radical | BIOPHYSICS | lignin biodegradation | MOLECULAR-WEIGHT SUBSTANCE | manganese peroxidase | Biodegradation, Environmental | Benzyl Alcohols - chemistry | Gas Chromatography-Mass Spectrometry | Hydroxylation | Oxidation-Reduction | Phanerochaete - enzymology | Oxidants - metabolism | Lignin - chemistry | Anisoles - metabolism | Anisoles - chemistry | Hydroxyl Radical - metabolism | Chromatography, High Pressure Liquid | Glycols - metabolism | Phenols - metabolism | Spectrophotometry, Ultraviolet | Hydrogen Peroxide - metabolism | Glycols - chemistry | Lignin - metabolism | Peroxidases - metabolism | Benzyl Alcohols - metabolism | Manganese Compounds - metabolism | Carbohydrate Dehydrogenases - metabolism | lignin biodegradation; cellobiose dehydrogenase; hydroxyl radical; manganese peroxidase; Phanerochaete chrysosporium; BASIDIOMYCETE PHANEROCHAETE-CHRYSOSPORIUM; HYDROXYL RADICAL GENERATION; MOLECULAR-WEIGHT SUBSTANCE; PHENOL OXIDASE ACTIVITY; WOOD DEGRADA
Journal Article
Journal of the American Society for Mass Spectrometry, ISSN 1044-0305, 1991, Volume 2, Issue 4, pp. 270 - 277
Journal Article
Organometallics, ISSN 0276-7333, 01/2019, Volume 38, Issue 2, pp. 351 - 360
The dimeric beta-diketiminato calcium hydride, [(BDI)CaH](2) (BDI = HC{(Me)CN-2,6-i-Pr2C6H3}(2)), reacts with terminal alkenes to provide the corresponding... 
BENZYL COMPLEXES | THF | IODIDE | X-RAY | REACTIVITY | CHEMISTRY, ORGANIC | POLYMERIZATION | POTASSIUM | HEAVY GRIGNARD-REAGENTS | BENZYLCALCIUM COMPLEXES | STRONTIUM | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 08/2015, Volume 21, Issue 32, pp. 11462 - 11474
The effect of fluorination on the conformational and hydrogen‐bond (HB)‐donating properties of a series of benzyl alcohols has been investigated experimentally... 
conformation analysis | hydrogen‐bond acidity | benzylic alcohols | fluorine | hydrogen-bond acidity | VAN | RECOGNITION | BARRIER | INTERNAL-ROTATION | ORGANOFLUORINE CHEMISTRY | CONFORMER | CHEMISTRY, MULTIDISCIPLINARY | CF2 GROUP | SPECTRA | C-H | ACCEPTOR | Alcohol | Infrared spectroscopy | Landscapes | Solvation | Mathematical analysis | Derivatives | Benzyl alcohol | Fluorination | Hydroxyl groups | Full Papers
Journal Article
ACS Sustainable Chemistry & Engineering, ISSN 2168-0485, 07/2018, Volume 6, Issue 7, pp. 9269 - 9276
Journal Article
Organometallics, ISSN 0276-7333, 08/2012, Volume 31, Issue 15, pp. 5494 - 5499
The migratory insertion reaction of a carbene into a palladium–acyl bond has been observed both for monoaminocarbenes and for methoxycarbenes. The acyl... 
ALPHA-DIAZOCARBONYL COMPOUNDS | CATALYZED INSERTION | BENZYL BROMIDES | CARBON-CARBON BOND | CRYSTAL-STRUCTURE | C-C BOND | ENOLATE COMPLEXES | CHEMISTRY, ORGANIC | FORMING REDUCTIVE ELIMINATION | VINYL HALIDES | N-TOSYLHYDRAZONES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Organometallics, ISSN 0276-7333, 02/2003, Volume 22, Issue 4, pp. 775 - 781
Rare-earth metal complexes of the type [Ln{η5:η1-C5Me4SiMe2(C4H3O-2)}(CH2SiMe3)2(THF)] (Ln = Y, Lu) were prepared by σ-bond metathesis of [Ln(CH2SiMe3)3(THF)2]... 
POLAR MONOMERS | BENZYL COMPLEXES | LANTHANIDES | HYDRIDO COMPLEXES | ORGANOMETALLIC CHEMISTRY | CHEMISTRY, ORGANIC | YTTRIUM ALKYL | POLYMERIZATION | MONOANIONIC ANCILLARY LIGANDS | C-H BONDS | RAY CRYSTAL-STRUCTURE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 02/2014, Volume 55, Issue 7, pp. 1271 - 1280
Aryl nitriles can be efficiently synthesized through transition-metal-mediated cyanation of aryl halides, arenes, aryl boronic acids, and so on. Among those... 
Arenes | Cyanations | Aryl nitriles | Copper catalysis | Aryl halides | CARBON | AMMONIUM IODIDE | CHEMISTRY, ORGANIC | CYANIDE SOURCE | BROMIDES | INDOLES | C-H CYANATION | BENZYL CYANIDE | PALLADIUM-CATALYZED CYANATION | EFFICIENT | Catalysts | Aromatic compounds | Tetrahedrons | Cyanides | Catalysis | Copper | Bonding | Acetone
Journal Article
Organometallics, ISSN 0276-7333, 02/1996, Volume 15, Issue 3, pp. 923 - 927
From the dilithio reagent o-C6H4(NLiSiiPr3)2 (2), the new complexes [o-C6H4(NSiiPr3)2]2Zr (3), [o-C6H4(NSiiPr3)2]Zr(OtBu)2 (4), [o-C6H4(NSiiPr3)2]TiCl2 (5),... 
BENZYL COMPLEXES | CHEMISTRY | CHEMISTRY, ORGANIC | EARLY TRANSITION-METALS | PHOSPHINE COMPLEXES | THERMOCHEMICALLY BASED STRATEGIES | C-H BONDS | ALKYL COMPLEXES | RAY CRYSTAL-STRUCTURE | BOND METATHESIS MECHANISM | M = TI | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article