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chemistry, multidisciplinary (79) 79
borenium (72) 72
reactivity (61) 61
borenium cations (58) 58
chemistry (58) 58
boron (49) 49
chemistry, inorganic & nuclear (48) 48
activation (42) 42
complexes (42) 42
frustrated lewis pairs (38) 38
boranes (30) 30
borinium (29) 29
cations (29) 29
catalysis (25) 25
chemistry, organic (24) 24
lewis-acid (21) 21
bor (20) 20
borane (20) 20
alkynes (16) 16
index medicus (16) 16
ions (16) 16
kation (15) 15
borenium cation (14) 14
borylation (14) 14
derivatives (14) 14
hydroboration (14) 14
alkenes (13) 13
chemical properties (11) 11
hydrogen (11) 11
lewis acid (11) 11
ligands (11) 11
boronium (10) 10
carbenes (10) 10
free hydrogen activation (10) 10
hydrogenation (10) 10
internal alkynes (10) 10
ligand (10) 10
reduction (10) 10
adducts (9) 9
arene borylation (9) 9
catalysts (9) 9
dehydrogenation (9) 9
hydride (9) 9
lewis acids (9) 9
lewis-säure (9) 9
1,1-carboboration (8) 8
acid (8) 8
bonding (8) 8
carbon (8) 8
cation (8) 8
cleavage (8) 8
esters (8) 8
hydrides (8) 8
hydrogenation catalysis (8) 8
molecular structure (8) 8
alkine (7) 7
bond activation (7) 7
chemical bonds (7) 7
chemical sciences (7) 7
crystal-structure (7) 7
diborane (7) 7
dihydrogen (7) 7
generation (7) 7
h bond activation (7) 7
homogeneous catalysis (7) 7
ion (7) 7
molecular-structure (7) 7
n-heterocyclic carbenes (7) 7
olefins (7) 7
organic chemistry (7) 7
oxidation (7) 7
pairs (7) 7
room-temperature (7) 7
temperature (7) 7
transformation (7) 7
acidity (6) 6
analysis (6) 6
borenium ions (6) 6
boron compounds (6) 6
c-h activation (6) 6
carben (6) 6
cationic (6) 6
chemical synthesis (6) 6
density functional calculations (6) 6
dihydrogen activation (6) 6
electrons (6) 6
electrophilic arene borylation (6) 6
elektron (6) 6
imines (6) 6
lewis acidity (6) 6
lewis base (6) 6
models, molecular (6) 6
nitrogen (6) 6
phosphorus (6) 6
röntgendiffraktion (6) 6
terminal alkynes (6) 6
x-ray-diffraction (6) 6
1,2-carboboration (5) 5
anion (5) 5
anions (5) 5
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ORGANIC & BIOMOLECULAR CHEMISTRY, ISSN 1477-0520, 06/2019, Volume 17, Issue 22, pp. 5520 - 5525
The borylative cyclisation of 1,2-dialkynyl benzenes with BCl3 leads to dibenzopentalenes (via intramolecular SEAr) or benzofulvenes (via chloride addition)... 
CHEMISTRY, ORGANIC | ROUTE | BORENIUM CATIONS | ALKYNES | AMINOBORATION
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 08/2017, Volume 56, Issue 15, pp. 8627 - 8643
As main-group chemistry, in particular boron chemistry, has expanded and developed over the past 20 years, one reagent has risen to prominence as well.... 
CATALYZED HYDROBORATION | UNSATURATED-COMPOUNDS | GENERAL-SYNTHESIS | TRANS-HYDROBORATION | ALLIED REACTIONS | TERMINAL ALKYNES | FRUSTRATED LEWIS PAIRS | BORENIUM CATIONS | INTERNAL ALKYNES | PROPARGYL REARRANGEMENT | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2017, Volume 56, Issue 4, pp. 1135 - 1140
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2011, Volume 50, Issue 9, pp. 2098 - 2101
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 10/2016, Volume 22, Issue 41, pp. 14618 - 14624
A diverse range of Lewis acidic alkyl, vinyl and aryl boranes and borenium compounds that are capable of new carbon–carbon bond formation through selective... 
main group | allylboron | borenium | carboboration | borocation | ACTIVATION | HYDROGENATION | MOLECULAR-STRUCTURE | FRUSTRATED LEWIS PAIRS | HIGH OPTICAL PURITY | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | 1,1-CARBOBORATION | SI-H | CHEMISTRY | BORENIUM CATIONS | Carbamates | Chemical bonds | Boron | Carbon-carbon composites | Aromatic compounds | Boranes | Cations | Boron compounds | Bonding | Complexity | Organic compounds
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2014, Volume 136, Issue 3, pp. 914 - 917
The formation of a hitherto unknown three-coordinate dicationic hydrido boron complex is described. Interestingly, supporting ligand carbodicarbene gave... 
BORYL ANION | HETEROCYCLIC CARBENE-BORANES | CARBODICARBENES | BORINIUM | REACTIVITY | CHEMISTRY | RADICALS | BORENIUM CATIONS | PARENT BORYLENE | BOND | CHEMISTRY, MULTIDISCIPLINARY | Boron | Research | Electrophiles | Carbenes
Journal Article
Dalton Transactions, ISSN 1477-9226, 2016, Volume 45, Issue 14, pp. 6060 - 6070
The 1,1-carboboration of 1-Me3Si-1-alkynes is the dominant reaction observed using [PhBCl(2-DMAP)][AlCl4], 1, and PhBCl2 electrophiles, with highly substituted... 
PHENYLBORATION | ARENE BORYLATION | 1,1-CARBOBORATION | ACTIVATION | ALKYNYLSILANES | 1,1-ORGANOBORATION | SELECTIVE SYNTHESIS | INTERNAL ALKYNES | BORENIUM CATIONS | ALKYNYLBORANES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Organometallics, ISSN 0276-7333, 12/2017, Volume 36, Issue 24, pp. 4952 - 4960
The relative (to BEt3) hydride ion affinity (HIA) of a series of acridine borenium salts has been calculated, with some HIAs found to be similar to that for... 
CATALYSIS | ALKENES | BORON | SIGMA-BOND ACTIVATION | HYDROBORATIONS | CARBENE-BORANES | CHEMISTRY, ORGANIC | ELECTROPHILIC BORYLATION | BORENIUM CATIONS | ALKYNES | PAIRS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Chemical Science, ISSN 2041-6520, 2018, Volume 9, Issue 6, pp. 1433 - 1438
The activation of a H-H bond, the simplest covalent bond, is a fundamentally important process. Addition of H-2 to an elemental center typically occurs on low... 
N-HETEROCYCLIC CARBENE | FREE HYDROGEN ACTIVATION | H-2 BINDING | COMPLEXES | REACTIVITY | FRUSTRATED LEWIS PAIRS | BORENIUM CATIONS | OXIDATIVE ADDITION | BORANES | CHEMISTRY, MULTIDISCIPLINARY | SIGMA-BOND METATHESIS
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 02/2016, Volume 138, Issue 7, pp. 2126 - 2129
Journal Article
Science, ISSN 0036-8075, 12/2016, Volume 354, Issue 6317, pp. aaf7229 - aaf7229
Journal Article
Dalton Transactions, ISSN 1477-9226, 08/2015, Volume 44, Issue 32, pp. 14359 - 14367
Bronsted acid HNTf2 (Tf = SO2CF3) mediated dehydrogenative hydride abstraction from (L-1)BH3 (3) and (L-2)BH3 (4) (L-1 = IPrCH2 = 1,3-(2,6-di-isopropylphenyl)... 
BORYL ANION | NEUTRAL DIBORENE | HYDROGEN STORAGE-SYSTEMS | N-HETEROCYCLIC-CARBENE | CRYSTAL-STRUCTURE DETERMINATION | TRIPLE BOND | TRANSITION-STATES | BORENIUM CATIONS | MAIN-GROUP ELEMENTS | BORANE COMPLEXES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2015, Volume 54, Issue 19, pp. 5722 - 5726
Journal Article
Chemical science (Cambridge), ISSN 2041-6520, 04/2016, Volume 7, Issue 4, pp. 2537 - 2543
Whilst hydrogen is a potentially clean fuel for energy storage and utilisation technologies, its conversion to electricity comes at a high energetic cost. This... 
Journal Article