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borylation (1034) 1034
chemistry, multidisciplinary (870) 870
chemistry, organic (814) 814
catalysis (414) 414
activation (359) 359
c-h borylation (314) 314
index medicus (292) 292
complexes (269) 269
boron (264) 264
esters (247) 247
arenes (243) 243
functionalization (242) 242
derivatives (239) 239
palladium (235) 235
chemistry, inorganic & nuclear (222) 222
cross-coupling reactions (219) 219
chemistry (211) 211
c-h activation (194) 194
room-temperature (192) 192
hydroboration (182) 182
catalyzed borylation (175) 175
halides (173) 173
aryl halides (169) 169
ligand (166) 166
cross-coupling reaction (164) 164
ligands (157) 157
alkynes (153) 153
chemical properties (149) 149
copper (147) 147
aromatic compounds (142) 142
reactivity (142) 142
alkenes (141) 141
organoboron compounds (139) 139
arylation (132) 132
cross-coupling (128) 128
molecular structure (125) 125
palladium-catalyzed borylation (122) 122
catalysts (121) 121
iridium (121) 121
synthesis (120) 120
chemistry, physical (117) 117
arylboronic acids (113) 113
reagents (108) 108
organic-synthesis (100) 100
organic chemistry (96) 96
bisdiboron (95) 95
dehydrogenative borylation (95) 95
bonds (94) 94
aryl (93) 93
bor (93) 93
analysis (90) 90
article (89) 89
chemical reactions (87) 87
rhodium (87) 87
stereoselective-synthesis (87) 87
boronic acids (85) 85
coupling reactions (85) 85
regioselectivity (84) 84
bond activation (82) 82
acids (81) 81
chemical synthesis (81) 81
c-h bonds (77) 77
aldehydes (73) 73
oxidative addition (72) 72
stereoisomerism (70) 70
mechanism (69) 69
asymmetric-synthesis (68) 68
diboration (68) 68
iridium-catalyzed borylation (68) 68
silylation (68) 68
bond formation (67) 67
selectivity (67) 67
cleavage (66) 66
homogeneous catalysis (66) 66
pinacolborane (65) 65
boronic esters (63) 63
chemistry, applied (63) 63
research (63) 63
alcohols (62) 62
nickel (62) 62
terminal alkynes (62) 62
chemical bonds (61) 61
coupling reaction (58) 58
ketones (58) 58
efficient (57) 57
oxidation (57) 57
aryl chlorides (56) 56
enantioselective synthesis (56) 56
boron compounds - chemistry (55) 55
functional groups (55) 55
one-pot synthesis (55) 55
route (55) 55
synthetic methods (55) 55
construction (54) 54
funktionalisierung (54) 54
functionalisation (53) 53
usage (53) 53
chemical sciences (52) 52
functional-group (52) 52
heterocycles (52) 52
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1. Full Text Recent advances in catalytic C−H borylation reactions
by Xu, Liang and Wang, Guanghui and Zhang, Shuai and Wang, Hong and Wang, Linghua and Liu, Li and Jiao, Jiao and Li, Pengfei
Tetrahedron, ISSN 0040-4020, 12/2017, Volume 73, Issue 51, pp. 7123 - 7157
In the past decades, the iridium-catalyzed C–H bond borylation and other newly discovered catalytic borylation reactions have received extensive research... 
Selectivity | C−H activation | Organoboron compounds | Borylation | PERIODIC MESOPOROUS ORGANOSILICA | DEHYDROGENATIVE BORYLATION | IRIDIUM CATALYST | C(SP)-H BORYLATION | CHEMISTRY, ORGANIC | TERMINAL ALKYNES | C-H activation | PHOTOCHEMICAL CONDITIONS | METHYL-GROUP | REGIOSELECTIVE BORYLATION | BOND ACTIVATION | LATE-STAGE FUNCTIONALIZATION | Fine chemicals
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2. Full Text Chiral Bidentate Boryl Ligand Enabled Iridium-Catalyzed Asymmetric C(sp 2 )-H Borylation of Diarylmethylamines
by Zou, Xiaoliang and Zhao, Haonan and Li, Yinwu and Gao, Qian and Ke, Zhuofeng and Senmiao Xu, Xu
Journal of the American Chemical Society, ISSN 0002-7863, 2019, Volume 141, Issue 13, pp. 5334 - 5342
Optically active organoboronic acids and their derivatives are an important family of target compounds in organic chemistry, catalysis, and medicinal... 
DIELS-ALDER | ENANTIOSELECTIVE SYNTHESIS | ARENES | C(SP)-H BORYLATION | REGIOSELECTIVE BORYLATION | DIRECTED ORTHO BORYLATION | BOND ACTIVATION | C-H BORYLATION | EFFICIENT | CHEMISTRY, MULTIDISCIPLINARY | SILYLATION
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3. Full Text Decarboxylative Borylation of mCPBA-Activated Aliphatic Acids
by Wei, D and Liu, TM and Zhou, B and Han, B
ORGANIC LETTERS, ISSN 1523-7060, 01/2020, Volume 22, Issue 1, pp. 234 - 238
A decarboxylative borylation of aliphatic acids for the synthesis of a variety of alkylboronates has been developed by mixing m-chloroperoxybenzoic acid... 
CATALYZED DECARBONYLATIVE BORYLATION | METAL-FREE BORYLATION | B BOND | CARBON | CROSS-COUPLING REACTION | CHEMISTRY, ORGANIC | PHOTOINDUCED BORYLATION | ARYL | C-H BORYLATION | ADDITIVE-FREE | CLEAVAGE
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4. Full Text Functional Group Interconversion: Decarbonylative Borylation of Esters for the Synthesis of Organoboronates
by Guo, Lin and Rueping, Magnus
Chemistry – A European Journal, ISSN 0947-6539, 11/2016, Volume 22, Issue 47, pp. 16787 - 16790
A new and efficient nickel‐catalyzed decarbonylative borylation reaction of carboxylic acid esters with bis(pinacolato)‐diboron has been developed. This... 
nickel | C−H borylation | esters | decarbonylative cross-coupling | C−O bond activation | ROOM-TEMPERATURE | BORONIC ACID | O BOND | C-H borylation | NICKEL CATALYSIS | C-O bond activation | CHEMISTRY, MULTIDISCIPLINARY | METAL-FREE BORYLATION | CROSS-COUPLING REACTIONS | ARYL HALIDES | BOND ACTIVATION | CATALYZED BORYLATION | MIXED-LIGAND SYSTEMS | Esters | Chemical properties | Aromatic compounds | Strategy | Transformations | Nickel | Tolerances | Carboxylic acids | Substrates
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5. Full Text Room temperature Pd(0)/Ad(3)P-catalyzed coupling reactions of aryl chlorides with bis(pinacolato)diboron
by Dong, J and Guo, H and Peng, W and Hu, QS
TETRAHEDRON LETTERS, ISSN 0040-4039, 03/2019, Volume 60, Issue 11, pp. 760 - 763
Room temperature Pd(0)/Ad(3)P-catalyzed cross-coupling reactions of aryl chlorides with bis(pinacolato) diboron are described. The Pd(0)/Ad(3)P catalyst,... 
HALIDES | IPSO-BORYLATION | NEOPENTYLGLYCOLBORYLATION | Borylation reaction | CHEMISTRY, ORGANIC | Tris(1-adamantyl)phosphine | Palladium | Aryl chlorides | PALLADIUM-CATALYZED BORYLATION | EFFICIENT CATALYST | CYCLOPALLADATED FERROCENYLIMINE | HALOARENES | C-H BORYLATION | LIGAND | PRECATALYST
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6. Full Text Visible-Light Photoredox Borylation of Aryl Halides and Subsequent Aerobic Oxidative Hydroxylation
by Jiang, Min and Yang, Haijun and Fu, Hua
Organic Letters, ISSN 1523-7060, 10/2016, Volume 18, Issue 20, pp. 5248 - 5251
Efficient and practical visible-light photoredox borylation of aryl halides and subsequent aerobic oxidative hydroxylation were developed. The protocols use... 
METAL-FREE BORYLATION | PALLADIUM-CATALYZED BORYLATION | ROOM-TEMPERATURE | CROSS-COUPLING REACTIONS | BOND FUNCTIONALIZATION | SYNTHETIC APPLICATIONS | CHEMISTRY, ORGANIC | C-H BORYLATION | ALKOXY DIBORON REAGENTS | AROMATIC-SUBSTITUTION | ARYLBORONIC ACIDS
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7. Full Text Direct Conversion of Arylamines to Pinacol Boronates: A Metal‐Free Borylation Process
by Mo, Fanyang and Jiang, Yubo and Qiu, Di and Zhang, Yan and Wang, Jianbo
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2010, Volume 49, Issue 10, pp. 1846 - 1849
Leave the metal out: Arylboronates are produced in moderate to good yields by direct borylation of readily available aryl amines (see scheme). The reaction can... 
Sandmeyer reaction | cross‐coupling | diazo compounds | aryl boronates | borylation | Diazo compounds | Aryl boronates | Cross-coupling | Borylation | ORGANOBORON COMPOUNDS | CROSS-COUPLING REACTION | ONE-POT SYNTHESIS | CHEMISTRY, MULTIDISCIPLINARY | PALLADIUM-CATALYZED BORYLATION | ARYLBORONIC ESTERS | IRIDIUM COMPLEXES | ARYL HALIDES | cross-coupling | C-H BORYLATION | AROMATIC BORYLATION | ROOM-TEMPERATURE REACTIONS | Amines - chemistry | Butanones - chemistry | Molecular Structure | Boron - chemistry
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8. Full Text Stereocontrolled Total Synthesis of (−)‐Stemaphylline
by Varela, Ana and Garve, Lennart K. B and Leonori, Daniele and Aggarwal, Varinder K
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2017, Volume 56, Issue 8, pp. 2127 - 2131
Homologation of readily available α‐boryl pyrrolidines with metal carbenoids is especially challenging even when good leaving groups (Cl−) are employed. By... 
total synthesis | Stemona alkaloids | lithiation–borylation | stereocontrol | boronic esters | CATALYSIS | ASYMMETRIC-SYNTHESIS | ACID | lithiation-borylation | CHEMISTRY, MULTIDISCIPLINARY | ALKYL-HALIDES | METHODOLOGY | ENANTIOSELECTIVE SYNTHESES | LITHIATION | DERIVATIVES | BORYLATION | Alkaloids | Esters | Synthesis | Organic compounds | Amines | Chloride | Communications | Communication
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9. Full Text Additive- and Photocatalyst-Free Borylation of Arylazo Sulfones under Visible Light
by Xu, Yuliang and Yang, Xinying and Fang, Hao
The Journal of Organic Chemistry, ISSN 0022-3263, 10/2018, Volume 83, Issue 20, pp. 12831 - 12837
We developed a photocatalyst-free and additive-free, visible light induced borylation reaction using arylazo sulfones as starting material. This protocol shows... 
METAL-FREE BORYLATION | DECARBOXYLATIVE BORYLATION | SELECTIVE REACTIONS | ROOM-TEMPERATURE | ARYLBORONIC ESTERS | CROSS-COUPLING REACTION | NI-CATALYZED BORYLATION | CHEMISTRY, ORGANIC | ALKOXY DIBORON REAGENTS | SYNTHETIC ROUTE | IN-SITU
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10. Full Text Recent Advances in C–B Bond Formation through a Free Radical Pathway
by Yan, Guobing and Huang, Dayun and Wu, Xiangmei
Advanced Synthesis & Catalysis, ISSN 1615-4150, 03/2018, Volume 360, Issue 6, pp. 1040 - 1053
The development of a methodology for the preparation of arylboronic acids or arylboronates is of significant interest to organic chemists. Classical synthetic... 
free radicals | visible light | arylboronic esters | photoredox catalysts | borylation | ROOM-TEMPERATURE | CROSS-COUPLING REACTION | HETEROCYCLIC CARBENE BORANES | H BORYLATION | TRIPLET PHOTOSENSITIZERS | CHEMISTRY, ORGANIC | SYNTHETIC ROUTE | METAL-FREE BORYLATION | PALLADIUM-CATALYZED BORYLATION | ARYL DIAZONIUM SALTS | CARBON-CARBON | CHEMISTRY, APPLIED | Chemical tests and reagents | Transition metals | Free radicals | Hydrocarbons | Lithium | Organoboron compounds | Boron | Halides | Aromatic compounds | Reagents | Chemists | Chemical bonds | Reaction mechanisms | Borates
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11. Full Text Selection of boron reagents for Suzuki-Miyaura coupling
by Lennox, Alastair J. J and Lloyd-Jones, Guy C
Chemical Society Reviews, ISSN 0306-0012, 01/2014, Volume 43, Issue 1, pp. 412 - 443
Suzuki-Miyaura (SM) cross-coupling is arguably the most widely-applied transition metal catalysed carbon-carbon bond forming reaction to date. Its success... 
CATALYZED DEHYDROGENATIVE BORYLATION | HETEROCYCLIC CARBENE LIGANDS | ONE-POT SYNTHESIS | ELECTROPHILIC DISPLACEMENT-REACTIONS | TERMINAL ALKYNES | C-H BORYLATION | STEREOSELECTIVE-SYNTHESIS | ASYMMETRIC HYDROBORATION | CHEMISTRY, MULTIDISCIPLINARY | ARYLBORONIC ACIDS | 2-CARBON BUILDING-BLOCK
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12. Full Text Chiral Copper(II)‐Catalyzed Enantioselective Boron Conjugate Additions to α,β‐Unsaturated Carbonyl Compounds in Water
by Kobayashi, Shū and Xu, Pengyu and Endo, Toshimitsu and Ueno, Masaharu and Kitanosono, Taku
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2012, Volume 51, Issue 51, pp. 12763 - 12766
Copper pins on the boron: The enantioselective 1,4‐addition of diboron to α,β‐unsaturated compounds proceeds smoothly in the presence of catalytic amounts of... 
β‐borylation | copper | asymmetric catalysis | boron | synthetic methods | β-borylation | beta-borylation | RING-OPENING REACTIONS | AQUEOUS-MEDIA | ORGANIC-REACTIONS | N-HETEROCYCLIC CARBENES | ORGANOBORONIC ESTERS | CHEMISTRY, MULTIDISCIPLINARY | BETA-BORATION | LEWIS-ACID CATALYSTS | ASYMMETRIC ALDOL REACTIONS | MESO-EPOXIDES
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13. Full Text Regioselectivity of the borylation of alkanes and arenes
by Hartwig, John F
Chemical Society Reviews, ISSN 0306-0012, 04/2011, Volume 40, Issue 4, pp. 1992 - 2002
The borylation of alkanes and arenes has become some of the most practical C-H bond functionalization chemistry. Most striking is the high regioselectivity of... 
FREE-RADICAL SUBSTITUTION | SATURATED-HYDROCARBONS | CHLORIDE COMPLEXES | IRIDIUM COMPLEXES | DIRECTED ORTHO BORYLATION | REGIOSPECIFIC FUNCTIONALIZATION | ALKYL ISOMERIZATION EQUILIBRIA | CATALYZED BORYLATION | REDUCTIVE ELIMINATION | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS
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