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Angewandte Chemie (International ed.), ISSN 1433-7851, 2016, Volume 55, Issue 32, pp. 9239 - 9243
...(I) dimers. In every case, these compounds are kinetically stabilized by sterically bulky N , N ′‐chelating, or N , N ′, O ‐tripodal, anionic ligands, so far confined... 
magnesium(I) | bulky amides | DFT calculations | metal–metal bonding | ACTIVATION | metal-metal bonding | COMPLEXES | COMPOUND | COORDINATION | STATE | H-2 | CHEMISTRY, MULTIDISCIPLINARY | DIGERMYNE | CHEMISTRY | BEARING | MG-MG BONDS | Metal bonding | Amides | Magnesium | Solvents | Covalence | Mathematical analysis | Bonding strength | Chemical bonds | Ligands | Dimers | Bonding | Crystal structure | Chemical Sciences
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 2013, Volume 19, Issue 51, pp. 17358 - 17368
Journal Article
Accounts of Chemical Research, ISSN 0001-4842, 10/2005, Volume 38, Issue 10, pp. 784 - 793
...−C10 range, whose demand is growing fast. Identifying and fine-tuning the parameters that influence the activity and selectivity of metal catalysts constitute major challenges at the interface between ligand design, coordination... 
ASYMMETRIC CATALYSIS | ZIEGLER CATALYSTS | OLEFIN POLYMERIZATION CATALYSTS | ALPHA-OLEFINS | COORDINATION CHEMISTRY | BULKY SUBSTITUENTS | HOMOGENEOUS CATALYSTS | MIGRATORY INSERTION | P,N-PHOSPHINOPYRIDINE LIGANDS | CHEMISTRY, MULTIDISCIPLINARY | TRIMERIZATION | Models, Chemical | Nickel - chemistry | Nitrogen - chemistry | Chelating Agents - chemistry | Phosphorus - chemistry | Ligands | Catalysis | Ethylenes - chemistry | Dimerization | Polymerization | Chemical properties | Structure | Organometallic chemistry | Analysis | Ethylene
Journal Article
Chemistry : a European journal, ISSN 1521-3765, 2019, Volume 25, Issue 50, pp. 11745 - 11757
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 06/2019, Volume 361, Issue 12, pp. 2832 - 2835
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2019, Volume 58, Issue 2, pp. 607 - 611
The steric bulk of the well‐known DIPPBDI ligand (CH[C(CH3)N‐DIPP]2, DIPP=2,6‐diisopropylphenyl) was increased by replacing isopropyl for isopentyl groups... 
bulky ligand | magnesium | alkaline earth metal | metal-metal bonding | low valence | MG-MG | BENZENE | COMPLEXES | REACTIVITY | DIMERS | ADDUCT | CHEMISTRY, MULTIDISCIPLINARY | Organic chemistry | Reduction | Benzene | Ligands | Magnesium | Dimerization | Dipping
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 12/2016, Volume 55, Issue 24, pp. 12568 - 12582
... of (phenylimino)­pyridine ligands on manganese centers for this purpose. The key feature is the asymmetric structure of the redox-noninnocent ligand that permits independent tuning of its steric and electronic properties. The α... 
BULKY BIPYRIDINE LIGANDS | CRYSTAL-STRUCTURE | BRONSTED ACIDS | AB-INITIO | ELECTROCHEMICAL REDUCTION | METAL | CATALYST | CHARGE-TRANSFER | CARBON-DIOXIDE | RHENIUM | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 2010, Volume 16, Issue 30, pp. 9237 - 9247
.... The performance of the ligands is comparable to a Buchwald‐type triarylphosphane, namely, (2′‐methyl[1,1′‐biphenyl]‐2‐yl)diphenylphosphane, which in contrast to the calixarenyl phosphanes tested may display chelating behaviour in solution... 
palladium | calixarenes | supramolecular catalysis | cross‐coupling | bulky monophosphanes | Bulky monophosphanes | Supramolecular catalysis | Palladium | Cross-coupling | Calixarenes | PHOSPHINE | DENDRIPHOS | SCOPE | COMPLEXES | CRYSTAL | CHEMISTRY, MULTIDISCIPLINARY | cross-coupling | CATALYSTS | HYDROFORMYLATION | Binding | Cross coupling | Aromatic compounds | Chlorides | Chemical reactions | Ligands
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2017, Volume 56, Issue 38, pp. 11615 - 11619
The synthesis of the new m‐terphenyl‐substituted cyclopentadienyl ligand precursor 1‐cyclopentadiene‐2,6‐bis(2,4,6‐trimethylphenyl)benzene (TerMesCpH) is described... 
chelates | cyclopentadienyl ligands | crystallography | bulky ligands | alkali metals | BENZENE | MAIN-GROUP | COMPOUND | POLYMERIZATION | CHEMISTRY, MULTIDISCIPLINARY | ETHYLENE | NICKEL | REDUCTION | METALLOCENE | Cyclopentadiene | Cobalt | Chelates | Salts | Iodides | Alkali metals | X-ray diffraction | Cesium | Lithium | Isomers | Crystallography | Benzene | Ligands | Oxidation | Coordination compounds | Chemical synthesis | Metal complexes | Potassium
Journal Article
Journal of molecular catalysis. A, Chemical, ISSN 1381-1169, 2015, Volume 406, pp. 224 - 237
....•Ligand substituent electronic effects seem to affect cyclometallation tendency.•Results suggest that cyclometallation caused poor catalytic prospects... 
Suzuki–Miyaura coupling | Palladacycle | Structure–property correlation | Homogeneous catalysis | Organometallic cyclometallation | Structure-property correlation | Suzuki-Miyaura coupling | PALLADIUM | PRECATALYSTS | HECK | CHEMISTRY, PHYSICAL | HETEROGENEOUS CATALYSIS | BULKY | CROSS-COUPLING REACTIONS | SYSTEMS | ARYL | HEMILABILITY
Journal Article
Dalton transactions : an international journal of inorganic chemistry, ISSN 1477-9226, 2009, Issue 35, pp. 7215 - 7222
A series of benzobisimidazolium salts 1a-d has been prepared by tetraalkylation of benzobisimidazol. The salts 1a-d react with two equivalents of... 
TEMPLATE SYNTHESIS | N-HETEROCYCLIC CARBENE | IRIDIUM | PALLADIUM COMPLEXES | BUILDING-BLOCKS | COORDINATION | STERICALLY BULKY | CATALYSTS | RATIONAL DESIGN | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Tetrahedron, ISSN 0040-4020, 2019, Volume 75, Issue 32, pp. 4199 - 4211
...–N bonds under mild reaction conditions. This work summarizes a variety of C–N cross-coupling reactions using biaryl monophosphines as supporting ligands... 
Palladium | Biaryl monophosphine ligands | C–N cross coupling | PRECATALYSTS | DESIGN | ZEROVALENT PALLADIUM | HIGHLY-ACTIVE CATALYST | COMPLEXES | ARYLATION | CHEMISTRY, ORGANIC | OXIDATIVE ADDITION | BULKY | C-N cross coupling | DIALKYLBIARYL PHOSPHINES | AMINATION REACTIONS
Journal Article