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Angewandte Chemie - International Edition, ISSN 1433-7851, 02/2009, Volume 48, Issue 7, pp. 1313 - 1316
Journal Article
2017, New Directions in Organic and Biological Chemistry, ISBN 9781498729093
Web Resource
2017, New Directions in Organic and Biological Chemistry, ISBN 9781498729093
Web Resource
06/2011
This thesis describes synthetic applications of α-keto carbocations, which represent potentially useful, but poorly studied, reversed polarity equivalents of... 
carbocation | stereoselectivity | 0490
Dissertation
European Journal of Organic Chemistry, ISSN 1434-193X, 08/2015, Volume 2015, Issue 24, pp. 5370 - 5380
In order to elucidate the mechanism for the isomerization of the 2‐norbornyl carbocation into its most stable isomer, the 1,3‐dimethylcyclopentenyl... 
Non‐classical carbocation | Carbocations | 2‐Norbornyl carbocation | Rearrangement | 2-Norbornyl carbocation | Non-classical carbocation | SOLVOLYSIS | CARBENIUM IONS | CARBONIUM | AB-INITIO | CHEMISTRY, ORGANIC | REARRANGEMENTS | SPECTROSCOPY | NORBORNYL | CHEMISTRY | CATION | DERIVATIVES | Activation energy | Isomerization
Journal Article
Angewandte Chemie - International Edition, ISSN 1433-7851, 2017, Volume 56, Issue 1, pp. 368 - 370
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 11/2019, Volume 2019, Issue 44, pp. 7394 - 7398
Diastereoconvergent direct dehydrative nucleophilic substitutions of diastereomeric mixtures of diarylmethanols with 1,3‐dicarbonyls in the presence of SnBr4... 
Tin | Carbocations | Synthetic methods | Chiral auxiliaries | Diastereoselectivity
Journal Article
Chemistry - A European Journal, ISSN 0947-6539, 02/2010, Volume 16, Issue 7, pp. 2045 - 2049
Journal Article
Angewandte Chemie - International Edition, ISSN 1433-7851, 11/2009, Volume 48, Issue 46, pp. 8757 - 8760
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 02/2015, Volume 2015, Issue 6, pp. 1226 - 1234
Friedel–Crafts arylation of α‐hydroxy ketones such as 2‐hydroxy‐1,2,2‐triarylethanones has been achieved with a variety of arenes and heteroarenes in the... 
Arylation | Carbocations | Synthetic methods | Ketones
Journal Article
Synlett, ISSN 0936-5214, 06/2011, Volume 2011, Issue 9, pp. 1235 - 1238
Abstract The reaction of indole and various methyl-substituted indoles with the title compounds was studied in the presence of chiral phosphoric acids, which... 
cluster | electrophilic aromatic substitutions | enantioselectivity | organocatalysis | alkylations | carbocations | stereoselective synthesis | BENZYLIC CARBOCATIONS | PHOSPHORIC-ACID | KINETIC RESOLUTION | CHEMISTRY, ORGANIC | ALKYLATION REACTIONS | CARBON-CARBON
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 03/2013, Volume 2013, Issue 7, pp. 1193 - 1208
Journal Article
ACS Catalysis, ISSN 2155-5435, 06/2016, Volume 6, Issue 6, pp. 3670 - 3673
The C–F bond is the strongest single bond to carbon, constituting an intrinsic challenge for selective catalytic activation in the presence of other functional... 
Brønsted acid | Friedel-Crafts | aliphatic fluoride | autocatalysis | carbocations
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 06/2013, Volume 2013, Issue 18, pp. 3621 - 3633
Journal Article
Advances in carbocation chemistry, ISSN 1047-3645, 1989
Journal
Chemistry – A European Journal, ISSN 0947-6539, 12/2006, Volume 13, Issue 1, pp. 336 - 345
Rate and equilibrium constants for the reactions of pyridines with donor‐substituted benzhydrylium ions have been determined spectrophotometrically. The... 
organocatalysis | intrinsic barriers | pyridines | kinetics | carbocations | Pyridines | Carbocations | Kinetics | Organocatalysis | Intrinsic barriers
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2008, Volume 47, Issue 41, pp. 7892 - 7895
A skeleton in the closet: The unprecedented title rearrangement of 1,6‐enynes has been observed with gold and platinum catalysts (see scheme, [M]=metal... 
gold | metal carbenes | enynes | rearrangement | carbocations | Gold | Enynes | Carbocations | Metal carbenes | Rearrangement
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 07/2016, Volume 138, Issue 27, pp. 8400 - 8403
Electrochemical oxidation of toluene derivatives in the presence of a sulfilimine gave benzylaminosulfonium ions as stabilized benzyl cation pools, which... 
AMINATION | ALKOXYSULFONIUM IONS | TYROSINE-PHOSPHATASE 1B | CARBON NUCLEOPHILES | AMINES | CARBOCATIONS | BOND FUNCTIONALIZATION | ANODIC OXIDATIONS | GENERATION | FORMYLCHROMONE DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2008, Volume 47, Issue 52, pp. 10106 - 10109
Stereoelectronic factors are apparently responsible for the high selectivity observed in the title SN1‐type reaction of acetates 1 in favor of the anti... 
Lewis acids | nucleophilic substitution | alkynes | carbocations | bismuth | Bismuth | Carbocations | Nucleophilic substitution | Alkynes
Journal Article
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