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ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 11/2017, Volume 56, Issue 47, pp. 15088 - 15092
An enantioselective C-H amidation of phosphine oxides by using an iridium(III) catalyst bearing an atropchiral cyclopentadienyl (Cp-x) ligand is reported. A... 
BRONSTED ACID | BOND AMIDATION | ACTIVATION | ASYMMETRIC-SYNTHESIS | BIARYL COMPOUNDS | EFFICIENT SYNTHESIS | P-chirality | asymmetric catalysis | P-STEREOGENIC PHOSPHINAMIDES | CHEMISTRY, MULTIDISCIPLINARY | iridium | CYCLOPENTADIENYL LIGANDS | C-H activation | chiral Cp ligand | AMINO-ACIDS | METAL CATALYSIS
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 02/2017, Volume 829, pp. 31 - 36
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2017, Volume 56, Issue 47, pp. 15088 - 15092
An enantioselective C−H amidation of phosphine oxides by using an iridium(III) catalyst bearing an atropchiral cyclopentadienyl (Cpx) ligand is reported. A... 
iridium | P-chirality | asymmetric catalysis | C−H activation | chiral Cp ligand | Oxides | Catalysis | Enantiomers | Organic acids | Transformation | Catalysts | Phosphine | Phosphorus | Ligands | Carboxylic acids | Iridium | Leucine
Journal Article
Chemistry - A European Journal, ISSN 0947-6539, 02/2016, Volume 22, Issue 7, pp. 2270 - 2273
Chiral spirocyclic sultams are a valuable compound class in organic and medicinal chemistry. A rapid entry to this structural motif involves a [3+2] annulation... 
chiral Cp ligands | C-H activation | asymmetric catalysis | sultams | rhodium | CALPAIN-I INHIBITORS | AROMATIC KETIMINES | ACTIVATION | C-H BOND | ASYMMETRIC-SYNTHESIS | CHEMISTRY, MULTIDISCIPLINARY | CYCLOPENTADIENYL LIGANDS | FUNCTIONALIZATION | N-SULFONYL KETIMINES | CATALYZED 3+2 ANNULATION | CYCLIC KETIMINES
Journal Article
Angewandte Chemie - International Edition, ISSN 1433-7851, 02/2019, Volume 58, Issue 8, pp. 2514 - 2518
A chiral Cp Rh catalyst system in situ generated from a Cp Rh (cod) precatalyst and bis(o-toluoyl) peroxide as activating oxidant was developed for a C-H... 
chiral Cp ligands | ring opening | asymmetric catalysis | C−H activation | rhodium
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2017, Volume 56, Issue 1, pp. 364 - 367
Compounds with stereogenic phosphorus atoms are frequently used as ligands for transition‐metal as well as organocatalysts. A direct catalytic enantioselective... 
chiral Cp ligands | P-chirality | asymmetric catalysis | C−H activation | rhodium | Rhodium | Enantiomers | Catalysis | Phosphorus | Atomic properties | Ligands | Activation | Chemical synthesis | Alkynes
Journal Article
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 09/2018, Volume 57, Issue 39, pp. 12901 - 12905
An enantioselective C-H arylation of phosphine oxides with o-quinone diazides catalyzed by an iridium(III) complex bearing an atropchiral cyclopentadienyl... 
chiral Cp ligands | ACTIVATION | MONOPHOSPHINES | P-chirality | asymmetric catalysis | CHEMISTRY, MULTIDISCIPLINARY | iridium | CYCLOPENTADIENYL LIGANDS | FUNCTIONALIZATION | ATROPISOMERS | C-H activation | OLEFINATION | ATROPOSELECTIVE SYNTHESIS | ASYMMETRIC CATALYTIC-REACTIONS | CYCLIZATION | CARBOXYLIC-ACIDS
Journal Article
Angewandte Chemie (International ed. in English), ISSN 1433-7851, 11/2017, Volume 56, Issue 47, pp. 15088 - 15092
An enantioselective C-H amidation of phosphine oxides by using an iridium(III) catalyst bearing an atropchiral cyclopentadienyl (Cp ) ligand is reported. A... 
AMARYLLIDACEAE ALKALOIDS | ENT-LYCORICIDINE | NITROSOCARBONYL COMPOUNDS | P-chirality | asymmetric catalysis | NARCICLASINE ALKALOIDS | CHEMISTRY, MULTIDISCIPLINARY | iridium | (+)-LYCORICIDINE | (+)-NARCICLASINE | DIHYDROXYLATION | C-H activation | chiral Cp ligand | DIELS-ALDER REACTION | DERIVATIVES | D-GLUCOSE
Journal Article
by Sun, Y and Cramer, N
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 01/2017, Volume 56, Issue 1, pp. 364 - 367
Compounds with stereogenic phosphorus atoms are frequently used as ligands for transition-metal as well as organocatalysts. A direct catalytic enantioselective... 
BRONSTED ACID | chiral Cp ligands | ASYMMETRIC-SYNTHESIS | ENANTIOSELECTIVE SYNTHESIS | BIARYL COMPOUNDS | QUATERNARY STEREOCENTERS | P-chirality | asymmetric catalysis | CHEMISTRY, MULTIDISCIPLINARY | H BOND ACTIVATION | CYCLOPENTADIENYL LIGANDS | DIRECTING GROUPS | C-H activation | STEREOGENIC PHOSPHORUS-COMPOUNDS | METAL CATALYSIS | rhodium
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2018, Volume 57, Issue 39, pp. 12901 - 12905
An enantioselective C−H arylation of phosphine oxides with o‐quinone diazides catalyzed by an iridium(III) complex bearing an atropchiral cyclopentadienyl... 
iridium | chiral Cp ligands | P-chirality | asymmetric catalysis | C−H activation | Oxides | Catalysis | Enantiomers | Quinone | Iridium compounds | Phosphine | Phosphorus | Ligands | Iridium | Leucine
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2019, Volume 58, Issue 50, pp. 18136 - 18140
An efficient CpxRhIII‐catalyzed enantioselective alkenyl C−H functionalization/[4+1] annulation of acryl amides and allenes is reported. The described... 
chiral Cp ligands | [4+1]-annulation | asymmetric catalysis | C−H activation | rhodium
Journal Article
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 06/2019, Volume 58, Issue 26, pp. 8902 - 8906
Chiral sulfoximines with stereogenic sulfur atoms are promising motifs in drug discovery. We report an efficient method to access chiral sulfoximines through a... 
AMIDATIONS | chiral Cp ligands | ACTIVATION | sulfoximines | ACIDS | ANNULATION | ONE-POT | IODINATION | asymmetric catalysis | CHEMISTRY, MULTIDISCIPLINARY | DISCOVERY | 4-ALKYNALS | Rhodium | LIGANDS | kinetic resolution | INHIBITOR
Journal Article
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 02/2019, Volume 58, Issue 8, pp. 2514 - 2518
A chiral (CpRhIII)-Rh-x catalyst system in situ generated from a (CpRhI)-Rh-x(cod) precatalyst and bis(o-toluoyl) peroxide as activating oxidant was developed... 
BICYCLIC HYDRAZINES | chiral Cp ligands | ACTIVATION | ASYMMETRIC-SYNTHESIS | COMPLEXES | asymmetric catalysis | CHEMISTRY, MULTIDISCIPLINARY | DESYMMETRIZATION | CYCLOPENTADIENYL LIGANDS | C-H activation | ring opening | OLEFINS | BOND | ACCESS | rhodium | DIAZABICYCLES
Journal Article
ACS CATALYSIS, ISSN 2155-5435, 11/2019, Volume 9, Issue 11, pp. 10226 - 10231
Benzonorcaradienes and benzonorcarenes are attractive scaffolds that occur in natural products as well as biologically active compounds. However, there is a... 
CP LIGANDS | BUCHNER REACTION | INSERTION | cyclopropane | COMPLEXES | ISOMERIZATION | CHEMISTRY, PHYSICAL | asymmetric catalysis | cyclization | REARRANGEMENT | ruthenium | REDUCTION | chiral cyclopentadienyl ligands
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2019, Volume 58, Issue 8, pp. 2514 - 2518
A chiral CpxRhIII catalyst system in situ generated from a CpxRhI(cod) precatalyst and bis(o‐toluoyl) peroxide as activating oxidant was developed for a C−H... 
chiral Cp ligands | ring opening | asymmetric catalysis | C−H activation | rhodium | Enantiomers | Catalysis | Transformation | Peroxide | Ethers | Dienes | Aromatic compounds
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2019, Volume 58, Issue 26, pp. 8902 - 8906
Chiral sulfoximines with stereogenic sulfur atoms are promising motifs in drug discovery. We report an efficient method to access chiral sulfoximines through a... 
kinetic resolution | chiral Cp ligands | sulfoximines | asymmetric catalysis | Rhodium | Sulfur compounds | Diazo compounds | Phenylalanine | Drug discovery | Catalysis | Enantiomers | Sulfur | Pharmacology | Kinases | Intermediates
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 02/2016, Volume 22, Issue 7, pp. 2270 - 2273
Chiral spirocyclic sultams are a valuable compound class in organic and medicinal chemistry. A rapid entry to this structural motif involves a [3+2] annulation... 
chiral Cp ligands | asymmetric catalysis | C−H activation | sultams | rhodium | Rhodium | Enantiomers | Catalysis | Organic chemistry | Chemical reactions | Carboxylic acids | Alkynes
Journal Article
Chemistry (Weinheim an der Bergstrasse, Germany), 02/2016, Volume 22, Issue 7, pp. 2270 - 2273
Chiral spirocyclic sultams are a valuable compound class in organic and medicinal chemistry. A rapid entry to this structural motif involves a [3+2] annulation... 
chiral Cp ligands | asymmetric catalysis | C−H activation | sultams | rhodium | Naphthalenesulfonates - chemistry | Hydrogen Bonding | Carboxylic Acids - chemistry | Ligands | Molecular Structure | Catalysis | Rhodium - chemistry | Spiro Compounds - chemistry
Journal Article
03/2019, ISBN 3527343644, 16
Rhodium(III) complexes bearing chiral cyclopentadienyl ligands have recently emerged as effective catalysts for enantioselective CH functionalization. In this... 
chiral Cp ligands | CH activation | asymmetric catalysis | rhodium
Book Chapter
APPLIED ORGANOMETALLIC CHEMISTRY, ISSN 0268-2605, 01/2014, Volume 28, Issue 1, pp. 38 - 43
Two new half-sandwich (5)-Cp*-rhodium(III) and (5)-Cp*-ruthenium(II) complexes have been prepared from corresponding bis(phosphino)amine ligands,... 
PHOSPHORUS-BASED LIGANDS | ASYMMETRIC TRANSFER HYDROGENATION | CHIRAL LIGANDS | transfer hydrogenation | POLYMERIZATION | bis(phosphino)amine | HYDRIDE | CHEMISTRY, INORGANIC & NUCLEAR | ruthenium | RUTHENIUM(II) CHEMISTRY | AMINOPHOSPHINE COMPLEXES | CHEMISTRY, APPLIED | PALLADIUM(II) | DERIVATIVES | CATALYSTS | rhodium
Journal Article
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