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chemistry, organic (24) 24
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Chemical Communications, ISSN 1359-7345, 2018, Volume 54, Issue 80, pp. 11292 - 11295
The bis(trifluoromethane)sulfonimide (Tf2NH) catalyzed intramolecular hydroamidation of terminal alkynes is reported. The combination of Et3SiH and Tf2NH... 
BRONSTED ACID | CHIRAL HOMOPROPARGYL SULFONAMIDES | ENANTIOSELECTIVE SYNTHESIS | NITROGEN-HETEROCYCLES | A-C | HYDROAMINATION | ALKYNES | EFFICIENT | CHEMISTRY, MULTIDISCIPLINARY | CYCLIZATION
Journal Article
Chemical Communications, ISSN 1359-7345, 2010, Volume 46, Issue 8, pp. 1275 - 1277
Isoindoline derivatives with high enantiomeric purity (up to 98% ee) have been accessed by formal double arylation of azomethines. 
SYSTEM | CATALYSIS | 1,3-DIPOLAR CYCLOADDITION | CHIRAL BRONSTED ACID | ENANTIOSELECTIVE ALPHA-ARYLATION | YLIDES | CHEMISTRY, MULTIDISCIPLINARY | STEREOSELECTIVE SYNTHESIS
Journal Article
Journal of Heterocyclic Chemistry, ISSN 0022-152X, 05/2007, Volume 44, Issue 3, pp. 575 - 590
Key intermediate in the synthesis of the title compounds 9a‐c and 10a‐c was the chiral α‐bromoimide 1 which has been prepared by radical bromination of the... 
N-ACYLIMINIUM IONS | ACID | CONFIGURATION | CHIRAL AUXILIARIES | CHEMISTRY, ORGANIC | RECEPTOR | AMIDOALKYLATION | ACETALS | PIPERIDINES | DERIVATIVES | BINDING
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2017, Volume 56, Issue 35, pp. 10451 - 10456
Journal Article
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 08/2017, Volume 56, Issue 35, pp. 10451 - 10456
The enantioselective N-alkylation of indole and its derivatives with aldimines is efficiently catalyzed by a zinc-ProPhenol dinuclear complex under mild... 
BRONSTED ACID | IMINES | COMPLEXES | asymmetric catalysis | CHIRAL PHOSPHORIC-ACID | CHEMISTRY, MULTIDISCIPLINARY | chiral isoindolines | N-alkylation | CYCLIC AMINALS | MARINE SPONGE | indoles | FRIEDEL-CRAFTS REACTION | zinc | DERIVATIVES | PRECURSORS | N,O-AMINALS
Journal Article
Tetrahedron, ISSN 0040-4020, 06/2019, Volume 75, Issue 24, pp. 3239 - 3247
An enantioselective palladium-catalyzed C(sp )-H carbamoylation for the preparation of chiral isoindolines was described for the first time. With chiral... 
Carbamoylation | Chiral phosphorus ligand | Isoindolines | Enantioselective | Palladium catalysis | ACTIVATION | ASYMMETRIC-SYNTHESIS | EFFICIENT SYNTHESES | MECHANISM | CHEMISTRY, ORGANIC | INTRAMOLECULAR ALKANE ARYLATION | CHIRAL MONOPHOSPHORUS LIGANDS | STEREOSELECTIVE-SYNTHESIS | C(SP)-H | BETA-LACTAMS | ACCESS | Palladium | Dichloropropane | Catalysis | Enantiomers | Chlorides
Journal Article
Synlett, ISSN 0936-5214, 12/2017, Volume 28, Issue 20, pp. 2901 - 2905
Abstract An N -benzyl pyrroloimidazolone derived from l -proline hydantoin undergoes asymmetric lithiation with n -BuLi/TMEDA in toluene to give products of... 
letter | benzylic | deuteration | imidazolone | chiral auxiliary | lithiation | diastereoselective | transmetalation | ISOINDOLINE-BORANE COMPLEX | ALKYLATION | CHEMISTRY, ORGANIC | ALPHA-LITHIATION | ASYMMETRIC DEPROTONATION | ORGANOLITHIUMS | ENANTIOSELECTIVE SUBSTITUTION-REACTIONS | (-)-SPARTEINE | AMINES | GENERATION | ELECTROPHILIC SUBSTITUTION
Journal Article
TETRAHEDRON LETTERS, ISSN 0040-4039, 08/1995, Volume 36, Issue 33, pp. 5877 - 5880
Metalation-alkylation of isoindoline 5 in the form of its chiral formamidine, 6 leads to C-2-dialkylated derivatives in high ee's. 
CHIRAL FORMAMIDINES | TETRAHYDROISOQUINOLINES | CHEMISTRY, ORGANIC
Journal Article
Phosphorus, Sulfur, and Silicon and the Related Elements, ISSN 1042-6507, 04/2013, Volume 188, Issue 4, pp. 331 - 339
Journal Article
E-Journal of Chemistry, ISSN 0973-4945, 2011, Volume 8, Issue 3, pp. 1417 - 1423
A new synthetic method for the preparation of high enantiopure (R)-2-((2-oxooxazolidin-5-yl)methyl)isoindoline-1,3-dione has been developed. The enantiopurity... 
Linezolid | Enantiomeric excess | Chiral HPLC | (R)-2-((2-Oxooxazolidin-5-yl)methyl)isoindoline-1,3-dione | Antibacterial agents | OXAZOLIDINONE CLASS | DUP-721 | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Organic Letters, ISSN 1523-7060, 08/2008, Volume 10, Issue 16, pp. 3527 - 3530
Lithiation of BF3-complexed dimethylaminoferrocene occurs exclusively ortho to the dimethylamino group in the cyclopentadienyl ring providing structurally... 
ENANTIOSELECTIVE SUBSTITUTION-REACTIONS | DEPROTONATION | ISOINDOLINE-BORANE COMPLEX | METALATION | ASYMMETRIC-SYNTHESIS | PLANAR CHIRALITY | TERTIARY-AMINES | CHEMISTRY, ORGANIC | AROMATIC-ALDEHYDES | DERIVATIVES | CHIRAL FERROCENE LIGANDS
Journal Article
Inorganica Chimica Acta, ISSN 0020-1693, 2009, Volume 362, Issue 4, pp. 1065 - 1070
α-Pinene was successfully employed as a chiral pool precursor for the preparation of a chiral bis(pyridylimino)isoindoline ligand, pinBPI. Simple palladium(II)... 
X-ray structure determination | Palladium | BAI ligands | Chiral ligands | Conformation | ZN(II) | REACTIVITY | STRUCTURAL-CHARACTERIZATION | NETWORKS | PD-II COMPLEX | CHEMISTRY, INORGANIC & NUCLEAR | METAL-ORGANIC FRAMEWORKS | BIS(2-PYRIDYLIMINO)ISOINDOLE BPI LIGANDS | SOLIDS | ISOINDOLINE PINCER LIGAND | COORDINATION POLYMERS
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 01/2003, Volume 68, Issue 2, pp. 378 - 386
Variously substituted linear enediynes phosphines oxides possessing the double bond at either the terminal or internal position and with the phosphine oxide... 
ONE-STEP CONSTRUCTION | ALLENEDIYNES | ASYMMETRIC-SYNTHESIS | NICKEL-CATALYZED <2+2+2>-COCYCLIZATION | CHIRAL POOL | FRAMEWORK | CHEMISTRY, ORGANIC | ISOQUINOLINE DERIVATIVES | CYCLOTRIMERIZATION | CYCLIZATION | ISOINDOLINE
Journal Article
Science China Chemistry, ISSN 1674-7291, 11/2019, Volume 62, Issue 11, pp. 1529 - 1536
The catalytic radical-initiated asymmetric 1,2-aminosilylation of alkene with a hydrosilane under Cu(I)/CPA cooperative catalysis has been developed. This... 
Chemistry | Chemistry/Food Science, general | Cu/chiral phosphoric acid | alkenes | asymmetric radical chemistry | aminosilylation | silyl radical
Journal Article