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Angewandte Chemie (International ed. in English), ISSN 1433-7851, 12/2017, Volume 56, Issue 52, pp. 16631 - 16635
The traceless Petasis borono-Mannich reaction of enals, sulfonylhydrazines, and allylboronates catalyzed by chiral biphenols results in an asymmetric reductive... 
organocatalysis | asymmetric synthesis | diazene | allylation | hydrazones
Journal Article
Zeitschrift für Kristallographie - New Crystal Structures, ISSN 1433-7266, 01/2018, Volume 233, Issue 1, pp. 153 - 154
S, monoclinic, (no. 14), = 19.436(3) Å, = 6.1396(6) Å, = 16.362(3) Å, = 108.100(16)°, = 1855.8(5) Å , = 4, ) = 0.0502, ) = 0.1224, = 100 K. 
1531206 | CRYSTALLOGRAPHY | STEREOSELECTIVE-SYNTHESIS | REDUCTION | MONOALKYL DIAZENES
Journal Article
by Liu, QQ and Luo, XX and Wei, SJ and Wang, YZ and Zhu, JX and Liu, Y and Quan, FL and Zhang, M and Xia, CC
TETRAHEDRON LETTERS, ISSN 0040-4039, 06/2019, Volume 60, Issue 26, pp. 1715 - 1719
A palladium-catalyzed direct C-X bond formation of azobenzenes with 1,3-dibromo-5,5-dimethylhydantoin or trichloro isocyanuric acid via C-H activation has been... 
(E)-1,2-Bis(2,6-dichloro-phenyl)diazene | C-H activation | RED-LIGHT | ACYLATION | PHOTOSWITCHES | (E)-1,2-Bis(2,6-dibromo-phenyl)diazene | CHEMISTRY, ORGANIC | AZOARENES | Azobenzenes
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 08/2014, Volume 55, Issue 33, pp. 4549 - 4552
Air-promoted coupling reaction of arylhydrazines and arylamines is developed for the selective synthesis of 2-aminobiaryls. This protocol provides a green,... 
2-Aminobiaryl | Arylhydrazine | Air oxidation | Radical reaction | OXIDATION | DIAZENES | BIARYL COMPOUNDS | CHEMISTRY, ORGANIC | PHENYLHYDRAZINE
Journal Article
Journal of Organic Chemistry, ISSN 0022-3263, 04/2018, Volume 83, Issue 7, pp. 3537 - 3546
A mild approach to diazenylation of active methylene compounds and N-heterocyclic compounds with arylhydrazine hydrochlorides in the presence of iodine under... 
OXIDATION | VISIBLE-LIGHT | DEHYDROGENATION | RADICAL ARYLATION | DIAZENES | AROMATIC AZO-COMPOUNDS | DRUG-DELIVERY | ANILINES | CHEMISTRY, ORGANIC | BOND-CLEAVAGE | AZOBENZENE PHOTOSWITCHES
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 04/2015, Volume 137, Issue 16, pp. 5292 - 5295
We report that a regioselective reductive transposition of primary allylic bromides is catalyzed by a biphilic organophosphorus (phosphetane) catalyst.... 
ORGANIC-SYNTHESIS | PHOSPHONIUM SALTS | PHOSPHINE CATALYSIS | WITTIG REACTION | LITHIUM ALUMINUM-HYDRIDE | ORGANOFLUOROPHOSPHONIUM SALTS | STEREOSELECTIVE CONSTRUCTION | BAYLIS-HILLMAN ACETATES | MONOALKYL DIAZENES | FORMATE REDUCTION | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
NATURE CHEMISTRY, ISSN 1755-4330, 07/2010, Volume 2, Issue 7, pp. 558 - 565
The biological reduction of N-2 to give NH3 may occur by one of two predominant pathways in which nitrogenous NxHy intermediates, including hydrazine (N2H4),... 
NITROGENASE | FEMO COFACTOR | REDUCTION | RAY CRYSTAL-STRUCTURES | COMPLEXES | DINITROGEN | REACTIVITY | DIAZENE | METAL | CHEMISTRY, MULTIDISCIPLINARY | TRIS(PHOSPHINO)SILYL LIGANDS
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 06/2015, Volume 56, Issue 23, pp. 3527 - 3530
Using a Kukhtin–Ramirez-like condensation employing hexamethylphosphorous triamide, the addition of 1,2-dicarbonyls to diazenes affords direct access to -acyl... 
Hydrazones | Umpolung | Diaoxaphospholene | Phosphine | Diazenes | PHOSPHORUS | DESIGN | QUINONES | CHEMISTRY, ORGANIC | POTENT | ACYLHYDRAZONES | ALPHA-DIKETONES | DERIVATIVES | Synthesis | Organic compounds
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 2017, Volume 15, Issue 18, pp. 3917 - 3923
The SNAr reaction of 2-chloroazulene derivative 1 with ethoxycarbonyl groups at the 1,3-positions of the azulene ring with several amines afforded the... 
SOLAR-CELLS | DIAZENES | 2 AZULEN-1-YL MOIETIES | AGGREGATION-INDUCED EMISSION | BEHAVIOR | ELECTRONIC-SPECTRA | CHEMISTRY, ORGANIC | BASICITY | MEMORY DEVICES | DERIVATIVES | CATALYZED DIRECT ARYLATION
Journal Article
Chemical Communications, ISSN 1359-7345, 2016, Volume 52, Issue 5, pp. 958 - 961
We report highly chemo-and regioselective reductive transpositions of methyl carbonates to furnish olefin products with complementary regioselectivity to that... 
ROUTE | CYCLOADDITION | AMINATION | DEOXYGENATION | PROPARGYLIC ALCOHOLS | MONOALKYL DIAZENES | SINGLE-STEP | ALLENES | FORMATE REDUCTION | CHEMISTRY, MULTIDISCIPLINARY | EFFICIENT METHOD
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 10/2019, Volume 899
Aside from alkene cross metathesis, involving two different alkene units, cross metathesis reactions of two functionally different unsaturated units -... 
Imine preparation | Azo compounds | Ruthenium-imido complex | Ruthenium carbene-complex | Alkene-diazene cross metathesis
Journal Article
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 09/2018, Volume 57, Issue 38, pp. 12494 - 12498
An organocatalytic oxidation platform that capitalizes on the capacity of hydrazines to undergo rapid autoxidation to diazenes is described. Commercially... 
ORGANIC-MOLECULES | diazenes | CONVENIENT OXIDATION | oxidation | DECOMPOSITION | CARBONYL-COMPOUNDS | AROMATIC-ALDEHYDES | benzo[c]cinnoline | CHEMISTRY, MULTIDISCIPLINARY | organocatalysis | KETONES | Kornblum oxidation | AMINES | ALIPHATIC AZO-COMPOUNDS | AEROBIC OXIDATION | BENZYL HALIDES
Journal Article
Chinese Journal of Organic Chemistry, ISSN 0253-2786, 06/2017, Volume 37, Issue 6, pp. 1407 - 1411
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2018, Volume 57, Issue 38, pp. 12494 - 12498
An organocatalytic oxidation platform that capitalizes on the capacity of hydrazines to undergo rapid autoxidation to diazenes is described. Commercially... 
organocatalysis | oxidation | Kornblum oxidation | diazenes | benzo[c]cinnoline | Hydrolysis | Oxidation-reduction reaction | Catalysis | Aldehydes | Halides | Autoxidation | Hydrazines | Computer applications | Oxidation | Reoxidation | Hydrazine | Substrates
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 09/2016, Volume 57, Issue 36, pp. 4066 - 4069
Azobenzenes reacted with 3-ethoxycyclobutanoes to give 2,3-dihydro-pyridazin-4(1 )-ones by using EtAlCl as a Lewis acid. Thus, ring cleavage of... 
Cycloaddition | Hydropyridazine | Cyclobutanone | Regioselectivity | Azobenzene | ORGANIC-SYNTHESIS | ROUTE | DIAZENES | ACID | REACTIVITY | CHEMISTRY, ORGANIC | CLEAVAGE | CYCLOBUTANE DERIVATIVES | RING | DIELS-ALDER REACTION | Azo compounds | Surface active agents
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 04/2012, Volume 134, Issue 13, pp. 5782 - 5785
A one-pot synthesis of allenes by the 2-nitrobenzenesulfonylhydrazide-mediated coupling of hydroxyaldehydes or ketones with alkynyl trifluoroborate salts is... 
BORONIC ACIDS | CATALYZED CYCLOISOMERIZATION | MANNICH REACTION | ALDEHYDE TOSYLHYDRAZONES | CHIRAL BIPHENOLS | CARBON-CARBON | STEREOSELECTIVE-SYNTHESIS | N-ALLYLHYDRAZONES | SIGMATROPIC REARRANGEMENT | MONOALKYL DIAZENES | CHEMISTRY, MULTIDISCIPLINARY | Ketones | Analysis | Chemical bonds | Chemical properties | Aldehydes | Borates | Decomposition (Chemistry)
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 2016, Volume 14, Issue 10, pp. 2828 - 2832
An efficient multicatalytic strategy for the construction of nitrogen-containing heterocycles has been reported. The powerful combination of organic and metal... 
TRANSITION-METAL CATALYSIS | ASYMMETRIC-SYNTHESIS | ACID | DIAZENES | HETEROCYCLES | DIELS-ALDER REACTION | CHEMISTRY, ORGANIC | HYDRAZINES | ENAMINE CATALYSIS | PYRIDAZINES | ORGANOCATALYTIC ROUTE
Journal Article
Revista de Chimie, ISSN 0034-7752, 07/2015, Volume 66, Issue 7, pp. 1074 - 1082
Several new azulenyl diazenes containing furazans or furoxans heterocycles were prepared. Despite both the diazotation and azo coupling reactions were... 
Furazans | Furoxans | Azulene | Azo coupling | Diazenes | azulene | furazans | DYES | diazenes | NITROFUROXANS | AZULEN-1-YL-BENZOTHIAZOL-2-YL DIAZENES | SALTS | CHEMISTRY, MULTIDISCIPLINARY | AZO CHROMOPHORES | ENGINEERING, CHEMICAL | furoxans | azo coupling | PHOTORESPONSIVE BEHAVIOR
Journal Article
Journal of Organic Chemistry, ISSN 0022-3263, 12/2012, Volume 77, Issue 23, pp. 10699 - 10706
Journal Article
Angewandte Chemie - International Edition, ISSN 1433-7851, 04/2011, Volume 50, Issue 15, pp. 3446 - 3449
Journal Article
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