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1. Full Text [RhIII(Cp)]-Catalyzed Cascade Arylation and Chlorination of α‑Diazocarbonyl Compounds with Arylboronic Acids and N‑Chlorosuccinimide for Facile Synthesis of α‑Aryl-α-chloro Carbonyl Compounds
by Ng, Fo-Ning and Lau, Yan-Fung and Zhou, Zhongyuan and Yu, Wing-Yiu
Organic Letters, ISSN 1523-7060, 04/2015, Volume 17, Issue 7, pp. 1676 - 1679
A Rh­(III)-catalyzed cascade arylation and chlorination of α-diazocarbonyl compounds with arylboronic acids and N-chlorosuccinimide was achieved. The reaction... 
PALLADIUM-CATALYZED INSERTION | RHODIUM | CROSS-COUPLING REACTION | CHEMISTRY, ORGANIC | RADICAL CYCLIZATION REACTIONS | DIAZO-COMPOUNDS | STEREOSELECTIVE-SYNTHESIS | CARBENE MIGRATORY INSERTION | H BOND FUNCTIONALIZATION | VINYL HALIDES | DIAZOESTERS | Azo Compounds - chemistry | Halogenation | Ketones - chemistry | Azo Compounds - chemical synthesis | Organometallic Compounds - chemistry | Boronic Acids - chemistry | Molecular Structure | Catalysis | Rhodium - chemistry | Succinimides - chemistry
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2. Full Text Catalyst‐Dependent Chemoselective Formal Insertion of Diazo Compounds into C−C or C−H Bonds of 1,3‐Dicarbonyl Compounds
by Liu, Zhaohong and Sivaguru, Paramasivam and Zanoni, Giuseppe and Anderson, Edward A and Bi, Xihe
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2018, Volume 57, Issue 29, pp. 8927 - 8931
A catalyst‐dependent chemoselective one‐carbon insertion of diazo compounds into the C−C or C−H bonds of 1,3‐dicarbonyl species is reported. In the presence of... 
silver catalysis | 1,3-dicarbonyl compounds | diazo compounds | C−H insertion | C−C insertion | 3-dicarbonyl compounds | ENANTIOSELECTIVE SYNTHESIS | C-C insertion | BETA-KETO-ESTERS | QUATERNARY CARBON STEREOCENTERS | CHEMISTRY, MULTIDISCIPLINARY | N-TOSYLHYDRAZONES | FUNCTIONALIZATION | C-H insertion | TRANSITION-METAL | CARBENE INSERTION | ALPHA-DIAZOESTERS | ASYMMETRIC RING-EXPANSION | DERIVATIVES | Diazo compounds | Catalysis | Catalysts | Quaternary | Scandium | Chemical bonds | Insertion | Carbon | Alkylation | Substrates
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3. Aromatic diazo compounds
by Saunders, K. H. (Kenneth Herbert) and Allen, R. L. M. (Reginald Lancelot Mountford)
1985, 3rd ed. --, ISBN 0713134992, xxv, 899
Azides | Diazo compounds
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4. Full Text Gold-catalyzed transformations of α-diazocarbonyl compounds: selectivity and diversity
by Liu, Lu and Zhang, Junliang
Chemical Society Reviews, ISSN 0306-0012, 2/2016, Volume 45, Issue 3, pp. 56 - 516
Metal carbenes, generated from the decomposition of diazo compounds by transition-metals, have a broad range of applications in organic synthesis. The progress... 
CYCLOADDITION REACTIONS | INSERTION | HETEROCYCLIC CARBENE | CARBENE-TRANSFER-REACTIONS | COMPLEXES | CYCLOPROPANATION | H BOND FUNCTIONALIZATION | ALKYNES | VINYL DIAZO DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | ETHYL DIAZOACETATE | Silver | Synthesis | Insertion | Chemical reactions | Transformations | Iron | Copper | Carbenes
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5. Full Text Cobalt(III)‐Catalyzed Alkylation of Primary C(sp3)–H Bonds with Diazo Compounds
by Yan, Sheng‐Yi and Ling, Peng‐Xiang and Shi, Bing‐Feng
Advanced Synthesis & Catalysis, ISSN 1615-4150, 09/2017, Volume 359, Issue 17, pp. 2912 - 2917
Chelation‐assisted C(sp2)–H metalation/carbenoid insertion has been well investigated. However, the analogous carbene functionalization of C(sp3)–H bonds... 
carbenoid insertion | alkylation | cobalt | diazo compounds | C(sp3)–H activation | H activation | C(sp | ALPHA-DIAZOCARBONYL COMPOUNDS | CHEMISTRY, ORGANIC | CARBENE MIGRATORY INSERTION | N-OXIDES | C-H ACTIVATION | FACILE SYNTHESIS | MILD CONDITIONS | UNPROTECTED INDOLES | METAL CARBENE | C(sp)-H activation | COBALT CATALYSIS | RH(III)-CATALYZED SYNTHESIS | CHEMISTRY, APPLIED | Antibiotics | Chemical bonds | Chelation | Insertion | Cobalt compounds | Functional groups | Alkylation
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6. Full Text Cycloaddition reactions of enoldiazo compounds
by Cheng, Qing-Qing and Deng, Yongming and Lankelma, Marianne and Doyle, Michael P
Chemical Society Reviews, ISSN 0306-0012, 2017, Volume 46, Issue 17, pp. 5425 - 5443
Enoldiazo esters and amides have proven to be versatile reagents for cycloaddition reactions that allow highly efficient construction of various carbocycles... 
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7. Full Text Cycloaddition reactions of enoldiazo compounds
by Cheng, Qing-Qing and Deng, Yongming and Lankelma, Marianne and Doyle, Michael P
Chemical Society Reviews, ISSN 0306-0012, 8/2017, Volume 46, Issue 17, pp. 5425 - 5443
Enoldiazo esters and amides have proven to be versatile reagents for cycloaddition reactions that allow highly efficient construction of various carbocycles... 
METAL CARBENE TRANSFORMATIONS | ALPHA-DIAZOCARBONYL COMPOUNDS | ASYMMETRIC-SYNTHESIS | CATALYZED 4+3 CYCLOADDITION | AROMATIC AZOMETHINE IMINES | DONOR-ACCEPTOR CYCLOPROPENES | RHODIUM-STABILIZED VINYLCARBENOIDS | DIAZO-COMPOUNDS | C-H ACTIVATION | CHEMISTRY, MULTIDISCIPLINARY | PROTECTED ENOL DIAZOACETATES
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8. Full Text Reaction of Diazo Compounds with Organoboron Compounds
by Li, Huan and Zhang, Yan and Wang, Jianbo
Synthesis, ISSN 0039-7881, 11/2013, Volume 45, Issue 22, pp. 3090 - 3098
Abstract The transition-metal-free reactions of diazo compounds with organoboron compounds are reviewed. This type of reaction provides an alternative approach... 
short review | hydrazine | transition-metal-free reactions | diazo compounds | boron | 1,2-migration | ALPHA-DIAZOCARBONYL COMPOUNDS | ASYMMETRIC ALLYLBORATION | REGIOSPECIFIC SYNTHESIS | TOSYLHYDRAZONES | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | ETHYL DIAZOACETATE | KETONES | METAL-CATALYZED REACTIONS | ESTERS | REACTIONS INVOLVING BORON | 2-migration
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9. Full Text Enantiodivergent Desymmetrization in the Rhodium(III)‐Catalyzed Annulation of Sulfoximines with Diazo Compounds
by Shen, Bingxue and Wan, Boshun and Li, Xingwei
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2018, Volume 57, Issue 47, pp. 15534 - 15538
RhIII‐ and IrIII‐catalyzed asymmetric C−H functionalization reactions of arenes have relied on the employment of chiral RhIII/IrIII cyclopentadienyl catalysts,... 
sulfoximes | desymmetrization | enantiodivergence | asymmetric C−H activation | rhodium | CATALYSIS | ASYMMETRIC-SYNTHESIS | N BOND | 2+2+2 CYCLOADDITION | COMBINATION | C-H ACTIVATION | CHEMISTRY, MULTIDISCIPLINARY | FUNCTIONALIZATION | LIGANDS | asymmetric C-H activation | Diazo compounds | Rhodium | Enantiomers | Organic acids | Coupling (molecular) | Organic chemistry | Catalysts | Aromatic compounds | Chemical reactions | Carboxylic acids | Catalysis
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10. Full Text Cobalt(III)‐Catalyzed Directed CH Coupling with Diazo Compounds: Straightforward Access towards Extended π‐Systems
by Zhao, Dongbing and Kim, Ju Hyun and Stegemann, Linda and Strassert, Cristian A and Glorius, Frank
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2015, Volume 54, Issue 15, pp. 4508 - 4511
The first highly efficient and scalable cobalt‐catalyzed directed CH functionalization with carbene precursors is presented. This methodology provides a... 
carbenes | CH activation | cobalt | π‐systems | heterocycles | Heterocycles | π-systems | C-H activation | Carbenes | Cobalt
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11. Full Text Redox‐Neutral Rhodium‐Catalyzed CH Functionalization of Arylamine N‐Oxides with Diazo Compounds: Primary C(sp3)H/C(sp2)H Activation and Oxygen‐Atom Transfer
by Zhou, Bing and Chen, Zhaoqiang and Yang, Yaxi and Ai, Wen and Tang, Huanyu and Wu, Yunxiang and Zhu, Weiliang and Li, Yuanchao
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2015, Volume 54, Issue 41, pp. 12121 - 12126
An unprecedented rhodium(III)‐catalyzed regioselective redox‐neutral annulation reaction of 1‐naphthylamine N‐oxides with diazo compounds was developed to... 
density functional calculations | CH activation | heterocycles | nitrogen oxides | rhodium | C-H activation | ROOM-TEMPERATURE | DIRECT ARYLATION | O HYDROGEN-BONDS | ALKYNES | CLEAVAGE | CHEMISTRY, MULTIDISCIPLINARY | RH(III)-CATALYZED SYNTHESIS | DERIVATIVES | ALKENYLATION | CARBENOID FUNCTIONALIZATION | Mandelic Acids - chemical synthesis | Oxidation-Reduction | Nitrogen Oxides - chemistry | 1-Naphthylamine - chemistry | Indoles - chemical synthesis | Models, Molecular | Hydrogen - chemistry | Azo Compounds - chemistry | Mandelic Acids - chemistry | Amination | Malonates - chemistry | Aniline Compounds - chemistry | Catalysis | Indoles - chemistry | Rhodium - chemistry | Oxidants | Mathematical analysis | Oxidizing agents | Byproducts | Chemical reactions | Strategy | Derivatives | Bonding
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12. Full Text Gold-catalyzed transformations of α-diazocarbonyl compounds: selectivity and diversity
by Liu, Lu and Zhang, Junliang
Chemical Society reviews, ISSN 0306-0012, 02/2016, Volume 45, Issue 3, pp. 506 - 516
Metal carbenes, generated from the decomposition of diazo compounds by transition-metals, have a broad range of applications in organic synthesis. The progress... 
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13. Full Text Diastereoselective Three-Component Synthesis of β‑Amino Carbonyl Compounds Using Diazo Compounds, Boranes, and Acyl Imines under Catalyst-Free Conditions
by Luan, Yi and Yu, Jie and Zhang, Xiaowei and Schaus, Scott E and Wang, Ge
The Journal of Organic Chemistry, ISSN 0022-3263, 05/2014, Volume 79, Issue 10, pp. 4694 - 4698
Diazo compounds, boranes, and acyl imines undergo a three-component Mannich condensation reaction under catalyst-free conditions to give the anti β-amino... 
BORONIC ACIDS | ALPHA-DIAZOCARBONYL COMPOUNDS | ASYMMETRIC ALLYLBORATION | REGIOSPECIFIC SYNTHESIS | CF3-SUBSTITUTED BORANES | CHIRAL BIPHENOLS | ESTERS | CHEMISTRY, ORGANIC | ENANTIOSELECTIVE ADDITION | ETHYL DIAZOACETATE | MULTICOMPONENT REACTION | Azo Compounds - chemistry | Stereoisomerism | Boranes - chemistry | Imines - chemistry | Amino Acids - chemistry | Molecular Structure | Amino Acids - chemical synthesis | Catalysis | Diazo compounds | Borane | Chemical properties | Research | Note
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14. Full Text Ruthenium(II)‐Catalyzed C−H Activation of Imidamides and Divergent Couplings with Diazo Compounds: Substrate‐Controlled Synthesis of Indoles and 3H‐Indoles
by Li, Yunyun and Qi, Zisong and Wang, He and Yang, Xifa and Li, Xingwei
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2016, Volume 55, Issue 39, pp. 11877 - 11881
Indoles are an important structural motif that is commonly found in biologically active molecules. In this work, conditions for divergent couplings between... 
ruthenium | transition-metal catalysis | indoles | C−H activation | diazo compounds | ROOM-TEMPERATURE | CATALYZED REACTIONS | ONE-POT | BOND FUNCTIONALIZATIONS | N-OXIDES | CHEMISTRY, MULTIDISCIPLINARY | DIRECTING GROUPS | C-H activation | FUSED INDOLES | RH(III)-CATALYZED SYNTHESIS | ALPHA-DIAZOACETAMIDES | CYCLIZATION | Diazo compounds | Ruthenium | Catalysis
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