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boron (49) 49
chemistry, multidisciplinary (46) 46
diborene (40) 40
reactivity (31) 31
bor (28) 28
chemistry (26) 26
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chemistry, inorganic & nuclear (9) 9
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Chemistry : a European journal, ISSN 0947-6539, 2016, Volume 22, Issue 48, pp. 17169 - 17172
Room temperature hydrogenation of an SIDep‐stabilized diboryne (SIDep=1,3‐bis(diethylphenyl)‐4,5‐dihydroimidazol‐2‐ylidene) and a cAAC‐supported diboracumulene... 
carbenes | main-group chemistry | reaction mechanism | hydrogenation | diborenes | ACTIVATION | HYDROBORATION | SINGLE | ANALOGS | COMPOUND | REACTIVITY | H-2 | CHEMISTRY, MULTIDISCIPLINARY | NEUTRAL DIBORENE | BORON TRIPLE BOND | Hydrogenation | Synthesis (chemistry) | Boron | Catalysts | Bridging | Mathematical analysis | Chemical bonds | Hydrides
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 05/2018, Volume 57, Issue 20, pp. 5947 - 5951
The room‐temperature, ambient‐pressure reactions of CO2 with two species containing boron–boron multiple bonds led to the incorporation of either one or two... 
carbon dioxide | diborynes | CO2 fixation | boron | diborenes | fixation | SINGLE | DIOXIDE | REACTIVITY | TRIPLE BOND | FRUSTRATED LEWIS PAIRS | DIBORENE | CHEMISTRY, MULTIDISCIPLINARY | CARBON-MONOXIDE | CHEMISTRY | NITROGEN | OXIDES | Carbon dioxide | Boron | Cycloaddition | Reaction mechanisms | Molecular chains | Structural analysis
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2015, Volume 54, Issue 14, pp. 4362 - 4366
A number of unprecedented photophysical phenomena were observed in the study of luminescent π‐diborene complexes of Cu and Ag. These observations included... 
intersystem crossing | coinage metals | fluorescence | boron | diborenes
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2014, Volume 53, Issue 35, pp. 9280 - 9283
An isolable phenylborylene species supported by two oxazol‐2‐ylidene ligands was synthesized and structurally characterized. Computational studies revealed the... 
borylenes | carbenes | reactive species | boron | nucleophiles | FORM | DIBORENES | ANIONIC DIMETALLOBORYLENE COMPLEX | BORANES | CHEMISTRY, MULTIDISCIPLINARY | BORYLLITHIUM | BULKY | TRANSITION-METAL BORYL | CHEMISTRY | ALKYL AMINO CARBENES | GENERATION | Chemical tests and reagents | Chromium | Boron | Conjugates | Computation | Ligands | Nucleophiles | Adducts | Fragmentation
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2014, Volume 53, Issue 28, pp. 7360 - 7363
Utilizing a cyclic (alkyl)(amino)carbene (CAAC) as a ligand, neutral CAAC‐stabilized radicals containing a boryl functionality could be prepared by reduction... 
carbenes | structure elucidation | radicals | reduction | boron | ELECTRON SIGMA-BOND | ANION | BORYL RADICALS | DIBORENES | REACTIVITY | COORDINATION | BORANES | CHEMISTRY, MULTIDISCIPLINARY | REDUCTIONS | ALKYL AMINO CARBENES | GENERATION | Reduction | Boron | Mathematical analysis | X-rays | Inert | Derivatives | Density | Radicals | Adducts
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 03/2014, Volume 53, Issue 12, pp. 3241 - 3244
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2014, Volume 53, Issue 12, pp. 3241 - 3244
Synthetic access to electron‐precise boron chains is hampered by the preferential formation of nonclassical structures. The few existing strategies for this... 
oxygen heterocycles | polyboranes | hydroboration | diborenes | sulfur heterocycles | METAL-PROMOTED REACTIONS | COMPLEX | COMPOUND | COORDINATION | BORANE | CHEMISTRY, MULTIDISCIPLINARY | DIBORANE | TRANSITION-METAL | BORON HYDRIDES | CHEMISTRY | Boron | Hydroboration | Synthesis | Coupling agents | Catalysts | Strategy | Reducing agents | Catalysis
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2017, Volume 56, Issue 45, pp. 14287 - 14292
Under a CO atmosphere, the dihydrodiborene [(cAAC)HB=BH(cAAC)] underwent coordination of CO concomitant with reversible hydrogen migration from boron to the... 
insertion | cyclic (alkyl)(amino)carbenes | ring expansion | diborenes | CO activation | CYCLOOCTAPYRROLES | MOLECULAR KNOTS | CONFORMATION | CHEMISTRY, MULTIDISCIPLINARY | AROMATICITY | N-CONFUSED PORPHYRIN | LUMINESCENT | SUBSTITUTED EXPANDED PORPHYRINS | CHEMISTRY | METAL-COMPLEX | CHIRALITY | Hydrogen | Insertion | Cleavage | Boron | Carbon monoxide | Migration | Alkynes
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2015, Volume 54, Issue 15, pp. 4469 - 4473
The reaction of the bisboracumulene (CAAC)2B2 (CAAC=1‐(2,6‐diisopropylphenyl)‐3,3,5,5‐tetramethylpyrrolidin‐2‐ylidene) with excess tert‐butylisocyanide... 
main‐group elements | multiple bonds | thermolysis | boron | diborenes | main-group elements | CARBENE | COMPLEXES | REACTIVITY | CHEMISTRY, MULTIDISCIPLINARY | MOLECULES | ISOCYANIDE | RADICALS | STABLE METHYLENEBORANES | PAIR | Telomerase | Ligands | Complexation | Boron | Electrochemical analysis | Heating | Electronics | Voltammetry | Formations | Adducts
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2017, Volume 56, Issue 33, pp. 9829 - 9832
A zwitterionic boraalkenyl boronium 3 was synthesized by reduction of cyclic (alkyl)(amino)carbene (cAAC) and trimethylphosphine (PMe3)‐coordinated... 
allenes | multiple bonds | boron | isoelectronic analogs | diborenes | PHOSPHORUS MULTIPLE BONDS | COMPLEXES | REACTIVITY | BORENIUM | CHEMISTRY, MULTIDISCIPLINARY | DIBORANE | BASE | METAL CARBENE TRANSFORMATIONS | ELEMENT | SINGLET CARBENES | BORON TRIPLE BOND | Surface active agents | Reduction | Diffraction | Computer applications | X-ray diffraction | Chemical bonds | Cleavage | Crystal structure
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 01/2017, Volume 56, Issue 3, pp. 889 - 892
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 2018, Volume 24, Issue 1, pp. 266 - 273
A series of NHC‐supported 1,2‐dithienyldiborenes was synthesized from the corresponding (dihalo)thienylborane NHC precursors. NMR and UV/Vis spectroscopic... 
spectroscopy | boron | diborenes | electron donors | N-heterocyclic carbenes | INSERTION | AB-INITIO | COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY | POTENTIAL CURVES | BORON MULTIPLE BONDS | CHALCOGENS | LIGANDS | BORYLENE | GENERATION | Coplanarity | Stability | Nuclear magnetic resonance--NMR | Crystallography | Destabilization | Electrons
Journal Article