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difluoroalkylation (125) 125
chemistry, organic (105) 105
chemistry, multidisciplinary (59) 59
alkenes (58) 58
fluorine (55) 55
trifluoromethylation (51) 51
catalysis (39) 39
difluoromethylation (39) 39
photoredox catalysis (37) 37
aryl boronic acids (36) 36
derivatives (30) 30
functionalized difluoromethyl bromides (26) 26
c-h difluoroalkylation (25) 25
hydrazones (25) 25
palladium (24) 24
medicinal chemistry (22) 22
cyclization (21) 21
aldehydes (20) 20
copper (20) 20
alkynes (19) 19
heteroarenes (19) 19
radicals (19) 19
access (18) 18
carboxylic-acids (18) 18
chemistry, applied (18) 18
fluorination (18) 18
light photoredox catalysis (18) 18
alpha,beta-unsaturated carboxylic-acids (17) 17
arylboronic acids (17) 17
ethyl bromodifluoroacetate (16) 16
unactivated alkenes (15) 15
functional groups (14) 14
ketones (14) 14
reagents (14) 14
chemistry (13) 13
fluoroalkylation (13) 13
n,n-dialkylhydrazones (13) 13
perfluoroalkylation (13) 13
arenes (12) 12
inhibitors (12) 12
iodides (12) 12
photocatalysis (12) 12
acids (11) 11
arylation (11) 11
bromides (11) 11
chemical synthesis (11) 11
copper-mediated difluoromethylation (11) 11
functionalization (11) 11
halides (11) 11
nickel (11) 11
olefins (11) 11
organic chemistry (11) 11
substrates (11) 11
visible-light (11) 11
aryl (10) 10
carbonyl-compounds (10) 10
synthesis (10) 10
alkylation (9) 9
c-h functionalization (9) 9
copper-catalyzed trifluoromethylation (9) 9
difluoroacetylation (9) 9
heterocycles (9) 9
metal-free (9) 9
phosphonates (9) 9
synthetic methods (9) 9
transfer radical-addition (9) 9
aromatic compounds (8) 8
catalyzed difluoroalkylation (8) 8
fluor (8) 8
functional-group (8) 8
funktionelle gruppe (8) 8
isocyanides (8) 8
decarboxylative difluoroalkylation (7) 7
index medicus (7) 7
light (7) 7
organic-synthesis (7) 7
oxidative trifluoromethylation (7) 7
phenanthridine derivatives (7) 7
photoredox (7) 7
reaction-condition (7) 7
reaktionsbedingung (7) 7
selective difluoroalkylation (7) 7
alkene (6) 6
building-blocks (6) 6
chemistry, physical (6) 6
cross-coupling (6) 6
cyclisation (6) 6
efficient (6) 6
fluoroalkylation reactions (6) 6
light-radiation (6) 6
monofluoroalkylation (6) 6
palladium-catalyzed difluoroalkylation (6) 6
pharmaceuticals (6) 6
photokatalyse (6) 6
radical reactions (6) 6
radical-addition (6) 6
regioselectivity (6) 6
sichtbares licht (6) 6
terminal alkynes (6) 6
visible light (6) 6
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Acta Chimica Sinica, ISSN 0567-7351, 02/2015, Volume 73, Issue 2, pp. 90 - 115
Journal Article
Accounts of Chemical Research, ISSN 0001-4842, 10/2016, Volume 49, Issue 10, pp. 2284 - 2294
Owing to their unique biological, physical, and chemical properties, fluoroalkylated organic substances have attracted significant attention from researchers... 
ALKENES | HETEROARENES | HETEROCYCLES | HYDROTRIFLUOROMETHYLATION | PHOTOCATALYSIS | COMPLEXES | FLUORINE | ALKYNES | DIFLUOROALKYLATION | CHEMISTRY, MULTIDISCIPLINARY | TRIFLUOROMETHYLATION
Journal Article
Organic Letters, ISSN 1523-7060, 06/2019, Volume 21, Issue 12, pp. 4745 - 4749
A metal-free photocatalytic protocol for efficient construction of difluoro-containing dibenzazepines is developed. The transformation is redox-neutral and... 
CHEMISTRY, ORGANIC | CATALYSIS | DESIGN | DIFLUOROALKYLATION | RADICAL REACTIONS
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 2018, Volume 16, Issue 21, pp. 3876 - 3880
A Cu-catalyzed oxidation of alcohols triggered by the radical difluoroalkylation of alkenes has been developed, providing facile access to a series of... 
ALPHA,BETA-UNSATURATED CARBOXYLIC-ACIDS | ALLYLIC ALCOHOLS | CYANO MIGRATION | SELECTIVE DIFLUOROALKYLATION | BOND FUNCTIONALIZATION | CHEMISTRY, ORGANIC | DECARBOXYLATIVE DIFLUOROALKYLATION | ANTI-MARKOVNIKOV HYDROFUNCTIONALIZATION | MIGRATION STRATEGY | PHOTOREDOX CATALYSIS | UNACTIVATED ALKENES
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2017, Volume 56, Issue 7, pp. 1898 - 1902
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 12/2018, Volume 59, Issue 51, pp. 4449 - 4453
The difluoroalkylation of unactivated benzo[d]isoxazoles with ethyl difluorobromoacetate by visible-light photoredox catalysis via direct and regioselective... 
Benzo[d]isoxazoles | Difluoroalkylation | Visible-light photocatalysis | Site-selectivity | DESIGN | ARENES | CHEMISTRY, ORGANIC | BENZISOXAZOLE | ALKENES | CARBONYLATION | CASCADE DIFLUOROALKYLATION | FLUORINE | DERIVATIVES | CYCLIZATION | ACCESS | Catalysis
Journal Article
Organic Letters, ISSN 1523-7060, 02/2019, Volume 21, Issue 3, pp. 671 - 674
A nickel-catalyzed defluorination of alpha-trifluoromethylated allyl/propargyl carbonates using bis(pinacolato)-diboron (B(2)pin(2)) as a reactant is... 
CHEMISTRY, ORGANIC | FLUORINE | DIFLUOROALKYLATION | ALKYNES | COUPLING REACTIONS | F BOND ACTIVATION
Journal Article
Nature Communications, ISSN 2041-1723, 03/2017, Volume 8, Issue 1, p. 14841
Although great success has been achieved in asymmetric fluoroalkylation reactions via nucleophilic or electrophilic processes, the development of asymmetric... 
BRONSTED ACID | VISIBLE-LIGHT | PALLADIUM | DIFLUOROMETHYLATION | MULTIDISCIPLINARY SCIENCES | ARYLATION | FUNCTIONAL-GROUPS | COPPER | STEREOSELECTIVE-SYNTHESIS | DIFLUOROALKYLATION | TRIFLUOROMETHYLTHIOLATION REACTIONS
Journal Article
Advanced Synthesis and Catalysis, ISSN 1615-4150, 2019, Volume 361, Issue 12, pp. 2945 - 2950
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 12/2018, Volume 59, Issue 51, pp. 4449 - 4453
The difluoroalkylation of unactivated benzo[ ]isoxazoles with ethyl difluorobromoacetate by visible-light photoredox catalysis via direct and regioselective C... 
Site-selectivity | Benzo[d]isoxazoles | Difluoroalkylation | Visible-light photocatalysis
Journal Article
Organic Letters, ISSN 1523-7060, 02/2017, Volume 19, Issue 4, pp. 938 - 941
The first direct α-arylation of aldehyde-derived N,N-dialkylhydrazones with electron deficient aryl and heteroaryl cyanides under visible-light photoredox... 
HYDRAZONES | CHEMISTRY, ORGANIC | AGENTS | INHIBITORS | DIFLUOROALKYLATION | DERIVATIVES | C-H BONDS
Journal Article
Accounts of Chemical Research, ISSN 0001-4842, 09/2018, Volume 51, Issue 9, pp. 2264 - 2278
Conspectus Difluoroalkylated compounds play a remarkably important role in life and materials sciences because of the unique characteristics of the... 
DIRECT FLUOROALKYLATION | PALLADIUM-CATALYZED DIFLUOROALKYLATION | ETHYL BROMODIFLUOROACETATE | ARYL BORONIC ACIDS | DIFLUOROMETHYLATED ARENES | FACILE ACCESS | BROMOZINC-DIFLUOROPHOSPHONATE | REDUCTIVE ELIMINATION | AROMATIC-COMPOUNDS | CHEMISTRY, MULTIDISCIPLINARY | ARYLBORONIC ACIDS
Journal Article
Chemical Communications, ISSN 1359-7345, 2016, Volume 52, Issue 8, pp. 1598 - 1601
A mild, versatile and efficient method for the silver(I)-catalyzed oxidative decarboxylative gem-difluoromethylenation has been developed. The radical cascade... 
ARYL BORONIC ACIDS | PHENANTHRIDINE DERIVATIVES | DIFLUOROMETHYL | PHOTOREDOX | ISOCYANIDES | DIFLUOROALKYLATION | CHEMISTRY, MULTIDISCIPLINARY | CYCLIZATION | CARBOXYLIC-ACIDS | BENZOIC-ACIDS | TRIFLUOROMETHYLATION
Journal Article
Organic Letters, ISSN 1523-7060, 11/2015, Volume 17, Issue 21, pp. 5188 - 5191
A palladium-catalyzed aryldifluoroalkylation of alkynes with ethyl difluoroiodoacetate and arylboronic acids as reaction partners is described. The alkyne... 
ETHYL BROMODIFLUOROACETATE | DIFLUOROMETHYLATION | ARYL BORONIC ACIDS | HYDROTRIFLUOROMETHYLATION | CHEMISTRY, ORGANIC | DIFLUOROACETYLATION | OXIDATIVE TRIFLUOROMETHYLATION | DIFLUOROALKYLATION | MEDIATED RADICAL ARYLDIFLUOROACETYLATION | UNACTIVATED ALKENES | BOND-FORMATION
Journal Article
Organic & Biomolecular Chemistry, ISSN 1477-0520, 01/2018, Volume 16, Issue 21, pp. 3876 - 3880
A Cu-catalyzed oxidation of alcohols triggered by the radical difluoroalkylation of alkenes has been developed, providing facile access to a series of... 
Carbonyl compounds | Catalytic oxidation | Alkenes | Ketones | Alcohol | Oxidation | Catalysis | Aldehydes | Copper | Alcohols | Carbonyls
Journal Article
Chemical Communications, ISSN 1359-7345, 04/2015, Volume 51, Issue 33, pp. 7222 - 7225
A novel visible light promoted carbodifluoroalkylation of allylic alcohols is disclosed. A series of difluoro 1,5-dicarbonyl compounds were obtained through a... 
H FUNCTIONALIZATION | REARRANGEMENT | ALKENES | DIFLUOROMETHYLATION | FLUOROALKYLATION | FLUORINE | RADICAL-ADDITION | DIFLUOROALKYLATION | CHEMISTRY, MULTIDISCIPLINARY | PHOTOREDOX CATALYSIS | TRIFLUOROMETHYLATION | Propanols - chemistry | Catalysis | Benzene Derivatives - chemistry | Light | Alkylation | Photochemical Processes
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 05/2016, Volume 81, Issue 9, pp. 3654 - 3664
An efficient and general method for C­(sp2)–H difluoroalkylation of aldehyde derived hydrazones via a CuII/B2pin2-catalyzed reaction between difluoroalkyl... 
PHARMACEUTICALS | ALPHA-ARYLATION | ALKYLATION | PROGRESS | CHEMISTRY, ORGANIC | FLUORINE | C-H DIFLUOROALKYLATION | ALPHA,ALPHA-DIFLUOROKETONES | RADICAL-ADDITION | BROMIDES | TRIFLUOROMETHYLATION
Journal Article
Organic Letters, ISSN 1523-7060, 10/2016, Volume 18, Issue 19, pp. 5130 - 5133
A new application of trifluoromethylating reagent, methyl fluorosulfonyldifluoroacetate (FO2SCF2CO2Me, Chen’s reagent), as the carbomethoxydifluoromethylating... 
MEDICINAL CHEMISTRY | VISIBLE-LIGHT | CHEMISTRY, ORGANIC | AROMATIC-SUBSTITUTION | DIFLUOROALKYLATION | FUNCTIONALIZED DIFLUOROMETHYL BROMIDES | ACCESS | UNACTIVATED ALKENES | FLUOROALKYLSULFONYL CHLORIDES | CARBOXYLIC-ACIDS | TRIFLUOROMETHYLATION
Journal Article
Organic Letters, ISSN 1523-7060, 06/2016, Volume 18, Issue 12, pp. 2880 - 2882
A decarboxylating alkynylation of α,α-difluoroarylacetic acids with ethynylbenziodoxolone reagents is reported. AgNO3 serves as the catalyst and K2S2O8 as the... 
ALKENES | ARYL BORONIC ACIDS | ORGANOBORONS | ALPHA-ARYLATION | FLUOROALKYLATION | CHEMISTRY, ORGANIC | ALIPHATIC CARBOXYLIC-ACIDS | ALKYNES | DIFLUOROALKYLATION | ACCESS | TRIFLUOROMETHYLATION
Journal Article
Organic Letters, ISSN 1523-7060, 03/2016, Volume 18, Issue 5, pp. 1143 - 1145
A K2S2O8/Cu­(OAc)2-mediated oxidative C–H/P–H cross-coupling of aldehyde hydrazones with diphenylphosphine oxide for the direct preparation of functionalized... 
FUNCTIONALIZATION | ALPHA-AMINOPHOSPHONATES | HYDROGENATION | LIGANDS | PHOSPHORYLATION | CHEMISTRY, ORGANIC | N,N-DIALKYLHYDRAZONES | INHIBITORS | DIFLUOROALKYLATION | ELECTROPHILIC SUBSTITUTION | C-H BONDS
Journal Article
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