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Chemistry - A European Journal, ISSN 0947-6539, 03/2019, Volume 25, Issue 17, pp. 4345 - 4357
Oxidative cleavage of the Csp -O bond in 1-arylisochromans with stoichiometric oxidants, such as CrO /H SO , has been practiced for decades in synthetic... 
oxidation | iron | isochromans | autoxidation | dioxygen
Journal Article
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, ISSN 0027-8424, 06/2014, Volume 111, Issue 24, pp. 8797 - 8802
Strategies for O-2 activation by copper enzymes were recently expanded to include mononuclear Cu sites, with the discovery of the copper-dependent... 
DIOXYGEN | ALPHA-HYDROXYLATING MONOOXYGENASE | ACTIVE-SITE | CRYSTAL-STRUCTURE | MULTIDISCIPLINARY SCIENCES | biofuels | COPPER | FAMILY | OXYGEN | DFT | dioxygen activation | END-ON | X-ray absorption spectroscopy | CELLULOSE | DOPAMINE BETA-MONOOXYGENASE
Journal Article
INORGANICA CHIMICA ACTA, ISSN 0020-1693, 04/2019, Volume 489, pp. 160 - 163
mu-Nitrido-bridged iron phthalocyanine dimers have attracted considerable attention because of their catalytic ability in alkane oxidation. However, clear and... 
DIOXYGEN | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Proceedings of the National Academy of Sciences of the United States of America, ISSN 0027-8424, 2014, Volume 111, Issue 24, pp. 8797 - 8802
Journal Article
Chemistry Letters, ISSN 0366-7022, 2/2009, Volume 38, Issue 2, pp. 182 - 183
Experiments show that [Ru(terpy)(bpy)(OH2)]2+ is highly active as a catalyst toward oxidation of water into molecular oxygen in spite of the mononuclear... 
CHEMISTRY, MULTIDISCIPLINARY | DIOXYGEN | WATER-OXIDATION
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 10/2015, Volume 137, Issue 40, pp. 12897 - 12905
A synthetic heme-Cu CcO model complex shows selective and highly efficient electrocatalytic 4e(-)/4H(+) O-2-reduction to H2O with a large catalytic rate (>105... 
OXYGEN ACTIVATION | RESONANCE RAMAN CHARACTERIZATION | ACTIVE-SITE | COUPLED ELECTRON-TRANSFER | IRON PORPHYRIN COMPLEXES | SPECTROSCOPIC CHARACTERIZATION | FUNCTIONAL ANALOGS | DIOXYGEN COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY | COPPER/DIOXYGEN ADDUCT FORMATION | O-2 REDUCTION
Journal Article
NATURE CHEMISTRY, ISSN 1755-4330, 07/2014, Volume 6, Issue 7, pp. 590 - 595
Enzymatic haem and non-haem high-valent iron-oxo species are known to activate strong C-H bonds, yet duplicating this reactivity in a synthetic system remains... 
NITROUS-OXIDE | DIOXYGEN ACTIVATION | DINITROGEN OXIDE | ACTIVE-SITES | ENZYMES | OXO | REACTIVITY | SPIN OXOIRON(IV) COMPLEX | BINDING | CHEMISTRY, MULTIDISCIPLINARY | 2ND-ORDER PERTURBATION-THEORY
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 02/2019, Volume 25, Issue 10, pp. 2376 - 2376
Non‐redox‐metal alkylperoxides have been recognized as a missing piece in the oxygenation chemistry puzzle since the first reference of their formation in... 
magnesium | oxygenation | dioxygen | peroxides | main group elements
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 06/2012, Volume 134, Issue 22, pp. 9098 - 9101
We report here an operationally simple, palladium-catalyzed cyclization reaction of N-aryl imines, affording indoles via the oxidative linkage of two C-H bonds... 
ACTIVATION | DIOXYGEN | C-H BOND | HECK | AROMATIC IMINES | OXIDANT | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | INDOLES
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 11/2010, Volume 132, Issue 45, pp. 15839 - 15841
We report a high performance oxygen reduction reaction (ORR) catalyst based on vertically aligned, nitrogen-doped carbon nanotube (VA-NCNT) arrays.... 
FUEL-CELLS | DIOXYGEN | CHEMISTRY, MULTIDISCIPLINARY | ELECTROCATALYSTS | Membrane fusion | Oxides | Structure | Analysis | Nanotubes
Journal Article
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, ISSN 1572-6657, 04/2015, Volume 743, pp. 134 - 138
Journal Article
Coordination Chemistry Reviews, ISSN 0010-8545, 09/2016, Volume 322, pp. 142 - 158
Discovery of soluble methane monooxygenase (sMMO) in 1966 aroused enthusiastic research on dinuclear iron centers, both in biological systems and chemical... 
Diiron enzymes | Dioxygen activation | Chemical models | Peroxo intermediates
Journal Article
by Zhang, YH and Yu, JQ
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 10/2009, Volume 131, Issue 41, pp. 14654 - 14654
Pd(II)-catalyzed ortho-hydroxylation of variously substituted benzoic acids under 1 atm of O-2 or air is achieved under nonacidic conditions. Extensive... 
OXIDATION | OXYGEN INSERTION | ACTIVATION | DIOXYGEN | METHANOL | PEROXIDES | MECHANISM | BENZOQUINONE | COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS
Journal Article
Proceedings of the National Academy of Sciences of the United States of America, ISSN 0027-8424, 08/2011, Volume 108, Issue 34, pp. 13990 - 13994
An efficient and selective four-electron plus four-proton (4e(-)/4H(+)) reduction of O-2 to water by decamethylferrocene and trifluoroacetic acid can be... 
Ferric hydroperoxo | Heme/copper | Dioxygen reduction | Kinetic mechanism | Enzyme model | DIOXYGEN | COMPLEX | ELECTROREDUCTION | MULTIDISCIPLINARY SCIENCES | REACTIVITY | HEME-COPPER OXIDASES | 4-ELECTRON REDUCTION | ferric hydroperoxo | IRON PORPHYRINS | kinetic mechanism | GRAPHITE-ELECTRODES | OXYGEN | heme/copper | BINDING | dioxygen reduction | enzyme model
Journal Article
by Wang, X and Lv, HC and Yang, LG and Dai, YQ
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, ISSN 1433-7266, 05/2017, Volume 232, Issue 3, pp. 385 - 386
C14H18Cl2Cu2N8O2, monoclinic, P2(1)/n (no. 14), a = 6.0166(6) angstrom, b = 15.2792(14) angstrom, c = 11.5833(12) angstrom, beta = 100.295(1)degrees, V =... 
DIOXYGEN | COMPLEX | CRYSTALLOGRAPHY
Journal Article
Journal of Biological Inorganic Chemistry, ISSN 0949-8257, 2014, Volume 19, Issue 4-5, pp. 529 - 539
Journal Article
Nature Communications, ISSN 2041-1723, 05/2016, Volume 7, Issue 1, p. 11470
Hydrogen peroxide (H2O2) in water has been proposed as a promising solar fuel instead of gaseous hydrogen because of advantages on easy storage and high energy... 
VISIBLE-LIGHT | COMPLEX | ENERGY | DIOXYGEN | REDUCTION | MULTIDISCIPLINARY SCIENCES | WATER OXIDATION | WO3 | H2O2 | EFFICIENCY | PHOTOSYNTHESIS
Journal Article
Journal of Catalysis, ISSN 0021-9517, 10/2017, Volume 354, pp. 78 - 83
The selective catalytic oxidation of alcohols is important both in laboratory and industrial production, and traditional oxidants cause environmentally lethal... 
Selective oxidation | Proton mediator | Copper | Dioxygen | Mechanism
Journal Article
INORGANIC CHEMISTRY, ISSN 0020-1669, 11/2019, Volume 58, Issue 22, pp. 15423 - 15432
The focus of this study is in the description of synthetic heme/copper/O-2 chemistry employing a heme-containing binucleating ligand which provides a... 
O BOND-CLEAVAGE | OXIDASE | ACTIVE-SITE | MU-PEROXO | INTERMEDIATE | DIOXYGEN REACTIVITY | COPPER | FUNCTIONAL-MODEL | COPPER/DIOXYGEN ADDUCT FORMATION | ELECTRONIC-STRUCTURE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Inorganica Chimica Acta, ISSN 0020-1693, 09/2018, Volume 481, pp. 166 - 170
The synthesis and solution characterization of the mononuclear copper(I) complex [Cu (PyNMe )(CH CN)] ( ) is described. This compound presents a symmetric... 
Oxygenases | Metastable species | Copper | Bioinorganic chemistry | Dioxygen
Journal Article
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