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dipnictenes (21) 21
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Chemistry – A European Journal, ISSN 0947-6539, 12/2018, Volume 24, Issue 71, pp. 18817 - 18817
London dispersion interactions contribute essentially to the overall stability of dipnictenes with an [E=E] 2+ (E = P, As, Sb) core supported by anionic... 
dipnictenes | local energy decomposition | pnictogens | heterocyclic carbenes | London dispersion
Journal Article
Inorganic chemistry, ISSN 0020-1669, 07/2019, Volume 58, Issue 15, pp. 10323 - 10332
A convenient synthetic route to Ga-stabilized pnictogen-centered radicals and gallapnictenes by manipulation of pnictogen-carbon bond strengths is presented.... 
ANION | SERIES | DIPNICTENES | REDUCTION | COMPLEXES | CHEMISTRY | CRYSTAL-STRUCTURES | OXIDATIVE ADDITION | CATIONS | CHEMISTRY, INORGANIC & NUCLEAR | Index Medicus
Journal Article
CHEMISTRY-A EUROPEAN JOURNAL, ISSN 0947-6539, 03/2018, Volume 24, Issue 13, pp. 3241 - 3250
Two equivalents of LGa (L=HC[C(Me)N(2,6-iPr(2)C(6)H(3))](2)) reacted with PX3 (X=Cl, Br) with insertion into two P-X bonds and formation of [L(X)Ga](2)PX (X=... 
subvalent compounds | GROUP-13 | DIPHOSPHENES | bond activation | OXIDATIVE ADDITION | ALUMINUM(I) | CHEMISTRY, MULTIDISCIPLINARY | ELECTRON LOCALIZATION | main group elements | quantum chemical calculations | CHEMISTRY | dipnictenes | BETA-DIKETIMINATE | LIGAND | OLEFIN COMPLEXES
Journal Article
CHEMISTRY-A EUROPEAN JOURNAL, ISSN 0947-6539, 04/2019, Volume 25, Issue 21, pp. 5445 - 5450
The synthesis and characterization of an (arsino)phosphaketene, As(PCO){[N(Dipp)](CH2)}(2) (Dipp=2,6-diisopropylphenyl) is reported along with its subsequent... 
boranes | 1ST COMPOUND | METAL-FUNCTIONALIZED PHOSPHAARSENES | DIPNICTENES | DIPHOSPHENES | COMPLEXES | phosphaketenes | REACTIVITY | catalysis | PHOSPHAKETENE | CHEMISTRY, MULTIDISCIPLINARY | SPECTROSCOPIC EVIDENCE | BOND COVALENT RADII | arsaphosphenes | main-group element | COORDINATED PHOSPHORUS-COMPOUNDS
Journal Article
CHEMISTRY-A EUROPEAN JOURNAL, ISSN 0947-6539, 12/2018, Volume 24, Issue 71, pp. 18922 - 18932
Several pnictogen dihalide complexes of the type (WCA-IDipp)EX2 (E=P, As, Sb; X=Cl, Br) that bear an anionic N-heterocyclic carbene ligand with a weakly... 
AUXILIARY BASIS-SETS | COORDINATION CHEMISTRY | DIHYDROGEN ACTIVATION | London dispersion | COMPLEXES | NHC | ADDUCTS | SALT-FREE REDUCTION | CHEMISTRY, MULTIDISCIPLINARY | MAIN-GROUP CHEMISTRY | LEWIS PAIRS | local energy decomposition | dipnictenes | pnictogens | CATALYSTS | N-heterocyclic carbenes
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 03/2019, Volume 25, Issue 17, pp. 4335 - 4339
The long‐sought carbene–bismuthinidene, (CAAC)Bi(Ph), has been synthesized. Notably, this represents both the first example of a carbene‐stabilized subvalent... 
carbenes | beryllium | bismuthinidenes | subvalency | bismuth | DIPNICTENES | PHOSPHAALKENES | CHEMISTRY, MULTIDISCIPLINARY | PHOSPHINIDENE COMPLEXES | DIBISMUTHENE | REDUCTION | LIGANDS | CHEMISTRY SYNTHESIS | DISTIBENE | Beryllium | Bismuth | X-ray diffraction | Communications | Communication
Journal Article
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 08/2019, Volume 58, Issue 32, pp. 11007 - 11012
Stable acyclic arsenium cations R2As+, isoelectronic analogues of germylenes, are rare in comparison to the corresponding phosphenium cations. The first... 
TRANSITION-METAL-COMPLEXES | DIPNICTENES | solid-state structures | 2-COORDINATE PHOSPHORUS | COORDINATION | arsenic | CHEMISTRY, MULTIDISCIPLINARY | main group chemistry | ELEMENTS | N-HETEROCYCLIC PHOSPHINES | P-ligands | pi-interactions | CHEMISTRY | MENSHUTKIN COMPLEX | PHOSPHENIUM | DIALKYLSTANNYLENE
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 06/2019, Volume 25, Issue 35, pp. 8249 - 8253
The first divinyldiarsenes [{(NHC)C(Ph)}As] 2 (NHC=IPr 3 a , SIPr 3 b ; IPr=C{(NAr)CH} 2 ; SIPr=C{(NAr)CH 2 } 2 ; Ar=2,6‐ i Pr 2 C 6 H 3 ) are reported.... 
double bond | main-group elements | arsenic | pi conjugation | vinyl | CATALYSIS | DIPNICTENES | COMPOUND | COMPLEXES | REACTIVITY | OXIDATIVE ADDITION | CHEMISTRY, MULTIDISCIPLINARY | REDUCTION | METAL | MULTIPLE BONDS | Dichloropropane | Chemical properties | Arsenic | Chlorides | Bonds | Organic chemistry | Energy gap | Metathesis | Molecular orbitals | Cleavage | Oxidation | Tellurium
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 05/2018, Volume 24, Issue 29, pp. 7358 - 7363
The use of bulky aryl(silyl)amides (R) as substituents for the stabilisation of phospha‐germynes and phospha‐stannynes (R−Ge≡P and R−Sn≡P, respectively) is... 
tin | nitrile analogues | germanium | bulky amides | phosphorus | DECARBONYLATION | COMPLEX | ANALOG | DIPNICTENES | DIPHOSPHENES | ALKYNE | CHEMISTRY, MULTIDISCIPLINARY | LIGANDS | 1,2-DIARYLDISILYNE | STABLE COMPOUND | SILICON TRIPLE BOND | Photolysis | Phosphides | Aromatic compounds | Tin | Amides | Germanium | Dimers
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 03/2019, Volume 2019, Issue 11-12, pp. 1669 - 1678
Reactions of two equivalents of LGa {L = HC[C(Me)NAr] 2 ; Ar = 2,6‐ i Pr 2 ‐C 6 H 3 } with SbX 3 (X = Cl, Br) yield double‐inserted products (LGaX) 2 SbX (X =... 
Main group elements | Antimony | Density functional calculations | Solid‐state structures | Carbenes | Solid-state structures | ACTIVATION | APPROXIMATION | DIPNICTENES | CHEMISTRY, INORGANIC & NUCLEAR | PHOSPHASILENE | REDUCTION | LIGANDS | BASIS-SETS | ORGANOANTIMONY | Organic chemistry | Quantum chemistry | Aromatic compounds | Ambient temperature | X-ray diffraction | Dispersion
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 03/2018, Volume 24, Issue 13, pp. 3241 - 3250
Two equivalents of LGa (L=HC[C(Me)N(2,6‐ i Pr 2 C 6 H 3 )] 2 ) reacted with PX 3 (X=Cl, Br) with insertion into two P−X bonds and formation of [L(X)Ga] 2 PX... 
bond activation | quantum chemical calculations | dipnictenes | subvalent compounds | main group elements | Nuclear magnetic resonance spectroscopy | Analysis | Substitutes | Magnetic resonance spectroscopy | Nuclear magnetic resonance--NMR | Quantum chemistry | Equivalence | Heating | Chemical bonds | Insertion | NMR spectroscopy
Journal Article
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, ISSN 0044-2313, 09/2018, Volume 644, Issue 17, pp. 1028 - 1033
The reactions of two equivalents of LGa {L = HC[C(Me)N(2,6-iPr(2)C(6)H(3))](2)} with SbX3 (X = Br, I, OEt) proceed with elimination of LGaX2 and formation of... 
Gallium | Multiple bonds | CARBENE ANALOG | DIPNICTENES | X-ray diffraction | REACTIVITY | Antimony | DOUBLY BONDED SYSTEMS | MAIN-GROUP ELEMENTS | CHEMISTRY, INORGANIC & NUCLEAR | DIBISMUTHENE | REDUCTION | CHEMISTRY SYNTHESIS
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 12/2018, Volume 24, Issue 71, pp. 18922 - 18932
Several pnictogen dihalide complexes of the type (WCA‐IDipp)EX 2 (E=P, As, Sb; X=Cl, Br) that bear an anionic N ‐heterocyclic carbene ligand with a weakly... 
dipnictenes | local energy decomposition | pnictogens | heterocyclic carbenes | London dispersion | N-heterocyclic carbenes | Stibenes | Quantum chemistry | Structural stability | Toluene | Metathesis | Lithium | Light emitting diodes | Chemical compounds | Carbenes | Dispersion | Organic chemistry | Cations | Magnesium
Journal Article
Heteroatom Chemistry, ISSN 1042-7163, 09/2014, Volume 25, Issue 5, pp. 306 - 312
The bromination reaction of the stable bis(ferrocenyl)dibismuthene, Fc*Bi=BiFc* ( 1 , Fc* = 2,5‐bis(3,5‐di‐ t ‐butylphenyl)ferrocenyl), with 0.5 equiv of BiBr... 
ORGANOMETALLIC COMPOUNDS | ELEMENTS | DIPNICTENES | COMPOUND | REACTIVITY | DOUBLY BONDED SYSTEMS | CRYSTAL | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Molecular Physics, ISSN 0026-8976, 10/2017, Volume 115, Issue 20, pp. 2597 - 2604
Journal Article
CHEMISTRY-AN ASIAN JOURNAL, ISSN 1861-4728, 04/2013, Volume 8, Issue 4, pp. 690 - 693
  Pi in the sky: 1,2-bis(ferrocenyl)distibene and 1,2-bis(ferrocenyl)dibismuthene derivatives, where two bulky ferrocenyl units are bridged by a Sb=Sb and... 
ELECTROCHEMISTRY | main-group elements | DIPNICTENES | MOLECULAR WIRES | COMPLEXES | RUTHENIUM | DOUBLY BONDED SYSTEMS | conjugation | pi interactions | CHEMISTRY, MULTIDISCIPLINARY | redox chemistry | sandwich complexes | SI=SI DOUBLE-BOND | HEAVIER GROUP-15 ELEMENTS | Electrons
Journal Article
Chemical Communications, ISSN 1359-7345, 08/2000, Issue 15, pp. 1353 - 1354
The condensation reaction of an overcrowded dihydrostibine with dibromobismuthine using 1,8-diazabicyclo[5.4.0]undec-7-ene as a base afforded the first stable... 
STATE | CRYSTAL | DIARSENE | DIPNICTENES | CHEMISTRY, MULTIDISCIPLINARY | DIPHOSPHENES
Journal Article
Journal Article
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